Synthesis of poly(5,6-difluoro-2,1,3-benzothiadiazole-alt-9,9-dioctyl-fluorene) via direct arylation polycondensation

Direct (Het)Arylation of Fluorinated Benzothiadiazoles and Benzotriazole with (Het)Aryl Iodides

(2014) Chun-Yang He et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct (Hetero)Arylation: A New Tool for Polymer Chemists

(2013) Lauren G. Mercier et al.   ACCOUNTS OF CHEMICAL RESEARCH

Influences of the Non-Covalent Interaction Strength on Reaching High Solid-State Order and Device Performance of a Low Bandgap Polymer with Axisymmetrical Structural Units

(2013) Jyun-Fong Jheng et al.   ADVANCED MATERIALS

Dithienocarbazole and Isoindigo based Amorphous Low Bandgap Conjugated Polymers for Efficient Polymer Solar Cells

(2013) Yunfeng Deng et al.   ADVANCED MATERIALS

10.2% Power Conversion Efficiency Polymer Tandem Solar Cells Consisting of Two Identical Sub-Cells

(2013) Jingbi You et al.   ADVANCED MATERIALS

A new ladder-type benzodi(cyclopentadithiophene)-based donor–acceptor polymer and a modified hole-collecting PEDOT:PSS layer to achieve tandem solar cells with an open-circuit voltage of 1.62 V

(2013) Yung-Lung Chen et al.   CHEMICAL COMMUNICATIONS

Optimization of direct arylation polymerization conditions for the synthesis of poly(3-hexylthiophene)

(2013) Andrey E. Rudenko et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Controllable Direct Arylation: Fast Route to Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Derivatives for Organic Optoelectronic Materials

(2013) Junxiang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine Substituents Reduce Charge Recombination and Drive Structure and Morphology Development in Polymer Solar Cells

(2013) Andrew C. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Integrated Materials Design of Organic Semiconductors for Field-Effect Transistors

(2013) Jianguo Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular Establishment of a Diketopyrrolopyrrole-Based Polymer Library via Pd-Catalyzed Direct C-H (Hetero)arylation: a Highly Efficient Approach to Discover Low-Bandgap Polymers

(2013) Qiang Guo et al.   MACROMOLECULAR RAPID COMMUNICATIONS

C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials

(2013) Ken Okamoto et al.   MACROMOLECULES

A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation

(2013) Masayuki Wakioka et al.   MACROMOLECULES

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Made to order

(2013) Antonio Facchetti   NATURE MATERIALS

A polymer tandem solar cell with 10.6% power conversion efficiency

(2013) Jingbi You et al.   Nature Communications

Fluorinated Porous Organic Polymers via Direct C–H Arylation Polycondensation

(2013) De-Peng Liu et al.   ACS Macro Letters

An Air-Stable Low-Bandgap n-Type Organic Polymer Semiconductor Exhibiting Selective Solubility in Perfluorinated Solvents

(2012) Youhei Takeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Semiconducting Polymers Prepared by Direct Arylation Polycondensation

(2012) Antonio Facchetti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

(2012) Ya-Nong Wang et al.   CHEMICAL COMMUNICATIONS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct C-H Arylation of Thieno[3,4-b]pyrazines: Synthesis of Advanced Oligomeric and Polymeric Materials

(2012) Nabiha I. Abdo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Effect of End Groups on Optoelectronic Properties of Poly(9,9-dioctylfluorene): A Study with Hexadecylfluorenes as Model Polymers

(2012) Qilin Wang et al.   Journal of Physical Chemistry C

Detailed Optimization of Polycondensation Reaction via Direct C-H Arylation of Ethylenedioxythiophene

(2012) Koutarou Yamazaki et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Pd-Catalysed Direct Arylation Polymerisation for Synthesis of Low-Bandgap Conjugated Polymers and Photovoltaic Performance

(2012) Shu-Wei Chang et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Donor–Acceptor Conjugated Polymers with Dithienocarbazoles as Donor Units: Effect of Structure on Semiconducting Properties

(2012) Yunfeng Deng et al.   MACROMOLECULES

Facile Syntheses of Dioxythiophene-Based Conjugated Polymers by Direct C–H Arylation

(2012) Haichao Zhao et al.   MACROMOLECULES

Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs

(2012) Wei Lu et al.   MACROMOLECULES

Synthesis of 4,4′-dinonyl-2,2′-bithiazole-based copolymers via Pd-catalyzed direct C–H arylation

(2012) Wei Lu et al.   Polymer Chemistry

Direct arylation polycondensation for the synthesis of bithiophene-based alternating copolymers

