4.7 Article

The effect of forming stresses on the sintering of ultra-fine Ce0.9Gd0.1O2-δ powders

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 33, Issue 7, Pages 1289-1296

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2012.12.015

Keywords

Sintering; Ceria; Ceramic; Slurry; Porosity

Ask authors/readers for more resources

The effect of particle and pore arrangement on sintering and densification of ultra-fine (similar to 130 nm) Ce0.9Gd0.1O2-delta powder was evaluated. The common understanding that higher initial density of a ceramic network leads to a higher sintered density is not valid for fine powders, which have extremely good sinterability when there is a favourable particle packing. The effect of the applied stresses during forming (which produce different particle packing arrangements) was investigated by forging green bodies by different shaping techniques, including casting, and cold isostatic pressing. Samples formed with techniques that apply low levels of stress had a particle arrangement which significantly enhanced sintering at low temperature, compared to those prepared by high stress techniques. The sample geometry, heat treatment for organic removal and the initial density of the green body had a negligible effect on the final density when the ratio of the pore size to particle size was around 1. (C) 2013 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Ceramics

Low-temperature synthesis of bismuth titanate by modified citrate amorphous method

V. B. Tinti, D. Marani, A. Kabir, A. B. Haugen, V. Esposito, D. Z. de Florio

Summary: A low-temperature chemical route was proposed in this study to prepare single-phase bismuth titanate samples, achieving lower temperature treatment and higher density, showing superior electrical properties. The samples exhibit high dielectric constant, low loss factor, and good piezoelectric characteristics.

CERAMICS INTERNATIONAL (2021)

Article Chemistry, Physical

In-depth exploration of the synergistic interplay between perovskite barium titanate nanoparticles and two-dimensional graphene oxide for flexible piezoelectric nanogenerators

Jin Kyu Han, Da Som Song, Yi Rang Lim, Wooseok Song, Sung Myung, Sun Sook Lee, Ki-Seok An, Ha-Kyun Jung, Simone Santucci, Vincenzo Esposito, Jongsun Lim

Summary: An unprecedented strategy for direct growth of perovskite piezoelectric barium titanate nanoparticles on two-dimensional graphene oxide was demonstrated to maximize the synergistic effects in enhancing the piezoelectric response of nanogenerators. The hybridization of BTO nanoparticles with graphene oxide improved the piezoelectric response compared to pristine BTO nanoparticles-based nanogenerators, due to the formation of homogeneous size distribution and the healing of oxygen vacancies in BTO crystals along with an enhancement in the crystallinity of GO through chemical reduction.

APPLIED SURFACE SCIENCE (2021)

Article Multidisciplinary Sciences

Induced giant piezoelectricity in centrosymmetric oxides

D-S Park, M. Hadad, L. M. Riemer, R. Ignatans, D. Spirito, V Esposito, V Tileli, N. Gauquelin, D. Chezganov, D. Jannis, J. Verbeeck, S. Gorfman, N. Pryds, P. Muralt, D. Damjanovic

Summary: This study breaks the crystallographic symmetry and induces large and sustainable piezoelectric effects in centrosymmetric materials. The experiment shows the generation of extraordinarily large piezoelectric responses in cubic fluorite gadolinium-doped CeO2-x films, which are two orders of magnitude larger than the responses observed in the presently best-known lead-based piezoelectric relaxor-ferroelectric oxide. This finding provides opportunities to design environmentally friendly piezoelectric materials.

SCIENCE (2022)

Article Chemistry, Physical

Enhanced electromechanical properties in low-temperature gadolinium-doped ceria composites with low-dimensional carbon allotropes

Jinkyu Han, Ahsanul Kabir, Victor Buratto Tinti, Simone Santucci, Da Som Song, So Young Kim, Wooseok Song, Eunyoung Kim, Sang Don Bu, Frank Kern, Daniel Zanetti de Florio, Vincenzo Esposito

Summary: In this study, a new electro-chemo-mechanical functional carbon-metal oxide hybrid material was successfully fabricated by coupling the spark plasma sintering (SPS) technique with the ball mill process. The hybrid materials display high ionic conductivity and electromechanical properties at room temperature, showing potential for various functional metal oxide composites.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Energy & Fuels

