Review
Chemistry, Analytical
Sheetal Sheetal, Sheetal Kundu, Sanjeeve Thakur, Ashish Kumar Singh, Manjeet Singh, Balaram Pani, Viswanathan S. Saji
Summary: This paper critically reviews the application of electrochemical techniques in corrosion monitoring and compares recent research progress to provide better insights.
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Marsel Karmo, Isaac Azahel Ruiz Alvarado, Wolf Gero Schmidt, Erich Runge
Summary: In this study, we investigate the atomic structures and electronic properties of the As-terminated GaAs(001) surface in the presence of hydrogen using ab initio density functional theory. By calculating energy landscapes and density of states, we provide a phase diagram dependent on the chemical potentials of As and H, and show the effect of hydrogen adsorption on the states near the fundamental band gap.
Article
Materials Science, Multidisciplinary
Jesus Manuel Jaquez-Munoz, Citlalli Gaona-Tiburcio, Ce Tochtli Mendez-Ramirez, Miguel Angel Baltazar-Zamora, Francisco Estupinan-Lopez, Raul German Bautista-Margulis, Josefina Cuevas-Rodriguez, Juan Pablo de los Rios, Facundo Almeraya-Calderon
Summary: The anodization of titanium is an effective method to protect titanium and its alloys from corrosive environments. In this study, the electrochemical corrosion behavior of Ti-6Al-2Sn-4Zr-2Mo and Ti-6Al-4V alloys anodized in 1M H2SO4 and H3PO4 solutions was evaluated. The anodized samples showed changes in E-corr values and a higher passivation zone. EIS analysis revealed a higher resistance for samples anodized in H3PO4 and Ti-6Al-2Sn-4Zr-2Mo.
Article
Materials Science, Multidisciplinary
Fengting Cao, Guangyao Gao, Jie Li, Tao Li, Zequan He, Tiegang Wang, Yanmei Liu, Qixiang Fan, Hui Ma, Xing-qiu Chen
Summary: The inhibitory effect of benzotriazole (BTA) on the corrosion of 20SiMn steel in 3.5 wt% NaCl solutions was studied. BTA was found to suppress the corrosion through chemisorption, but with limited effectiveness.
Article
Chemistry, Multidisciplinary
Jiang Li, Joakim Halldin Stenlid, Thomas Ludwig, Philomena Schlexer Lamoureux, Frank Abild-Pedersen
Summary: Accurate theoretical simulation of electrochemical activation barriers is crucial for understanding electrocatalysis. By developing an analytical approach based on charge conservation and decoupled potential energy surfaces, we successfully simulated the Pt-catalyzed alkaline hydrogen evolution reaction with consideration of solvent thermal fluctuations, showing the significant impact of water-metal distances on charge transfer barriers.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Electrochemistry
C. S. Witharamage, A. A. Darwish, J. Christudasjustus, J. Soltis, R. K. Gupta
Summary: The time-dependent corrosion behavior of pure aluminum (Al) in a chloride-containing environment was studied. It was found that the surface film of pure aluminum continuously dissolved over time, while the increasing thickness of the passive oxide film enhanced the resistance. Corrosion kinetics increased in the early stage of immersion due to accelerated localized corrosion, but were inhibited after longer immersion times due to corrosion product deposition.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Meng-Fu Chen, Yingqian Chen, Zhen Jia Lim, Ming Wah Wong
Summary: This study investigates the adsorption structure and mechanism of imidazolium-based ionic liquids (ILs) as corrosion inhibitors for iron using density functional theory (DFT) and ab initio molecular dynamics (AIMD). The results show that ILs strongly adsorb on the metal surface through chemisorption. The alkyl chain length of the cation significantly affects the adsorption energy. DFT calculations provide more accurate modeling of the adsorption process compared to classical molecular dynamics calculations. This computational study contributes to understanding the nature of adsorption in green and sustainable corrosion inhibition using ILs.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Review
Chemistry, Physical
Junsoo Han, Oumaima Gharbi
Summary: This review discusses the extent to which current theoretical models and techniques used in corrosion science can be applied to new alloy systems, and outlines some of the challenges that need to be overcome.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Engineering, Environmental
Tarun Kanti Sarkar, Mahendra Yadav, I. B. Obot