(2012) Junpei Kuwabara et al.   Polymer Chemistry

Pathways to a New Efficiency Regime for Organic Solar Cells

(2012) L. Jan Anton Koster et al.   Advanced Energy Materials

Synthesis of Poly(4,4-dialkyl-cyclopenta[2,1-b:3,4-b′]dithiophene-alt-2,1,3-benzothiadiazole) (PCPDTBT) in a Direct Arylation Scheme

(2012) Sebastian Kowalski et al.   ACS Macro Letters

End-Capping Effect of a Narrow Bandgap Conjugated Polymer on Bulk Heterojunction Solar Cells

(2011) Jin Kuen Park et al.   ADVANCED MATERIALS

Development of Fluorinated Benzothiadiazole as a Structural Unit for a Polymer Solar Cell of 7 % Efficiency

(2011) Huaxing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Triple Role of Fluoride Ions in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unprecedented Transmetalation from [ArPdFL2] Complexes

(2011) Christian Amatore et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Replacing Alkoxy Groups with Alkylthienyl Groups: A Feasible Approach To Improve the Properties of Photovoltaic Polymers

(2011) Lijun Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 5-Alkyl[3,4-c]thienopyrrole-4,6-dione-Based Polymers by Direct Heteroarylation

(2011) Philippe Berrouard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Increased open circuit voltage in fluorinated benzothiadiazole-based alternating conjugated polymers

(2011) Yong Zhang et al.   CHEMICAL COMMUNICATIONS

Stille Polycondensation for Synthesis of Functional Materials

(2011) Bridget Carsten et al.   CHEMICAL REVIEWS

Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics

(2011) Chengliang Wang et al.   CHEMICAL REVIEWS

Cross-coupling Reactions of Organoboranes: An Easy Method for C–C Bonding

(2011) Akira Suzuki et al.   CHEMISTRY LETTERS

Direct Arylation as a Synthetic Tool for the Synthesis of Thiophene-Based Organic Electronic Materials

(2011) Derek J. Schipper et al.   CHEMISTRY OF MATERIALS

Fluorine Substituted Conjugated Polymer of Medium Band Gap Yields 7% Efficiency in Polymer−Fullerene Solar Cells

(2011) Samuel C. Price et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iterative Binomial Synthesis of Monodisperse Polyfluorenes up to 64-mers and Their Chain-Length-Dependent Properties

(2011) Qilin Wang et al.   MACROMOLECULES

Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation

(2011) Wei Lu et al.   MACROMOLECULES

Controlled polymerizations for the synthesis of semiconducting conjugated polymers

(2011) Ken Okamoto et al.   Polymer Chemistry

Synthesis of Thiophene- and Bithiophene-Based Alternating Copolymers via Pd-Catalyzed Direct C–H Arylation

(2011) Yohei Fujinami et al.   ACS Macro Letters

High-Efficiency Organic Solar Cells Based on End-Functional-Group-Modified Poly(3-hexylthiophene)

(2010) Jong Soo Kim et al.   ADVANCED MATERIALS

Carbazole-based polymers for organic photovoltaic devices

(2010) Jiaoli Li et al.   CHEMICAL SOCIETY REVIEWS

Water/alcohol soluble conjugated polymers as highly efficient electron transporting/injection layer in optoelectronic devices

(2010) Fei Huang et al.   CHEMICAL SOCIETY REVIEWS

Improving polymer transistor performance via morphology control

(2010) Hoi Nok Tsao et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Analysis of AzineN-Oxide Direct Arylation: Evidence for a Critical Role of Acetate in the Pd(OAc)2Precatalyst

(2010) Ho-Yan Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)

(2010) Qifeng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices

(2009) Andrew C. Grimsdale et al.   CHEMICAL REVIEWS

Catalytic C–C coupling through C–H arylation of arenes or heteroarenes

(2009) Gian Paolo Chiusoli et al.   COORDINATION CHEMISTRY REVIEWS

Suzuki Polycondensation: Polyarylenes à la Carte

(2009) Junji Sakamoto et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Polymer solar cells with enhanced open-circuit voltage and efficiency

(2009) Hsiang-Yu Chen et al.   Nature Photonics

Defect chemistry of polyfluorenes: identification of the origin of “interface defects” in polyfluorene based light-emitting devices

(2008) Stefan Kappaun et al.   CHEMICAL COMMUNICATIONS

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Macromonomer Approach toward Fluorene-Based Monodisperse Conjugated Polymers

(2008) Qin Liu et al.   MACROMOLECULES

Fluorescent Conjugated Polymers That Incorporate Substituted 2,1,3-Benzooxadiazole and 2,1,3-Benzothiadiazole Units

(2008) Jean Bouffard et al.   MACROMOLECULES