期刊
APPLIED SURFACE SCIENCE
卷 358, 期 -, 页码 110-121出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2015.08.123
关键词
Graphite oxide; Reduced graphene oxide; Microwave; Exfoliation; Supercapacitors; Cyclic voltametry
类别
资金
- European project AUTOSUPERCAP (FP7)
- GSRT [12CHN205, GER-1813]
Microwave irradiation of graphite oxide constitutes a facile route toward production of reduced graphene oxide, since during this treatment both exfoliation and reduction of graphite oxide occurs. In this work, the effect of pristine graphite (type, size of flakes), pretreatment and oxidation cycles on the finally produced expanded material was examined. All the types of graphite that were tested afforded materials with high BET surface areas ranging from 940 m(2)/g to 2490 m(2)/g, without intervening an activation stage at elevated temperature. SEM and TEM images displayed exfoliated structures, where the flakes were significantly detached and curved. The quality of the reduced graphene oxide sheets was evidenced both by X-ray photoelectron spectroscopy and Raman spectroscopy. The electrode material capacitance was determined via electrochemical impedance spectroscopy and cyclic voltammetry. The materials with PEDOT binder had better performance (similar to 97 F/g) at low operation rates while those with PVDF binder performed better (similar to 20 F/g) at higher rates, opening up perspectives for their application in supercapacitors. (C) 2015 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据