Article
Engineering, Chemical
Shun Aoyama, Hiroki Nagasawa, Masakoto Kanezashi, Toshinori Tsuru
Summary: The effects of plasma treatment time on the gas permeation and pervaporation dehydration properties of organosilica membranes were investigated. The study found that increasing plasma modification time resulted in a decrease in pore size, leading to an increased He/N2 permeance ratio. The H2O/EtOH permeance ratio also increased from about 20 to over 1000 as the plasma modification time increased due to changes in pore structure and water adsorption properties.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Shun Aoyama, Hiroki Nagasawa, Masakoto Kanezashi, Toshinori Tsuru
Summary: In this study, a novel atmospheric-pressure water vapor plasma modification method was developed to enhance the pervaporation performance of organosilica membranes. The plasma treatment significantly improved the surface hydrophilicity and molecular sieving properties of the membranes, leading to high selectivity and permeance in the dehydration of alcohol solutions.
Article
Materials Science, Multidisciplinary
Artem Arkhangelskiy, Alberto Quaranta, Lucio Pancheri, Devid Maniglio
Summary: A novel method for creating conductive biocompatible coatings using cold plasma-assisted processes is reported in this study. The controlled deposition of conductive polymer PEDOT:PSS on substrates with different characteristics is achieved, and the stability and adhesion of the deposited films are studied. The influence of plasma reaction and etching mechanism on the electrical parameters is investigated using electrical resistance measurements. Additionally, the method is successfully applied to deposit stacked layers structures, opening up possibilities for designing basic passive electrical components and advanced biosensor devices with complex shapes.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Coatings & Films
Lee Organski, Xingxing Wang, Andrew Myers, Yun-Chu Chen, Kinam Park, Sarena. D. D. Horava, Coralie. A. A. Richard, Yoon Yeo, Alexey Shashurin
Summary: In this study, a DBD plasma apparatus was developed to continuously treat the inner surface of microbore tubing and investigate the effects of plasma power and treatment time on surface roughness and wettability.
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
(2022)
Article
Engineering, Industrial
Kazutoshi Katahira, Atsushi Ezura, Shogo Takesue, Jun Komotori
Summary: This study investigates the effect of atmospheric pressure nitrogen plasma combined with femtosecond laser surface modification on Ti-6Al-4V samples. The results suggest that the LP series samples (subjected to both laser and plasma irradiation) exhibit superior friction and wear characteristics due to the synergistic combination of three factors: increased smoothness through homogenizing laser-induced periodic surface groove shape structure, high hardness caused by grain refinement, and the formation of oxynitride leading to high toughness and low friction properties.
CIRP ANNALS-MANUFACTURING TECHNOLOGY
(2022)
Article
Metallurgy & Metallurgical Engineering
Kenta Nakazawa, Tatsuki Ohashi, Shotaro Saiki, Shoichi Kikuchi
Summary: The method of hardening AZ31 magnesium alloy using an atmospheric-pressure plasma jet at room temperature by exciting oxygen and nitrogen molecules to form an oxynitrided layer has been developed. This promising approach enhances the hardness of magnesium alloys without the need for heat treatment.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Metallurgy & Metallurgical Engineering
Kenta Nakazawa, Tatsuki Ohashi, Shotaro Saiki, Shoichi Kikuchi
Summary: Surface-hardening treatment for AZ31 magnesium alloy was achieved using an atmospheric-pressure plasma jet at room temperature, resulting in the formation of an oxynitrided layer and oxygen and nitrogen diffusion layer, which increased the hardness of the alloy. This method is a promising approach for locally hardening magnesium alloys without the need for heat treatment.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Chemistry, Physical
Sile Chen, Tao Cheng, Zhaoquan Chen, Xingyu Chen, Guan-Jun Zhang
Summary: Surface fluorination by low-temperature plasma treatment can enhance the surface electrical strength of insulating materials. The performance of modified materials is influenced by operation parameters, leading to different physical and chemical changes on the surface properties. Adjusting plasma exposure time, applied voltage, and CF4 volume fraction can affect the multi-effects caused by the various processes in the interface between plasma and material surface.
APPLIED SURFACE SCIENCE
(2021)
Review
Physics, Applied
Frank Foerster
Summary: This paper introduces the development and application of atmospheric pressure plasma technology, with a focus on the use of corona treatment to improve adhesion on material surfaces.
PLASMA PROCESSES AND POLYMERS
(2022)
Article
Engineering, Chemical
Z. Liu, C. Yang, T. Chen, W. S. Cai, L. H. Liu, L. M. Kang, Z. Wang, X. Q. Li, W. W. Zhang, Y. Y. Li
Summary: This study successfully eliminated the three unfavorable features of closed-pore hollow powder, satellite powder, and low excess free energy through discharge plasma modification of atomized titanium powder, and found that the activation energy of power-law creep for the modified powder is two times lower than that of the atomized counterpart.