2022 roadmap on 3D printing for energy

Albert Tarancon, Vincenzo Esposito, Marc Torrell, Marcel Di Vece, Jae Sung Son, Poul Norby, Sourav Barg, Patrik S. Grant, A. Vogelpoth, S. Linnenbrink, M. Brucki, T. Schopphoven, A. Gasser, Elif Persembe, Dionysia Koufou, Simon Kuhn, Rob Ameloot, Xu Hou, Kurt Engelbrecht, Christian R. H. Bahl, Nini Pryds, Jie Wang, Costas Tsouris, Eduardo Miramontes, Lonnie Love, Canhai Lai, Xin Sun, Martin Ryhl Kaern, Gennaro Criscuolo, David Bue Pedersen

Summary: The energy transition is a significant challenge and driving force for the scientific community. 3D printing offers great potential to automate the manufacturing of energy devices, improving performance and efficiency while reducing resource waste.

JOURNAL OF PHYSICS-ENERGY (2022)

Article Engineering, Manufacturing

Hybrid-3D printing of symmetric solid oxide cells by inkjet printing and robocasting

S. Anelli, M. Rosa, F. Baiutti, M. Torrell, V. Esposito, A. Tarancon

Summary: This study presents a new method for the fabrication of Solid Oxide Cells (SOCs) using self-standing robocast electrodes combined with inkjet printed electrolytes, completed through a cosintering process. Analysis and testing of the cells' characteristics confirmed the feasibility and reproducibility of this fabrication method.

ADDITIVE MANUFACTURING (2022)

Article Multidisciplinary Sciences

Atomically engineered interfaces yield extraordinary electrostriction

Haiwu Zhang, Nini Pryds, Dae-Sung Park, Nicolas Gauquelin, Simone Santucci, Dennis Christensen, Daen Jannis, Dmitry Chezganov, Diana A. Rata, Andrea R. Insinga, Ivano E. Castelli, Johan Verbeeck, Igor Lubomirsky, Paul Muralt, Dragan Damjanovic, Vincenzo Esposito

Summary: Electrostriction is a property of dielectric materials where a mechanical deformation is induced in response to an applied electric field. This study reports an engineered electrostriction effect achieved through the controlled interfaces of Gd2O3-doped CeO2 and Er2O3-stabilized delta-Bi2O3 on NdGaO3 substrates. The electrostriction coefficient achieved exceeds the best known materials by three orders of magnitude, and is attributed to the coherent strain from interfacial lattice discontinuity.

NATURE (2022)

Article Engineering, Manufacturing

Freeform injection molding of functional ceramics by hybrid additive manufacturing

Kyriakos Didilis, Debora Marani, Uffe Ditlev Bihlet, Astri Bjornetun Haugen, Vincenzo Esposito

Summary: This paper presents the technique of Freeform Injection Molding (FIM) and analyzes its ability in processing ceramic feedstocks. Through injection molding simulations to optimize parameters, the quality and performance of the samples were evaluated, and the related influencing factors were discussed.

ADDITIVE MANUFACTURING (2022)

Article Materials Science, Multidisciplinary

Oxidation inhibition of 3D printed porous steel by ceria-activated multilayers

Zhipeng Zhou, Venkata Karthik Nadimpalli, Aakil Raj Lalwani, Shu Wang, Yijing Shang, Zhihao Pan, David Bue Pedersen, Vincenzo Esposito

Summary: To enhance the oxidation resistance of porous metal components exposed to extreme conditions, a 3D-printed porous 410 L steel support with a novel ceramic multi-coating was developed. The support's simplified morphology with straight channels facilitates wet-chemical coating methods. The multi-coating method combining electrophoretic deposition and infiltration improves the interface between the ceramic and steel. The ceria-based coatings, exhibiting catalytic activity towards H2O and O2, offer both physical and dynamic chemical protection mechanisms. Electro-chemo-mechanical stability and superior corrosion resistance were demonstrated at 750°C in air-3% H2O for 122 hours (0.26 x10(-15) g(2) cm(4) s(-1)).

CORROSION SCIENCE (2023)

Review Chemistry, Multidisciplinary

Engineering of Electromechanical Oxides by Symmetry Breaking

Haiwu Zhang, Milica Vasiljevic, Achilles Bergne, Dae-Sung Park, Andrea R. Insinga, Shinhee Yun, Vincenzo Esposito, Nini Pryds

Summary: Complex oxides with diverse functionalities are crucial for cutting-edge electronics, energy, and information technologies. This review explores how to engineer thermodynamic variables to break the symmetry of centrosymmetric oxides and achieve/improve their electromechanical properties. The mechanisms used to break the inherent symmetry of conventional materials and discover novel applications are discussed. Accessing hidden phases could uncover opportunities for exotic properties like piezoelectricity and pyroelectricity. This review not only reports on engineering nonpolar oxides but also has implications for manipulating polar functional materials for better performance.

