Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 24, Pages 11399-11404Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo302375m
Keywords
-
Categories
Funding
- National Science Foundation [CHE-1009038]
- Direct For Mathematical & Physical Scien [1009038] Funding Source: National Science Foundation
- Division Of Chemistry [1009038] Funding Source: National Science Foundation
Ask authors/readers for more resources
Hofmann rearrangement of carboxamides to carbamates using Ozone as an oxidant can be efficiently catalyzed by iodobenzene. This reaction involves hypervalent iodine species generated in situ from catalytic amount of PhI and Oxone in the presence of 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) in aqueous methanol solutions. Under these conditions, Hofmann rearrangement of various carboxamides affords corresponding carbamates in high yields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
