Article
Polymer Science
Naved Azum, Malik Abdul Rub, Anish Khan, Maha M. Alotaibi, Abdullah M. Asiri
Summary: This study examines the effects of anionic surfactants on the anesthetic drug tetracaine hydrochloride. Through experimental techniques and theoretical models, various parameters were calculated. The results indicate the presence of interactions between the drug and surfactants in mixed micelles, with sodium dodecyl sulfate showing stronger interactions.
Article
Engineering, Environmental
Yunxuan Hu, Shuangyu Zhang, Chenghui Luo, Lei Wan, Shuang Wu, Shams Ali Baig, Xinhua Xu
Summary: In this study, surfactant-modified layered double hydroxides were successfully prepared and demonstrated excellent sorption ability for Sb(V) removal. The study found that acidity, alkalinity, and ionic strength had little impact on the sorption, while strong alkalinity inhibited the sorption effect. Ion exchange and the formation of brandholzitelike structures were identified as the primary mechanisms for Sb(V) sorption by the modified LDHs.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Sudipta Chatterjee, Godfred Ohemeng-Boahen, Divine Damertey Sewu, Barnabas Asamoah Osei, Seung Han Woo
Summary: Alkali treatment increased the adsorption capacity of goethite impregnated chitosan capsules for Congo red and caused changes in their physico-chemical properties, morphology, and mechanical stability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Viktoriia Klovak, Sergey Kulichenko, Serhii Lelyushok
Summary: The study investigates the influence of charge, hydrophobicity, and spatial characteristics on the analytical signal of cationic and anionic surfactants in their association with fluorescent reagents in aqueous solutions. The results show that the contribution of electrostatic interactions, hydrophobic matching, and spatial matching play a significant role in determining the surfactant analytical signal. The effects observed lead to the design of an analytical system for the determination of sodium dodecyl sulfate with a fluorescent reagent.
Article
Chemistry, Multidisciplinary
Karolina Stachurska, Urszula Marcisz, Maciej Dlugosz, Jan M. Antosiewicz
Summary: In this study, the interaction between chymotrypsin and SDS at different concentrations was investigated by recording the CD spectra of the solutions. It was found that supplementing the chymotrypsin solution with SDS to achieve the same final concentration led to different CD spectra compared to directly adding SDS to the chymotrypsin solution. These differences disappeared when the initial concentration of SDS in the protein solution was higher, indicating the irreversibility of the SDS addition process and the influence of the initial SDS amount on subsequent addition. Quantitative analysis of the CD spectra revealed an increase in the population of helical forms in chymotrypsin under the influence of SDS.
Article
Chemistry, Applied
Evgeniya A. Bezrodnykh, Yury A. Antonov, Boris B. Berezin, Sergey N. Kulikov, Vladimir E. Tikhonov
Summary: The study demonstrates for the first time that shorter chitosan chains interact more preferentially with SDS and form larger microparticles. It also shows that hydrogen bonding plays a major role in microparticles aggregation, with hydrophobic interaction having a lesser effect.
CARBOHYDRATE POLYMERS
(2021)
Article
Engineering, Environmental
Mustafa Yavuz Celik, M. Resit Korucu
Summary: Three types of carbonate building stones from Turkey were tested for their physical and mechanical properties after freeze-thaw cycles with salt solutions. Material characterization, including chemical and mineralogical-petrographic tests, pore size distribution, and physico-mechanical tests, was performed. The results showed that water absorption, uniaxial compressive strength, and ultrasonic wave measurement values of all samples increased after multiple freeze-thaw cycles. However, the water absorption of silver travertine and Burdur limestone decreased due to the presence of small pores. The ultrasonic pulse velocity (UPV) values of travertine samples decreased gradually with more freeze-thaw cycles, and the uniaxial compressive strength (UCS) values of all samples decreased in all solutions.
BULLETIN OF ENGINEERING GEOLOGY AND THE ENVIRONMENT
(2023)
Article
Green & Sustainable Science & Technology
Panagiotis Xanthopoulos, Koen Binnemans
Summary: Ion flotation is an efficient technique for recovering metal ions from dilute solutions, but its industrial implementation is limited due to neglecting collector regeneration. A solvometallurgical process was developed to decompose copper(II) tetraamine dodecyl sulfate sublates from foams generated after ion flotation, demonstrating almost quantitative copper recovery. In addition, a closed-loop flow sheet was proposed for copper recovery using regenerated SDS with similar efficiency to fresh SDS.