ADVANCED MATERIALS INTERFACES (2023)

Review Energy & Fuels

Powering internet-of-things from ambient energy: a review

Arindom Chatterjee, Carlos Nunez Lobato, Haiwu Zhang, Achilles Bergne, Vincenzo Esposito, Shinhee Yun, Andrea Roberto Insinga, Dennis Valbjorn Christensen, Carlos Imbaquingo, Rasmus Bjork, Hamsa Ahmed, Mariam Ahmad, Chun Yuen Ho, Morten Madsen, Jixi Chen, Poul Norby, Francesco Maria Chiabrera, Felix Gunkel, Ziwei Ouyang, Nini Pryds

Summary: Internet-of-thing (IoT) refers to a network of devices that collect and share data with each other through the internet, enabling access to raw information and facilitating intelligent decision making. With billions of IoT devices deployed, the challenge lies in creating self-powered units that can generate sufficient energy from ambient sources. This review paper discusses the recent progress in materials and device development for power and energy management in IoT applications, providing a comprehensive overview for new researchers and addressing challenges for those already in the field.

JOURNAL OF PHYSICS-ENERGY (2023)

Article Materials Science, Multidisciplinary

Post-lithiation: a way to control the ionic conductivity of solid-state thin film electrolyte

Jixi Chen, Alessandro Palliotto, Shinhee Yun, Dennis Valbjorn Christensen, Vincenzo Esposito, Nini Pryds

Summary: In this study, a method that combines synthesis optimization with a post-lithiation process is introduced to enhance the ionic conductivity of LLZO electrolyte. By compensating lithium loss and stabilizing the LLZO phase, the ionic conductivity is amplified by more than three orders of magnitude. The research also determines the optimal process conditions for the highest conductivity.

MATERIALS ADVANCES (2023)

Article Chemistry, Physical

Ni-free high-entropy rock salt oxides with Li superionic conductivity

Mattia Biesuz, Jixi Chen, Mauro Bortolotti, Giorgio Speranza, Vincenzo Esposito, Vincenzo M. Sglavo

Summary: High-entropy oxides with rock salt structure are materials with intriguing functional properties, but elements like Ni in their composition pose a threat to human health. In this study, we successfully develop a Ni-free high entropy rock salt by replacing nickel with manganese. Through suitable thermal treatment, we obtain samples with high density and good phase purity, and demonstrate the electrical properties of the materials.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Water Resources

Analytical solution for a strong free-surface water vortex describing flow in a full-scale gravitational vortex hydropower system

Vladimir Joel Alzamora Guzman, Julie Anne Glasscock

Summary: An analytical model of a strong free-surface water vortex was developed in this study, which calculates the maximum volumetric flow rate, air-core diameter, and rotational constant based on water head and geometric parameters. The simulated results showed excellent agreement with experimental observations using detailed data from a full-scale gravitational vortex hydropower system. This model does not assume a constant average velocity across the vortex radius, presenting advantages in turbine design for energy generation systems.

WATER SCIENCE AND ENGINEERING (2021)

Article Chemistry, Multidisciplinary

Gigantic electro-chemo-mechanical properties of nanostructured praseodymium doped ceria

Victor Buratto Tinti, Ahsanul Kabir, Jin Kyu Han, Sebastian Molin, Vincenzo Esposito

Summary: This study demonstrates large electrostriction in nanocrystalline 25 mol% praseodymium doped ceria (PCO) ceramics, showing superior performance comparable to, or even surpassing, traditional piezoelectric materials. Comparative analysis indicates that nanostructured PCO contains electromechanically active nanodomains, providing new insights into non-Newnham electrostrictors.

