4.6 Article

Thermodynamically Stable Dispersions of Quantum Dots in a Nematic Liquid Crystal

Journal

LANGMUIR
Volume 29, Issue 30, Pages 9301-9309

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la401475b

Keywords

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Funding

  1. Royal Society [2008/R1]
  2. National Academy of Science of Ukraine [0110U003977, 0109U008051, 288-12.10.2011]
  3. STCU-NASU [5205]
  4. ARCUS program
  5. EPSRC [EP/E064299/1] Funding Source: UKRI
  6. Engineering and Physical Sciences Research Council [EP/E064299/1] Funding Source: researchfish

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Using transmittance electron microscopy, fluorescence and polarizing optical microscopy, optical spectroscopy, and fluorescent correlation spectroscopy, it was shown that CdSe/ZnS quantum dots coated with a specifically designed surfactant were readily dispersed in nematic liquid crystal (LC) to form stable colloids. The mixture of an alkyl phosphonate and a dendritic surfactant, where the constituent molecules contain promesogenic units, enabled the formation of thermodynamically stable colloids that were stable for at least 1 year. Stable colloids are formed due to minimization of the distortion of the LC ordering around the quantum dots.

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