4.6 Article

High-temperature oxygen non-stoichiometry, conductivity and structure in strontium-rich nickelates La2-xSrxNiO4-δ (x=1 and 1.4)

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 111, Issue 1, Pages 125-130

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2008.03.022

Keywords

oxide materials; oxygen vacancies; thermodilatometry; electrical conductivity; neutron diffraction

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Oxygen non-stoichiometry, electrical conductivity and thermal expansion of La2-xSrxNiO4-delta phases with high levels of strontium-substitution (1 <= x <= 1.4) have been investigated in air and oxygen atmosphere in the temperature range 20-1050 degrees C. These phases retain the K2NiF4-type structure of La-2 NiO4 (tetragonal, space group l4/mmm). The oxygen vacancy fraction was determined independently from thermogravimetric and neutron diffraction experiments, and is found to increase considerably on heating. The electrical resistivity, thermal expansion and cell parameters with temperature show peculiar variations with temperature, and differ notably from La2NiO4 +/-delta in this respect. These variations are tentatively correlated with the evolution of nickel oxidation state, which crosses from. a Ni3+/Ni4+ to a Ni2+/Ni3+ equilibrium on heating. (c) 2008 Published by Elsevier B.V.

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