Article
Engineering, Multidisciplinary
Keita Shimada, Ryuki Morita, Masayoshi Mizutani, Tsunemoto Kuriyagawa
Summary: Powder jet deposition (PJD) is a spray coating method that can be done under atmospheric pressure and room temperature. By applying an atmospheric-pressure plasma jet (APPJ) assistance, the deposition rate of PJD can be increased.
PRECISION ENGINEERING-JOURNAL OF THE INTERNATIONAL SOCIETIES FOR PRECISION ENGINEERING AND NANOTECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Kelsea K. Miller, I. Shancita, Sanjoy K. Bhattacharia, Michelle L. Pantoya
Summary: This study used atmospheric pressure plasmas to reduce the aluminum oxide shell, with argon plasma treatment resulting in surface hydration and helium plasma treatment showing no surface hydration. Both plasma-treated aluminum particles exhibited reduced oxidation barriers and increased reaction rate constants.
MATERIALS & DESIGN
(2021)
Article
Chemistry, Multidisciplinary
Artem Arkhangelskiy, Alberto Quaranta, Antonella Motta, Yuejiao Yang, Vamsi K. Yadavalli, Devid Maniglio
Summary: This paper presents a method for controlled plasma deposition of the versatile biomaterial chitosan on various substrates. Through optimization, the deposition of multiple layers of different biomaterials and patterned surfaces were achieved. The research is of great significance for surface treatment of biomedical devices and biological response.
ADVANCED MATERIALS INTERFACES
(2022)
Review
Engineering, Chemical
R. Hazlett, C. Schmidmeier, J. A. O'Mahony
Summary: Challenges encountered in handling high-protein dairy powders are often due to poor flowability caused by increased cohesive forces between particles. Traditional agglomeration and novel approaches such as dry-and wet-coating and roller compaction can be used to improve powder flowability.
Article
Physics, Applied
Chaoxia Zhao, Xinxin Li, Dinesh K. K. Agrawal, Zhili Yan, Siyao Qi, Yao Liu, Tianbao Ma, Qian Chen, Yi Zhang, Ce Wang, Kama Huang
Summary: A microwave atmospheric pressure plasma jet (MW-APPJ) generator based on a substrate-integrated waveguide (SIW) resonator is proposed, which can achieve a thin, straight plasma needle with a length of 9 cm. It has a high microwave feeding efficiency of over 90% under a wide range of gas flow rates without the need for a microwave matching network. The plasma jet's morphology transitions from laminar to turbulent mode as the gas flow increases from 1 to 14 L/min. Additionally, the SIW-based plasma generator can effectively make the polyimide film super hydrophilic after a 5-min treatment.
PLASMA PROCESSES AND POLYMERS
(2023)
Article
Nanoscience & Nanotechnology
Sultan Khetani, Kar Wey Yong, Vinayaraj Ozhukil Kollath, Erin Eastick, Milad Azarmanesh, Kunal Karan, Arindom Sen, Amir Sanati-Nezhad
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Engineering, Environmental
Mohita Sharma, Arpita Nandy, Nicole Taylor, Senthil Velan Venkatesan, Vinayaraj Ozhukil Kollath, Kunal Karan, Venkataraman Thangadurai, Nicolas Tsesmetzis, Lisa M. Gieg
JOURNAL OF HAZARDOUS MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Matthias Van den Bergh, Andraz Krajnc, Stefan Voorspoels, Sergio Rodrigues Tavares, Steven Mullens, Isabelle Beurroies, Guillaume Maurin, Gregor Mali, Dirk E. De Vos
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Materials Science, Multidisciplinary
Sultan Khetani, Kar Wey Yong, Kevin Guan, Anupriya Singh, Arindam Phani, Vinayaraj Ozhukil Kollath, Seonghwan Kim, Kunal Karan, Arindom Sen, Amir Sanati-Nezhad
APPLIED MATERIALS TODAY
(2020)
Article
Chemistry, Physical
Anthony Maho, Michael Lobet, Nathan Daem, Pierre Piron, Gilles Spronck, Jerome Loicq, Rudi Cloots, Pierre Colson, Catherine Henrist, Jennifer Dewalque
Summary: Photonically structured TiO2 is used in perovskite solar cells to enhance light absorption and charge collection efficiency, with optimum light absorption shown with approximately 400nm diameter TiO2 hollow spheres filled with CH3NH3PbI3. Solar cells composed of approximately 220nm diameter large TiO2 pores filled with CH3NH3PbI3 achieve the highest conversion efficiency.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Energy & Fuels
Nathan Daem, Jennifer Dewalque, Felix Lang, Anthony Maho, Gilles Spronck, Catherine Henrist, Pierre Colson, Samuel D. Stranks, Rudi Cloots
Summary: This study reports the deposition of Cs2AgBiBr6 double perovskite thin films using spray processing for the first time, comparing their properties with spin-coated benchmark films. Incorporating spray-coated Cs2AgBiBr6 thin films in solar cells achieved a photoconversion efficiency of 2.3% with high open-circuit voltage. The study highlights the suitability of ultrasonic spray deposition for optimizing Cs2AgBiBr6 solar cells in terms of light absorption and charge transfer.
