4.6 Article

Composite inks of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate)/silver nanoparticles and electric/optical properties of inkjet-printed thin films

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 141, Issue 1, Pages 416-422

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2013.05.035

Keywords

Thin films; Polymers; Nanostructures; Electrical conductivity; Optical properties

Funding

  1. Marie Curie International Research Staff Exchange Scheme Project [PIRSES-GA-2010-269113]
  2. China-European Union technology cooperation project [1110]

Ask authors/readers for more resources

Poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate)/silver nanoparticles composite inks have been prepared through in situ synthesis and ultrasonic dispersion. The developed inks were proved to be suitable for various inkjet printing trials to deposit the thin films which were subsequently characterized to assess their electric and optical properties. The results have indicated that the dedoping of PSS from PEDOT during the in situ synthesis can be detrimental to the conductivity of the deposited composite films. However, the addition of silver nanoparticles to pristine PEDOT:PSS has significantly enhanced the conductivity of the thin films, with an inevitable loss in transparency. The various factors that can influence the properties of the thin films have also been analyzed and discussed. This study provides an insight into the effect of silver nanoparticles on PEDOT:PSS thin films deposited using inkjet printing process, and their properties due to the methods of ink formulation. (C) 2013 Elsevier B.V. All rights reserved.

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