4.7 Article

Fabrication, interface characterization and modeling of oriented graphite flakes/Si/Al composites for thermal management applications

Journal

MATERIALS & DESIGN
Volume 63, Issue -, Pages 719-728

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2014.07.009

Keywords

Composites; Graphite flake; Thermal conductivity; Interface structure; Amorphous

Funding

  1. National Natural Science Foundation of China [51201099]
  2. China Postdoctoral Science Foundation [2012M520891]
  3. foundation from the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University (China)
  4. FWO project of Belgium [U2 FA 070100/3506]

Ask authors/readers for more resources

Highly thermally conductive graphite flakes (Gf)/Si/Al composites have been fabricated using Gf, Si powder and an AlSi7Mg0.3 alloy by an optimized pressure infiltration process for thermal management applications. In the composites, the layers of Gf were spaced apart by Si particles and oriented perpendicular to the pressing direction, which offered the opportunity to tailor the thermal conductivity (TC) and coefficient of thermal expansion (CTE) of the composites. Microstructural characterization revealed that the formation of a clean and tightly-adhered interface at the nanoscale between the side surface of the Gf and Al matrix, devoid of a detrimental Al4C3 phase and a reacted amorphous Al-Si-O-C layer, contributed to excellent thermal performance along the alignment direction. With increasing volume fraction of Gf from 13.7 to 71.1 vol.%, the longitudinal (i.e. parallel to the graphite layers) TC of the composites increased from 179 to 526 W/m K, while the longitudinal CTE decreased from 12.1 to 7.3 ppm/K (matching the values of electronic components). Furthermore, the modified layers-in-parallel model better fitted the longitudinal TC data than the layers-in-parallel model and confirmed that the clean and tightly-adhered interface is favorable for the enhanced longitudinal TC. (C) 2014 Elsevier Ltd. All rights reserved.

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