Journal
APPLIED SURFACE SCIENCE
Volume 358, Issue -, Pages 110-121Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2015.08.123
Keywords
Graphite oxide; Reduced graphene oxide; Microwave; Exfoliation; Supercapacitors; Cyclic voltametry
Categories
Funding
- European project AUTOSUPERCAP (FP7)
- GSRT [12CHN205, GER-1813]
Ask authors/readers for more resources
Microwave irradiation of graphite oxide constitutes a facile route toward production of reduced graphene oxide, since during this treatment both exfoliation and reduction of graphite oxide occurs. In this work, the effect of pristine graphite (type, size of flakes), pretreatment and oxidation cycles on the finally produced expanded material was examined. All the types of graphite that were tested afforded materials with high BET surface areas ranging from 940 m(2)/g to 2490 m(2)/g, without intervening an activation stage at elevated temperature. SEM and TEM images displayed exfoliated structures, where the flakes were significantly detached and curved. The quality of the reduced graphene oxide sheets was evidenced both by X-ray photoelectron spectroscopy and Raman spectroscopy. The electrode material capacitance was determined via electrochemical impedance spectroscopy and cyclic voltammetry. The materials with PEDOT binder had better performance (similar to 97 F/g) at low operation rates while those with PVDF binder performed better (similar to 20 F/g) at higher rates, opening up perspectives for their application in supercapacitors. (C) 2015 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available