NANOSCALE (2021)

Article Materials Science, Ceramics

Phase equilibria in the ZrO2-GdO1.5-TaO2.5 system at 1500 °C

Dan Zhao, Yi Feng, Zhipeng Pi, Fan Zhang

Summary: Phase equilibria in the ZrO2-GdO1.5-TaO2.5 (ZGTO) system were experimentally investigated, and the differences between ZGTO and the existing ZrO2-YO1.5-TaO2.5 (ZYTO) were discussed. The study is useful for thermodynamic assessment of ZGTO and can guide the design of novel thermal barrier coatings materials.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Alumina precipitate along dislocations in rutile single crystal of diffusion couple during cooling from 1200° to 1400°C

Yutaka Ohya, Wingki Mey Hendra, Chika Takai-Yamashita, Takayuki Ban

Summary: Diffusion couples of rutile and corundum single crystals were prepared and examined to study the solid solution and precipitation of corundum in rutile during cooling. Different precipitation forms of corundum were observed under different cooling conditions.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Water-enhanced plasticity of calcium fluoride

Jiaming Zhan, Yunfa Guo, Hao Wang

Summary: This study systematically investigates the mechanical behaviors of calcium fluoride in humid environments. The effects of water on the deformation and plastic enhancement of CaF2 under indentation are explored through microindentation experiments, atomic simulations, and Raman spectroscopy measurement.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Microwave tunability in tin substituted barium titanate

Hangfeng Zhang, Henry Giddens, Theo Graves Saunders, Matteo Palma, Isaac Abrahams, Haixue Yan, Yang Hao

Summary: The relationship between low and high frequency tunabilities in tin substituted barium titanate ceramics was investigated. It was found that there are differences in tunabilities at different frequencies due to the different activities of larger ferroelectric domains and polar nanoclusters.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Boosting energy storage performance in negative temperature coefficient linear-like dielectrics via composite modulation in the superparaelectric state

Kaibiao Xi, Jiacheng Liu, Beibei Song, Huarong Cheng, Yihao Li, Xiaole Yu, Mupeng Zheng, Mankang Zhu, Yudong Hou

Summary: Composite modulation in the superparaelectric state of the BTBZ-CT system is proposed as an effective strategy to achieve both NTCC and excellent energy storage performance in dielectric ceramics. The addition of BZ and CT to BT ferroelectrics can move the SPE state to the normal use temperature zone, resulting in enhanced NTCC characteristics and energy storage performance. Furthermore, intentional precipitation of CT at grain boundaries can refine the grain size, increase the bandgap, and strengthen the local electric field distribution, thereby enhancing the breakdown electric field.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Sinterability of sodium bismuth titanate-based electroceramics at low temperatures

Hamed Salimkhani, Lovro Fulanovic, Till Froemling

Summary: The demand for robust multilayer ceramic capacitors with high-temperature and high-power capabilities is increasing rapidly. However, cost-effective production is a challenge. This study investigates the use of Na0.5Bi0.5TiO3-based materials as promising lead-free options. By adding sintering aids, the sintering temperature of Na0.5Bi0.5TiO3-BaTiO3-CaZrO3-BiAlO3 solid solutions was successfully reduced to 975 degrees C, suitable for co-sintering with Cu electrodes without adverse effects on capacitor properties.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Residual stress and interface debonding behavior in Si3N4w reinforced SiCN composites prepared by the PIP process: A case study

Mingxing Li, Ran Mo, Zeshui Xu, Jie Zhou, Conglin Zhang, Xuefeng Cui, Fang Ye, Laifei Cheng, Ralf Riedel

Summary: Polymer infiltration and pyrolysis is an effective method for preparing ceramic matrix composites. The transformation of polymer to ceramic during the process affects the residual stress and interface behavior in the composites.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Porous spheres enabling excellent high-temperature abradability and long lifetime for abradable seal coating

Yan Kang, Lin Chen, Chang-Jiu Li, Guan-Jun Yang

Summary: A novel abradable seal coating with low hardness and high bonding strength was successfully designed and prepared. This coating has significantly higher abradability and erosion resistance compared to metal-based coatings, and can retain excellent abradability and have a long lifetime during service.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Influence of raw material purity on microstructure and properties of calcia refractory

Qingzhong Song, Xiangdong Zha, Ming Gao, Yingche Ma

Summary: This study analyzes the influence of calcia refractory purity on the properties of calcia crucibles. Higher purity calcia results in well-developed grains and improved hydration resistance, leading to better high-temperature strength and thermal shock resistance. In contrast, lower purity calcia crucibles exhibit inferior properties. Therefore, high-purity calcia is considered a potential refractory for manufacturing oxide crucibles.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Ultra-low thermal conductivity and hydrophobic properties of high entropy β-type quaternary pyrosilicate