Summary: The investigation presents the superior corrosion inhibition capabilities of two novel indoline compounds for oil well/tubing steel in 15% HCl solution. The gravimetric studies confirm high corrosion inhibition efficiency, while the electrochemical analysis approves the reduction in cathodic corrosion reaction and anodic reaction due to inhibitor adsorption. The substrate surface analysis reveals the formation of a protective film to protect the surface from aggressive acid solution, and theoretical studies support the experimental corrosion parameters.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Biochemistry & Molecular Biology
Deshuai Zhen, Shaoqi Zhang, Xinyu Zhang, Hongjian Zhang, Jue Wang, Bo Chen, Yali Liu, Xiaohu Luo
Summary: In this study, polysaccharide chitosan and L-histidine were used to synthesize chitosan-based carbon dots (CA-CDs), which were then introduced as a corrosion inhibitor for mild steel in 1.0 M HCl solution. The CA-CDs exhibited high inhibition efficiency and their adsorption behavior well obeyed the Langmuir adsorption isotherm containing both chemisorption and physisorption. The study provides insights into the corrosion inhibition mechanism of CA-CDs.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
Sandhya Sudhakaran, Elezabeth V. Abraham, Harsha Mahadevan, Krishnan Anoop Krishnan
Summary: This research successfully enhanced the phosphate adsorption capacity of Montmorillonite clay by incorporating iron-loaded crosslinked chitosan into its interlayer lattice space. The synthesized Fe-CS-MT composite showed efficient phosphate removal from aqueous media, following Pseudo-second-order kinetic and Freundlich isotherm models. Various analytical tools confirmed the endothermic and spontaneous nature of the phosphate adsorption process on Fe-CS-MT, presenting an eco-friendly adsorbent for phosphate removal in natural conditions.
SURFACES AND INTERFACES
(2021)
Article
Multidisciplinary Sciences
Nhlalo M. Dube-Johnstone, Unarine Tshishonga, Simon S. Mnyakeni-Moleele, Lutendo C. Murulana
Summary: The corrosion inhibition effects of a novel thiazolidinedione derivative named B1 were investigated on mild steel in 1 M HCl using gravimetric analysis, electrochemical analysis, and Fourier transform infrared spectroscopy. B1 showed a maximum percentage inhibition efficiency of 92% at 303.15 K in gravimetric analysis and 83% in electrochemical analysis at the same temperature. Thermodynamic parameters indicated that B1 adsorbs onto the MS surface via a mixed type of action at lower temperatures and exclusively chemisorption at higher temperatures.
Article
Chemistry, Physical
David Raciti, Thomas P. Moffat
Summary: Electrochemical mass spectrometry (EC-MS) combined with chronoamperometry was used to quantify the coverage of surface hydride phase on Cu(111) in 0.1 mol/L H2SO4. The study tracked the 2 atomic mass unit (amu) signal for H2 production and charge passed to examine anion desorption, hydride formation, and the hydrogen evolution reaction (HER).
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
Zeeshan Ahmad Abbasi, Abdul Mateen, Mohamed Abbas, Muhammad Atiq Ur Rehman, Abdul Wadood
Summary: Mineral coatings have shown great potential in combating wear and corrosion in industries at a cost-effective ratio compared to synthetic ceramics. This study focuses on the deposition of chromite coatings with a high concentration of Chromium oxide (Cr2O3) on steel substrates using High Velocity Oxygen Fuel (HVOF) and Atmospheric plasma spray (APS) techniques. The effects of deposition processes and Cr2O3 enrichment on the microstructure, hardness, tribological, and electrochemical behavior of the coatings are investigated. Results indicate that coatings deposited with APS exhibit excellent wear resistance, and higher Cr2O3 content contributes to improved hardness, compactness, tribological, and corrosion performance.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Chemistry, Analytical
Lei Cheng, Rong Jin, Dechen Jiang, Jian Zhuang, Xiaobo Liao, Qiangqiang Zheng
Summary: High-spatial-resolution local electrochemical impedance spectroscopy (LEIS) was achieved using scanning electrochemical cell microscopy (SECCM-LEIS), with a spatial resolution of approximately 180 nm. The stability and reliability of this platform were confirmed through long-term tests and Kramers-Kronig transformation. This technology revealed larger electric double-layer capacitance and smaller interfacial resistance at the edges of N-doped reduced graphene oxide compared to the planar surface, suggesting high electrochemical activity at the edges.
