Article
Materials Science, Coatings & Films
Qiang Lin, Sulin Chen, Zhe Ji, Zhewei Huang, Zhinan Zhang, Bin Shen
Summary: This study demonstrates the deposition of UNCD films can be achieved in CH4/H-2 chemistry without Ar, and the re-nucleation rate can be specifically regulated by adjusting gas pressure and carbon concentration. A novel kinetic growth model was established to interpret the UNCD growth mechanism with CH4/H-2 chemistry, and the atmospheric window for the deposition of UNCD films was obtained. The study provides insights into the UNCD growth mechanism without Ar content and simplifies the gas strategy for UNCD growth.
SURFACE & COATINGS TECHNOLOGY
(2021)
Review
Chemistry, Physical
Yimin Lu, Guojun Huang, Sai Wang, Chaowei Mi, Shangfang Wei, Fangtao Tian, Wei Li, Haiyuan Cao, Yong Cheng
Summary: Pulsed laser deposition is an excellent technology for growing diamond-like carbon films, with high hardness, chemical inertness, low friction, and superior wear resistance. Various parameters and conditions influence the properties of the films, while new techniques like double laser beam deposition and hybrid pulsed laser deposition are under development. Applications in tribology, mechanics, medicine, and optics are driving further research and advancement in this field.
APPLIED SURFACE SCIENCE
(2021)
Article
Materials Science, Coatings & Films
Qiang Lin, Sulin Chen, Zhe Ji, Zhewei Huang, Zhinan Zhang, Bin Shen
Summary: The study revealed that the wear of diamond films at low temperatures is mainly induced by the strong adhesion between diamond and titanium, while at high temperatures, oxygen significantly etches the diamond films, causing loss of carbon atoms and increased wear.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Chemistry, Physical
Wen-Cheng Ke, Chih-Yung Chiang, Tae-Gyu Kim, Yi-Chan Lin, Chia-Yu Liao, Kuo-Jen Chang, Jia-Ching Lin
Summary: The study successfully grew N-doped UNCD conductive layer on InGaN-based LEDs using CNP enhanced nucleation, resulting in improved nucleation density and morphology. The LEDs exhibited a stable electroluminescence peak wavelength.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Michelle Salgado-Meza, Guillermo Martinez-Rodriguez, Pablo Tirado-Cantu, Eliel Eduardo Montijo-Valenzuela, Rafael Garcia-Gutierrez
Summary: The research investigates the impact of total pressure and microwave power on the electrical conductivity of N-UNCD films. Results show that inserting nitrogen atoms into the grain boundaries significantly enhances the electrical conductivity. Through X-ray diffraction and Raman spectroscopy, it was found that the N-UNCD films produced do not contain graphite phase but only crystalline nanodiamond grains. XPS analysis confirmed the presence of nitrogen and high conductivity in the N-UNCD films.
APPLIED SCIENCES-BASEL
(2021)
Article
Engineering, Industrial
Hua Wang, Xin Song, Xinchang Wang, Fanghong Sun
Summary: The study introduces a new type of diamond coating UNCD which enhances the cutting performances of PCB micro drills. Through the investigation of wear mechanisms of different diamond coatings, it is found that UNCD with tiny grain size reduces tool wear, while BD-MCD/BD-UNCD coated micro drill exhibits the best cutting performances while machining PCBs.
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY
(2021)
Article
Chemistry, Physical
Victor Ralchenko, Vadim Sedov, Artem Martyanov, Valery Voronov, Sergey Savin, Andrey Khomich, Mikhail Shevchenko, Andrey Bolshakov
Summary: We report on the growth of novel microcrystalline diamond-germanium composite films on Si substrates using microwave plasma assisted chemical vapor deposition. The structure of the films strongly depends on the deposition temperature, with competing Ge grains and diamond crystallites at lower temperatures, and enhanced diamond growth at higher temperatures. The composite shows optical transmission for wavelengths above 10 mm and exhibits bright optical emission of GeV color centers at 601 nm. The effective coefficient of thermal expansion can be tuned by adjusting the Ge volume fraction, facilitating integration with semiconductor wafers.
