4.7 Article

Yttria nettings by colloidal processing

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 34, Issue 10, Pages 2509-2517

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2014.03.006

Keywords

Yttria; Ceramic processing; Porous ceramic; Gas burners; Luminescence

Funding

  1. Sao Paulo Research Foundation (FAPESP)
  2. National Council for Scientific and Technological Development (CNPq)
  3. Coordination of Improvement of High Degree People (CAPES)

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Porous ceramic burners have been shown as a promising technology to produce heat and lighting by burning low calorific fuels like modern biomass. Among ceramics, yttria (Y2O3) presents considerable luminescent proprieties for gas burner technology. By colloidal processing of yttria, this work aims to produce luminescence ceramic nettings with potential to be used as gas burners. Processing parameters such as mean particle size, zeta potential and flow behavior were evaluated in order to prepare suitable suspensions for replica method. Yttria nanoparticles presented light emission with lambda = 550 nm when being thermal stimulated at 150 degrees C. Besides, the nano sized powders d(50) = 113.8 nm and specific surface area of 13.6 m(2) g(-1) could be highly stabilized at pH 10.5. Suspensions with 30 vol% of solids, pH 10.5, 1 wt% of dispersant and 0.3 wt% of binder presented shear thinning behavior and thixotropy suitable for replica method. As a result, samples sintered at 1600 degrees C/1 h showed homogeneous morphology of struts and porous microstructure desirable for gas recirculation and burning process. (C) 2014 Elsevier Ltd. All rights reserved.

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