Sehreish Abrar, Faisal Nazeer, Zhuang Ma, Ling Liu, Abdul Malik, Mustafa Kamal, Abdullah G. Al-Sehemi

Summary: To raise the operating temperature of Si-based ceramic matrix composites (CMCs), researchers have applied thermal/environmental barrier coating (T/EBCs) materials, typically rare earth silicates. However, the high thermal conductivity and the mismatch of thermal expansion have been major challenges in developing new materials that can offer thermal insulation and environmental protection to CMCs. In this study, entropy engineering was used to create a multicomponent equi-atomic single-phase pyro silicate with extremely low thermal conductivity and enhanced water vapor corrosion resistance. The research findings show the potential of high entropy disilicates in achieving ultra-low thermal conductivity and low weight loss in corrosive environments.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Heterogeneous oxidation behavior and kinetic mechanisms of SiBCN ceramic with structure of MA-SiBCN coated by PDCs-SiBCN

Zi-bo Niu, Daxin Li, Dechang Jia, Zhihua Yang, Kunpeng Lin, Paolo Colombo, Ralf Riedel, Yu Zhou

Summary: In this study, SiBCN ceramics with a special structure were prepared to improve the oxidation resistance. The effect of the structure on oxidation behavior and kinetics was investigated, revealing that the special structure can effectively inhibit heterogeneous oxidation and enhance the oxide layer composition.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Low temperature densification and dielectric characterization of CeO2 ceramics

Melike Donmez, Metehan Erdogan, Cihangir Duran

Summary: The limited densification of CeO2 ceramics was improved by using an anorthite-based glass, resulting in high dielectric constant and quality factor with minimum dielectric loss. The CeO2-(anorthite-based) glass ceramic showed promising results in terms of low temperature densification and microwave properties.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

High speed impact and solid-state deposition of alumina particles: A molecular dynamics study

S. Rahmati, R. G. A. Veiga, J. Mostaghimi, T. Coyle, A. Dolatabadi

Summary: This study provides an atomic-scale description of the high-velocity impact of alpha-Al2O3 particles onto an alpha-Al2O3 substrate during Aerosol Deposition (AD). The results suggest that the crystal orientation plays a crucial role in both plasticity and damage of the nanoparticles. Impact velocity has a direct correlation with plasticity and fragmentation, but adhesion efficiency has only a marginal increase. The crucial element lies in the substrate's surface alterations caused by the fragments left on the substrate after impact.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Long-term ablation mechanisms of the YB4-Al2O3-Si3N4 modified Cf/ HfC-SiC composites at 2600 °C

Bo-Wen Chen, Yan-Mei Kan, De-Wei Ni, Chun-Jing Liao, Hong-Da Wang, Yu-Sheng Ding, Shao-Ming Dong

Summary: This study characterized the long-term and repeated ablation properties of modified Cf/HfC-SiC composites with YB4-Al2O3-Si3N4 under an air plasma torch. The structural stability and viscosity of the oxide layer were found to affect the ablation resistance of the composites. By forming nano c-HfO2 grains and high-viscosity Al-Si-Y-O glassy phase, the structural stability of the oxide layer was improved, resulting in enhanced ablation resistance. However, the oxidation of Si3N4 led to the formation of NO, NO2, and excessive SiO2 glassy phase, which resulted in a porous structure and reduced the viscosity of the oxide layer. Therefore, the addition of Si3N4 decreased the ablation resistance of the composites.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Structure characters, and thermal evolution of electrical and elastic behaviors in xBi(Ni1/2Hf1/2)O3-(1-x)PbTiO3 solid solutions with a tetragonal-pseudocubic phase boundary

Yongxing Wei, Huawei Zhang, Siyuan Dong, Changqing Jin, Chenxing Bai, Junle Dai, Zengzhe Xi, Zhonghua Dai, Zengyun Jian, Li Jin

Summary: In this study, solid solutions of xBi(Ni1/2Hf1/2)O-3-(1 - x)PbTiO3 (xBNH-PT) were synthesized to investigate their phase boundary behaviors and physical properties. The presence of a tetragonal-pseudocubic phase boundary and a spontaneous ferroelectric-relaxor transition at specific compositions were confirmed. The introduction of a tetragonal-pseudocubic phase boundary improved the piezoelectric properties and suppressed the spontaneous ferroelectric-relaxor transition.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)