Journal
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 39, Issue 2-3, Pages 418-423Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2018.09.009
Keywords
Ceria; Point defects; Specific heat; Dielectric relaxation
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Funding
- internal NIMS project funds [PA5160, PA4020]
- King Mongkut's Institute of Technology Ladkrabang [2562-01-05-46]
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We report on magnetism, charge transport, dielectric properties and specific heat of Ce1-xSbxO2 ceramics sintered at 1650 degrees C with a final antimony content of 0 <= x <= 0.0017. In contrast to other donor dopants, such as Nb, Ta, U and W, charge compensation of antimony in Ce1-xSbxO2 does not involve the formation of the Ce3+ ions as revealed by the magnetic susceptibility data. Therefore, we conclude that antimony is mainly present as Sb3+ ion and acts as an acceptor dopant in Ce1-xSbxO2. This conclusion is also supported by a very low electrical conductivity of the Sb-doped ceria that shows an activation energy E-sigma similar to 0.97 eV. This activation energy is close to that observed in oxygen conducting acceptor-doped ceria and is significantly higher than the typical E-sigma similar to 0.1-0.3 eV values reported for n-type CeO2. Below 10 K, both an anomaly in the dielectric loss and a small specific heat surplus in Sb-doped ceria indicate a low-energy dipolar relaxation probably associated with a local dynamics of the off-centered Sb3+ point defects.
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