ANALYTICAL CHEMISTRY
(2021)
Article
Electrochemistry
P. Herrasti, E. Mazario, Francisco J. Recio
Summary: In this study, neodymium electrodes were used to immobilize magnetite nanoparticles for detecting H2O2 and glucose sensitivity. The peroxide content in contact lens fluid was also measured, showing less than 2% discrepancy between reported and measured values. The electrodes showed excellent reuse up to 10 times without loss of sensitivity and maintained good performance after 1 month of aging.
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2021)
Article
Engineering, Chemical
Natalya V. Likhanova, Nallely Lopez-Prados, Diego Guzman-Lucero, Octavio Olivares-Xometl, Irina V. Lijanova, Paulina Arellanes-Lozada, Janette Arriola-Morales
Summary: The study focused on the synthesis and evaluation of two PolyILs derived from alkylimidazolium imidazolate as corrosion inhibitors for API 5L X52 steel in oil reservoir production water. The PolyILs showed high inhibition efficiency of 80% with a mixed-type behavior. Adsorption mechanism involved blocking active sites through electrostatic attraction forces and chemical bond formation, resulting in reduced corrosion product formation on the steel surface.
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
(2022)
Article
Energy & Fuels
Joaquin Hernandez-Perez, Natalya Likhanova, Dennys Lopez-Falcon, Octavio Olivares-Xometl, Laura Munoz-Salazar, Fernando Trejo-Zarraga
Summary: Laboratory experiments showed that injecting 0.1 pore volume of emulsion slug is sufficient for adequate transportation of macroemulsions through porous media. Emulsions based on hydrophobic compounds were more effective than emulsions prepared from crude oil, with an additional oil recovery rate of up to 23.5% after injecting the emulsion slug.
PETROLEUM SCIENCE AND TECHNOLOGY
(2022)
Article
Environmental Sciences
S. Fernandez-Velayos, J. Sanchez-Marcos, A. Munoz-Bonilla, P. Herrasti, N. Menendez, E. Mazario
Summary: A method using 3D printing technology to prepare ZVI@PLA catalysts without post etching treatment was reported. The use of non-contact heating by magnetic induction (MIH) was shown to reactivate the surface of the catalyst, allowing for the ZVI@PLA catalyst to be reused up to 10 cycles with maintained efficiency. On the other hand, traditional thermal bath heating resulted in a gradual decrease in kinetic constant over 10 cycles.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Chemistry, Multidisciplinary
Fernanda L. Rivera, Nieves Menendez, Eva Mazario, Pilar Herrasti
Summary: In this study, a magnetic iron oxide nanoparticle-coated RVC electrode was used for the degradation of methylene blue. The electrode prepared by the dipping method showed the best degradation performance.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Multidisciplinary
Giselle Gomez-Sanchez, Octavio Olivares-Xometl, Natalya Likhanova, Paulina Arellanes-Lozada, Irina Lijanova, Victor Diaz-Jimenez, Diego Guzman-Lucero, Janette Arriola-Morales
Summary: The corrosion inhibition mechanism of API 5L X60 steel exposed to 1.0 M H2SO4 was evaluated using three vinylalkylimidazolium poly(ionic liquids) (PILs), which showed promising surface protection by surface adsorption and charge transfer processes.
