4.7 Article

The effect of chain extension method on the properties of polyurethane/SiO2 composites

Journal

MATERIALS & DESIGN
Volume 35, Issue -, Pages 358-362

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2011.09.045

Keywords

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Funding

  1. China National Nature and Science Foundation [50273025]

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The polyurethane (PU)/SiO2 composites with diverse microstructure were obtained with different chain extension methods by pre-polymerization method. The composites with multitudinous crosslink density micro-domains were denoted as PUm/SiO2 composites, the other were denoted as PUh/SiO2 composites. The microstructure and the properties of PUm/SiO2 and PUh/SiO2 composites were investigated. The results showed that the particles of SiO2 were well-dispersed in PU matrix. It was demonstrated that the mechanical properties of PUm/SiO2 composites had optimal tear strength and maintained similar tensile strength in comparison with PUh/SiO2 composites. Scanning electron microscope (SEM) photographs indicated that the tensile sectional morphology of PUm/SiO2 composites was presented complex without rules, which verified that the PUm/SiO2 composites had better fracture toughness and strength. Differential scanning calorimetry (DSC) studies suggested a better micro-phase separation of soft and hard segments in PUm/SiO2 composites. Besides, the PUm/SiO2 composites had excellent solvent resistance performance. (C) 2011 Elsevier Ltd. All rights reserved.

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