Article
Chemistry, Physical
Nick Gys, Laurens Siemons, Bram Pawlak, Kenny Wyns, Kitty Baert, Tom Hauffman, Peter Adriaensens, Frank Blockhuys, Bart Michielsen, Steven Mullens, Vera Meynen
Summary: Recent research has focused on grafting metal oxides with organophosphonic acids to enhance their functionality. This study examines the impact of amine groups on surface properties through experiments and theoretical calculations, revealing the presence of different surface conformations and interactions. The results indicate that the presence of amine groups affects surface modification and structure of the materials.
APPLIED SURFACE SCIENCE
(2021)
Article
Engineering, Chemical
Elena M. Seftel, Steven Mullens, Vera Meynen, Pegie Cool, Bart Michielsen
Summary: The research focuses on developing porous MgAl-layered double hydroxide microspheres with high sphericity and uniform particle size distribution using the droplet coagulation technique. The combination of characterization techniques highlighted the production of porous microspheres where LDH plate-like particles are held together in a calcium alginate network without altering their structural features, opening up new opportunities for LDH-type materials in packed bed applications.
Article
Chemistry, Physical
Hamideh Eskandari, Vinayaraj Ozhukil Kollath, Kunal Karan
Summary: The replacement of pure Pt catalysts with Pt-Co and Pt-Ni alloy catalysts has reduced the cost of fuel cells but also introduced performance degradation due to leaching out of cobalt and nickel. This study investigates the impact of proton-cobalt ion exchange on the hydration and conductivity of thin ionomer films, and finds that the water content decreases upon cobalt ion exchange, leading to a significant reduction in ionic conductivity.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Multidisciplinary Sciences
Muhammad Naoshad Islam, Abdul Bashith Mansoor Basha, Vinayaraj Ozhukil Kollath, Amir Peyman Soleymani, Jasna Jankovic, Kunal Karan
Summary: This study demonstrates the successful development of low-Platinum content polymer electrolyte fuel cells with high oxygen reduction reaction (ORR) activity and fast oxygen transport by introducing a bottom-up designed spherical carbon support with intrinsic Nitrogen-doping.
NATURE COMMUNICATIONS
(2022)
Article
Nanoscience & Nanotechnology
Nathan Daem, Alexandre Mayer, Gilles Spronck, Pierre Colson, Jerome Loicq, Catherine Henrist, Rudi Cloots, Anthony Maho, Michael Lobet, Jennifer Dewalque
Summary: This study investigates the impact of using photonic crystals for light management in perovskite solar cells through numerical simulations and experiments. The results show that the photonic nanostructures have an effect on both optical and electronic properties, but the actual light management benefits are weakened due to other factors.
ACS APPLIED NANO MATERIALS
(2022)
Article
Engineering, Environmental
Hongshan Zhu, Stephan Heinitz, Samuel Eyley, Wim Thielemans, Koen Binnemans, Steven Mullens, Thomas Cardinaels
Summary: 213Bi-labeled radiopharmaceuticals for cancer treatment are of great interest, and finding a suitable sorbent material for separating 213Bi from its parent radionuclide 225Ac is challenging. This study reports on the synthesis and evaluation of sulfonated carbon materials (SCMs) as sorbents in inverse 225Ac/213Bi generators. The sulfonation of carbon materials prepared at 500 degrees C (SCM-500) showed promising results, with high selectivity for Bi3+ over La3+ and high chemical 213Bi yield in column tests.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Nathan Daem, Jennifer Dewalque, Dong Kuk Kim, Gilles Spronck, Max Attwood, Jessica Wade, Catherine Henrist, Pierre Colson, Sandrine Heutz, Rudi Cloots, Anthony Maho
Summary: Cs2AgBiBr6 double perovskite compounds have been studied as promising candidates to address issues intrinsic to traditional lead-containing solar cells. By introducing a molecular layer of tetracene within the Cs2AgBiBr6-based photovoltaic architecture, improved interfacial charge transfers and reduced charge recombination are achieved, leading to enhanced performance in photovoltaic devices.
Article
Materials Science, Multidisciplinary
Ehsan Hosseini, Vinayaraj Ozhukil Kollath, Kunal Karan
JOURNAL OF MATERIALS CHEMISTRY C
(2020)
Article
Chemistry, Multidisciplinary
Alison Joy Fulton, Vinayaraj Ozhukil Kollath, Kunal Karan, Yujun Shi
NANOSCALE ADVANCES
(2020)