Article
Environmental Sciences
Yawen Xiao, Ahmed S. Helal, Eva Mazario, Alvaro Mayoral, Alexandre Chevillot-Biraud, Philippe Decorse, Remi Losno, Francois Maurel, Souad Ammar, John S. Lomas, Miryana Hemadi
Summary: In this study, Maghemite (gamma-Fe2O3) nanoparticles were functionalized with 3-aminopropyltriethoxysilane (APTES) and reacted with diethylenetriamine-pentaacetic acid (DTPA) to obtain a nanohybrid adsorbent DAMNP. The DAMNP showed high adsorption capacity and selectivity for uranyl ions, making it a promising candidate for recovering uranium from nuclear wastewaters.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Physical
Sergio Fernandez-Velayos, Nieves Menendez, Pilar Herrasti, Eva Mazario
Summary: Fe3O4 catalyst was synthesized in a single step via electrochemical synthesis for the degradation of Ofloxacin (OFX) using sodium persulfate (PS). The effects of catalyst and oxidant concentration, as well as temperature, on the degradation kinetics were studied. The results showed that higher reaction temperature, catalyst, and initial PS dose strongly influenced the degradation efficiency. Thermal activation of persulfate at 60 degrees C resulted in a much greater degradation efficiency compared to 20 degrees C.
Article
Chemistry, Multidisciplinary
Victor Diaz-Jimenez, Paulina Arellanes-Lozada, Natalya Likhanova, Octavio Olivares-Xometl, Ernesto Chigo-Anota, Irina Lijanova, Giselle Gomez-Sanchez, F. Verpoort
Summary: The present study investigates the corrosion inhibition mechanism of API 5L X52 steel in 1 M H2SO4 using DDMS+I-, revealing a charge transfer process controlled inhibition mechanism and a mixed-type CI behavior of the IL. Surface analysis confirmed the presence of FexOy, FeOOH, and IL on the surface, supporting the formation of an IL monolayer on the metal surface.
Article
Chemistry, Analytical
Eduardo Gaya, Nieves Menendez, Eva Mazario, Pilar Herrasti
Summary: A simple electrochemical sensor based on electrochemically synthesized Fe3O4 nanoparticles was constructed to detect dopamine, uric acid, and ascorbic acid. The sensor showed significant sensitivity and selectivity, without interference from the three analyte molecules presented simultaneously in solution. The sensor has been successfully applied for the detection of these molecules in real samples.
Article
Biochemistry & Molecular Biology
Giselle Gomez-Sanchez, Octavio Olivares-Xometl, Paulina Arellanes-Lozada, Natalya V. Likhanova, Irina V. Lijanova, Janette Arriola-Morales, Victor Diaz-Jimenez, Josue Lopez-Rodriguez
Summary: The temperature effect on the corrosion inhibition process of API 5L X60 steel in 1 M H2SO4 was studied using three vinylimidazolium poly(ionic liquid)s (PILs) by electrochemical techniques, surface analysis, and computational simulation. The maximal inhibition efficiency (75%) was achieved by Poly[VIMC4][Im] at 308 K and 175 ppm. PILs exhibited E-corr displacements indicating mixed-type corrosion inhibitors (CIs). The presence of PILs resulted in less surface damage, confirming their inhibiting effect.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Biochemistry & Molecular Biology
Emiliano Cornejo Robles, Octavio Olivares-Xometl, Natalya V. Likhanova, Paulina Arellanes-Lozada, Irina V. Lijanova, Victor Diaz-Jimenez
Summary: In this study, 15 ionic liquids (ILs) derived from quaternary ammonium and carboxylates were synthesized and characterized. Their evaluation as corrosion inhibitors (CIs) for API X52 steel in 0.5 M HCl was conducted. Potentiodynamic tests showed that the inhibition efficiency (IE) varied with the chemical configuration of the anion and cation. The ILs were found to be mixed-type CIs and the IE was directly proportional to the CI concentration. Surface analysis by scanning electron microscopy confirmed the reduced steel damage in the presence of CI due to the inhibitor-metal interaction.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Engineering, Environmental
S. Fernandez-Velayos, F. J. Recio, F. J. Palomares, N. Menendez, P. Herrasti, E. Mazario
Summary: Cu2O@CuxFeyO4 nanohybrids were synthesized as catalysts for tetracycline degradation. The nanohybrids showed a spherical morphology with an average diameter of 14(5) nm and high crystallinity. XPS results indicated a cuprite-enriched surface and a nonstoichiometric copper spinel structure in the inner layer. The electrochemical characterization demonstrated the synergistic effect of Fe3+/Fe2+ and Cu2+/Cu+ coupling in enhancing the activation of persulfate, resulting in higher degradation efficiency compared to other catalysts.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Evelyn Y. Calvillo-Munoz, Araceli Vega-Paz, Diego Guzman-Lucero, Irina Lijanova, Octavio Olivares-Xometl, Natalya Likhanova
Summary: The synthesis of water-soluble terpolymers by free-radical inverse microemulsion and solution polymerization techniques was investigated. The results showed that the solution method yielded terpolymers with higher molecular weights at lower temperatures, while the inverse microemulsion method incorporated more (vinylbenzyl)trimethylammonium chloride into the terpolymer structure.