Review
Materials Science, Multidisciplinary
Orlando Auciello, Dean M. Aslam
Summary: This comprehensive review highlights the progress made in the fundamental and applied materials science of diamond films, focusing on synthesis processes, characterization of properties, integration with other materials, and optimization for MEMS/NEMS device performance. The ultimate goal is to produce transformative impact on global quality of life through the development of advanced sensors, energy generation devices, and other MEMS/NEMS technologies.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Physics, Fluids & Plasmas
Michael N. R. Ashfold, Yuri A. Mankelevich
Summary: This article presents a self-consistent two-dimensional modeling of MW activated N2/H2 and N2/CH4/H2 plasmas, which are relevant to contemporary diamond CVD. It discusses the limited reactivity of N2 under typical processing conditions and the dominant role of N atoms in enhancing growth rates.
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Physical
Jae-Eun Kim, Joong Il Jake Choi, Jeongjin Kim, Bongjin Simon Mun, Ki-Jeong Kim, Jeong Young Park
Summary: The study found that friction increased with the pressure of oxygen, remained unchanged in nitrogen gas, and decreased in water due to tribochemical reactions. The dissociation of water molecules under water conditions resulted in reduced friction force between diamond materials. This research sheds light on the important role of vapor-phase oxygen and water in the tribological properties of carbon-based materials.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Computer Science, Information Systems
Mahmoud Shaban, Abdelrahman Zkria, Tsuyoshi Yoshitake
Summary: N-doped UNCD/a-C:H composite films grown on Si substrates were investigated using temperature-dependent impedance spectroscopy, revealing a low-frequency conduction mechanism and a relaxation process originating from space charges in grain boundaries. The incorporation of nitrogen in the composite film increased the concentration of charge carriers within grain boundaries, enhancing their conductivity. Additionally, the capacitance corresponding to grain boundaries was greater than that from UNCD grains due to differences in grain size and grain-boundary width in the composite.
Article
Materials Science, Multidisciplinary
Kai-Hung Yang, Pratik Joshi, Keith B. Rodenhausen, Anirudha V. Sumant, Shelby A. Skoog, Roger J. Narayan
Summary: The surface chemistry of nitrogen incorporated ultrananocrystalline diamond (N-UNCD) films was altered by plasma treatment utilizing oxygen and fluorine plasma chemistries. Contact angle and zeta potential measurements were used to characterize the modified N-UNCD surfaces, providing a more complete understanding of the interactions between solid surface and aqueous solution. The bonding character, surface composition, and morphology of the N-UNCD films were monitored before and after surface treatment using various techniques to ensure the grafting of functional groups, with results primarily influenced by surface termination.
Article
Engineering, Electrical & Electronic
Chengke Chen, Binjie Tang, Hui Xu, Jinping Pan, Meiyan Jiang, Xiao Li, Xiaojun Hu
Summary: In this study, a low-pressure annealing treatment was used to enhance the EFE properties of UNCD films without doping. The improved EFE current densities were attributed to the refinement of diamond grains and the formation of a conductive network.
ACS APPLIED ELECTRONIC MATERIALS
(2021)
Article
Chemistry, Physical
Yunhai Liu, Lei Chen, Bangzheng Jiang, Yangqin Liu, Bin Zhang, Chen Xiao, Junyan Zhang, Linmao Qian
Summary: The low friction behavior of hydrogenated diamond-like carbon (H-DLC) films under reciprocating and unidirectional motions differs significantly. Reciprocating sliding reduces the friction coefficient while increasing surface wear compared to unidirectional sliding. The uniformity and structure of the transfer layer and worn surface strongly depend on the sliding motions.
Article
Engineering, Electrical & Electronic
Mahmoud Shaban
Summary: In this study, heterojunction diodes based on UNCD/a-C:H composite films were modeled and characterized, showing promising potential for power electronics devices. Experimental analysis led to the design of high-performance Schottky diodes with barrier heights of 1 eV, turn-on voltages of 0.75 V, and breakdown voltages of 270 V. Simulation results demonstrated a power figure of merit of 1.04 MW cm(-2), indicating the feasibility of using nitrogen-doped UNCD/a-C:H in power electronics applications.
SEMICONDUCTOR SCIENCE AND TECHNOLOGY
(2021)