4.6 Article

Dynamic Behavior of Water Droplets on Solid Surfaces with Pillar-Type Nanostructures

Journal

LANGMUIR
Volume 28, Issue 12, Pages 5360-5371

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la205106v

Keywords

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Funding

  1. Leading Foreign Research Institute through the National Research Foundation of Korea (NRF)
  2. Ministry of Education, Science, and Technology (MEST) [K20703001798-11E0100-00310]
  3. Korean Research Foundation (KRF)
  4. Korea government (MEST) [20110027445]
  5. Korea Institute of Science and Technology Information

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In the present study, we investigated the static and dynamic behavior of water droplets on solid surfaces featuring pillar-type nano-structures by using molecular dynamics simulations. We carried out the computation in two stages. As a result of the first computational stage, an initial water cube reached an equilibrium state at which the water droplet showed different shapes depending on the height and the lateral and gap dimensions of the pillars. In the second computational stage, we applied a constant body force to the static water droplet obtained from the first computational stage and evaluated the dynamic behavior of the water droplet as it slid along the pillar-type surface. The dynamic behavior of the water droplet, which could be classified into three different groups, depended on the static state of the water droplet, the pillar characteristics (e.g., height and the lateral and gap dimensions of the pillars), and the magnitude of the applied body force. We obtained the advancing and receding contact angles and the corresponding contact angle hysteresis of the water droplets, which helped classify the water droplets into the three different groups.

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