Article
Materials Science, Multidisciplinary
Madeeha Riaz, Manahil Najam, Hina Imtiaz, Farooq Bashir, Tousif Hussain
Summary: This study focuses on the structural and biological analysis of Zn-Cu based biodegradable alloys for orthopedic applications. The results indicate that the alloys have good electrical conductivity and biocompatibility, with potential for promoting bone growth and healing process. Additionally, the alloys exhibit a low corrosion rate and improved corrosion resistance.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Rijo Rajeev, Sk Safikul Islam, Anitha Varghese, Gurumurthy Hegde, Suryasarathi Bose
Summary: In this study, a facile and selective electrochemical sensor was developed for the sensing of guanosine. The sensor utilized a unique porous structure and ordered framework, enabling linear detection of guanosine concentration in the range of 0.123-720 μM under specific conditions.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Rafael V. M. Freire, Dominique Celeste de A. Dias, Jose Yago Rodrigues Silva, Dayane Kelly Dias do Nascimento Santos, Larissa T. Jesus, Ricardo O. Freire, Severino A. Junior
Summary: This study reports the extraction and isolation of euphol from nature, its adsorption in nanosized ZIF-8, and the efficacy of this system against cancer cells. Experimental and simulation results show that ZIF-8 can enhance the effectiveness of euphol against cancer cells and selectively target cancer cells.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Manal A. Awad, Awatif A. Hendi, Maha M. Almoneef, Maymunah Alwehaibi, Khalid M. Ortashi, Wadha Alenazi, Fatimah S. Alfaifi, Shareefa Alahmariye, Asma Alangery, Warda Ali Alghoubiri, Haia Aldosari
Summary: In this study, magnesium-doped zinc oxide nanoparticles were synthesized and characterized. The research findings show that magnesium doping can alter the crystal structure and optical properties of zinc oxide, while enhancing its dielectric constant.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
F. J. Willars-Rodriguez, I. R. Chaverz-Urbiola, M. A. Hernandez-Landaverde, A. Zavala-Franco, E. A. Chavez-Urbiola, P. Vorobiev, Yu V. Vorobiev
Summary: This study focuses on manganese doped CdS thin films synthesized by chemical bath deposition. The incorporation of Mn2+ cations in CdS was found to influence the crystalline structure, morphology, and optoelectronic properties. Doped thin films exhibited a uniform hexagonal structure, changed growth orientation, and showed scale-like and needle-like morphologies. The bandgap and rectification speed of Schottky diodes were modified by introducing manganese. This study suggests the potential for affordable high-speed optoelectronic devices.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Mehdi Javidi, Hooman Karimi Abadeh, Fatemeh Namazi, Hamid Reza Yazdanpanah, Narjes Shirvani Shiri
Summary: This study investigated the synergistic effect of temperature, solution velocity, and sulphuric acid concentration on the corrosion behavior of carbon steel using response surface methodology. The results showed that temperature affected anodic reactions, solution velocity influenced cathodic reactions, and acid concentration altered the corrosion mechanisms by changing the properties of the surface layer.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
R. Sakthivel, Thirumoorthy Kulandaivel, Kirankumar Venkatesan Savunthari, K. Mohanraj, Hans-Uwe Dahms, Aswin kumar Anbalagan, Manjunath Rangasamy, Kien-Voon Kong
Summary: In this study, saturated fatty acids were incorporated with silane to modify viscose fabric, resulting in superhydrophobic and superoleophilic properties. The modified fabric showed excellent separation efficiency for oil and organic solvents, with high absorption capacity. The modified fabric also exhibited durability and retained its properties in harsh conditions.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Wei Zhang, Hong Lei, Wenqing Liu, Zefang Zhang, Yi Chen, Xiaogang Hu, Xiangshan Ye