JOURNAL OF SUSTAINABLE METALLURGY
(2021)
Article
Plant Sciences
Mariana Reginato, Virginia Luna, Jutta Papenbrock
Summary: In some areas of the world, high levels of sodium sulfate are found in the soil along with sodium chloride. While most studies focus on the salinity effects of sodium chloride, research on the inhibitory effects of sodium sulfate on plant growth is limited. Studies have shown that sodium sulfate may have a greater inhibitory effect on certain crop species compared to sodium chloride.
JOURNAL OF PLANT RESEARCH
(2021)
Article
Chemistry, Physical
Sepideh Khodaparast, William N. Sharratt, Gunjan Tyagi, Robert M. Dalgliesh, Eric S. J. Robles, Joao T. Cabral
Summary: This study investigates the micellar phase of pure and mixed aqueous solutions of SDS and DDAO, finding that the viscosity of mixed surfactant solutions increases exponentially with decreasing temperature and increasing DDAO content. A master curve for solution viscosity in terms of micellar aspect ratio is obtained, subsuming the effects of both temperature and DDAO composition in the experimental range investigated. The intrinsic viscosity of mixed micellar solutions is significantly higher than analytical and numerical predictions for Brownian suspensions of ellipsoidal colloids, emphasizing the importance of considering interactions of soft micelles under shear, especially at high concentrations.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Gunjan Tyagi, Dale Seddon, Sepideh Khodaparast, William N. Sharratt, Eric S. J. Robles, Joao T. Cabral
Summary: The study reveals that mixed SDS and DDAO can lead to decreased CMC and surface tension, with the most significant effect observed at a 1:1 molar ratio. The pH of mixed micellar solutions and molecular interaction parameters at the interface have larger magnitudes, but minimal changes are observed at fixed pH values.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Applied
Evgeniya A. Bezrodnyhk, Boris B. Berezin, Yury A. Antonov, Irina L. Zhuravleva, Anastasia A. Atamas, Aleksei A. Tsarenko, Andrey V. Rogachev, Vladimir E. Tikhonov
Summary: The interaction between binary chitosan/nonionic surfactant (NIS) system and sodium dodecyl sulfate (SDS) in aqueous solution is investigated in this study. The formation of insoluble complexes is weakened with a decrease in chitosan molecular weight and NIS critical micelle concentration, as well as an increase in NIS concentration. On the other hand, soluble complexes absorb SDS molecules until the charge of the complexes reaches a critical value, followed by aggregation of primary electrostatic complexes via hydrogen bonding. In contrast to the binary system, the ternary chitosan/NIS/SDS system forms complex nanoparticles through a head-to-tail binding mechanism, resulting in elongated filamentous microstructures. This finding has promising applications in the preparation of microbial stable pharmaceutical and cosmetic compositions, as well as drug delivery systems containing mixed surfactants.
CARBOHYDRATE POLYMERS
(2022)
Article
Chemistry, Analytical
Marko Pavlovic, Heman Kumar Ramiya Ramesh Babu, Saveh Djalali, Milan Vranes, Vasa Radoni, Lukas Zeininger
Summary: A novel method for monitoring mineral content of drinking water using responsive complex emulsions was reported, showing changes in droplet morphology to reflect variations in surfactant effectiveness due to metal cation addition. The study demonstrated that salt concentration and valency can influence the extent of droplet response, with divalent cations resulting in a more pronounced response. This device concept may provide a simple and cost-effective alternative for rapid monitoring of water hardness levels.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Shang Gao, Chrystian Ochoa, Vivek Sharma, Samanvaya Srivastava
Summary: The addition of salt significantly alters the stratification drainage process in micellar foam films formulated with ionic surfactants, leading to smaller step sizes and fewer steps in the thinning of the films. The long-range correlations between micelles are weakened, resulting in a rich nanoscopic topography and smaller intermicellar distances.
Article
Construction & Building Technology
Maohong Li, Xingzhi Zhou, Jumei Zhao, Shuxin Qu, Ping Wang, Guhua Li
Summary: In this study, a novel high-performance air entraining agent (HPAEA) was prepared by compounding sodium dodecyl sulfate (SDS) with a self-made fluorocarbon surfactant (S-FC) to improve the frost resistance of concrete. The results showed that when the concentration of S-FC reached 0.2 wt%, the foamability and foam stability of HPAEA were 2.9 times and 16.5 times higher than that of SDS, respectively, while the fresh air content was 1.6 times higher. Additionally, the air-void spacing factor in hardened mortar was reduced by more than 50%. It was concluded that the synergistic effect between SDS and S-FC in HPAEA improved its effectiveness in enhancing the frost resistance of concrete.
CONSTRUCTION AND BUILDING MATERIALS
(2023)