Summary: In this study, EDTA-grafted alumina composite abrasives were produced by a two-step process for the CMP of sapphire substrates. Experimental results showed that the modified abrasives exhibited better dispersion properties and significantly improved polishing efficiency, with higher material removal rates and lower surface roughness. The combination of chemical reaction and mechanical action enhanced the CMP performance.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Shumaila Rafaqat, Bushra Perveen, Warda Raqba, Warda Imran, Arshad Hussain, Naeem Ali
Summary: This study developed a MnP-based biosensor for quantitative measurement of dye concentrations using electrochemical signals. The effects of two different dyes on MnP activity were investigated, with one dye showing inhibitory effects and the other dye having no effect. The study demonstrates the potential application of enzyme-based biosensors in dye detection and toxicological monitoring.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Jinyan Shi, Oguzhan Yavuz Bayraktar, Baris Bayrak, Burak Bodur, Ali Oz, Gokhan Kaplan, Abdulkadir Cuneyt Aydin
Summary: The elemental composition of precursors is crucial for the performance development of geopolymers. The use of lime instead of metakaolin increases the fluidity and mechanical properties of geopolymers, while the addition of gypsum decreases them. Furthermore, higher lime content exacerbates the negative effect of gypsum.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Aayush Gupta, Kaveri Ajravat, Loveleen K. Brar, O. P. Pandey, Pandey Rajagopalan
Summary: This study focuses on the performance of Mn3O4-ZnO composite material in wastewater treatment and energy storage applications, and presents a detailed comparative analysis. Results show that the composite material with equal concentrations of Mn3O4 and ZnO exhibits excellent photocatalytic activity and high capacitance.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
V. Murugabalaji, Matruprasad Rout, Harsh Soni, Biranchi Narayan Sahoo
Summary: This study focuses on the corrosion characteristics of AA 7075 and AA 7075 based hybrid composite fabricated using stir casting and hot rolling techniques. The results show that the hybrid composite produced by hot cross rolling exhibits better corrosion resistance compared to the base metal. The addition of a small amount of graphite improves the bonding between the matrix and reinforcements, and the hot cross rolling enhances this bonding, leading to the formation of a strong passivation oxide layer and increased charge transfer resistance, thereby improving corrosion resistance.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Fangkun Ning, Qinghao Shi, Shuping Kong, Weitao Jia, Lifeng Ma
Summary: The paper investigates a new method of rolling sheets with variable chamfering amounts in both the transversal and normal directions. The feasibility of the technological process was tested through simulation and compared with experimental results. Three important process parameters, temperature, stress, and flow velocity, were used to evaluate the effects on chamfering amount before determining the optimal angle. The spread formula for evaluating the shape quality of the plate after ECR was obtained through testing and theory.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Aqeel Abbas, M. A. Hussein, Mohamed Javid
Summary: In this study, the AM60 magnesium alloy was processed using high-energy ball milling, and the results showed that different reinforcement agents had certain effects on particle size, crystallite size, lattice strain, and dislocation density.
MATERIALS CHEMISTRY AND PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
D. S. Mahmoud, E. M. Eldesouki, W. M. Abd El-Gawad
Summary: The development of flexible and lightweight microwave-absorbing materials has become a trendy topic. This study focuses on enhancing the microwave-absorbing performance of butadiene-acrylonitrile rubber (NBR) by incorporating novel reinforcing nanofillers. The results show that the NBR nanocomposite with a loading of 16 parts per hundred rubber (phr) of LiFe 20%/Si has the best microwave-absorbing performance.
MATERIALS CHEMISTRY AND PHYSICS
(2024)