4.7 Article Proceedings Paper

Radiation-induced segregation and phase stability in ferritic-martensitic alloy T 91

Journal

JOURNAL OF NUCLEAR MATERIALS
Volume 417, Issue 1-3, Pages 140-144

Publisher

ELSEVIER
DOI: 10.1016/j.jnucmat.2010.12.052

Keywords

-

Ask authors/readers for more resources

Radiation-induced segregation in ferritic-martensitic alloy T 91 was studied to understand the behavior of solutes as a function of dose and temperature. Irradiations were conducted using 2 MeV protons to doses of 1, 3, 7 and 10 dpa at 400 degrees C. Radiation-induced segregation at prior austenite grain boundaries was measured, and various features of the irradiated microstructure were characterized, including grain boundary carbide coverage, the dislocation microstructure, radiation-induced precipitation and irradiation hardening. Results showed that Cr, Ni and Si segregate to prior austenite grain boundaries at low dose, but segregation ceases and redistribution occurs above 3 dpa. Grain boundary carbide coverage mirrors radiation-induced segregation. Irradiation induces formation of Ni-Si-Mn and Cu-rich precipitates that account for the majority of irradiation hardening. Radiation-induced segregation behavior is likely linked to the evolution of the precipitate and dislocation microstructures. (C) 2010 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Multidisciplinary

In situ ion irradiation of amorphous TiO2 nanotubes

Chao Yang, Tristan Olsen, Miu Lun Lau, Kassiopeia A. Smith, Khalid Hattar, Amrita Sen, Yaqiao Wu, Dewen Hou, Badri Narayanan, Min Long, Janelle P. Wharry, Hui Xiong

Summary: Understanding the evolution of structure and morphology in nanomaterials is crucial for controlling their functionality. In this study, the effects of irradiation on the morphology and structure of amorphous and anatase TiO2 nanotubes were investigated. The anatase TiO2 nanotubes showed stability under irradiation due to their grain boundaries and surfaces, while the amorphous TiO2 nanotubes underwent irradiation-induced crystallization, with partially crystallized tubes bending due to internal stresses. These findings provide a new pathway for controlling the structure and morphology of energy storage materials.

JOURNAL OF MATERIALS RESEARCH (2022)

Article Nanoscience & Nanotechnology

Molecular dynamics simulation of vacancy and void effects on strain-induced martensitic transformations in Fe-50 at.% Ni model concentrated solid solution alloy

Chao Yang, Yash Pachaury, Anter El-Azab, Janelle Wharry

Summary: Vacancies have no significant effect on martensitic transformation, while voids activate the transformation by inducing shear strain accumulation due to dislocation pileup. The larger the void, the more pronounced the effect.

SCRIPTA MATERIALIA (2022)

Article Materials Science, Multidisciplinary

A data science approach for analysis and reconstruction of spinodal-like composition fields in irradiated FeCrAl alloys

Yash Pachaury, Tomohisa Kumagai, Janelle P. Wharry

Summary: This article presents a statistical method for analyzing continuously distributed data of irradiated FeCrAl alloys using Energy Dispersive X-ray Spectroscopy (EDS). By using probability distribution functions and covariance functions, the effects of alloy composition and irradiation dose on the spatial distribution and length scale of composition fluctuations were investigated.

ACTA MATERIALIA (2022)

Article Materials Science, Multidisciplinary

Synergies between H, He and radiation damage in dual and triple ion irradiation of candidate fusion blanket materials

Logan N. Clowers, Zhijie Jiao, Gary S. Was

Summary: Three ferritic/martensitic alloys were irradiated with single, dual, and triple ion beams to study cavity evolution. Co-injection of hydrogen with helium increased cavity number density and size, leading to higher swelling. F82H alloy exhibited the lowest swelling due to high sink strength, while CNA3 alloy showed higher swelling than F82H due to lower sink strength caused by precipitation dissolution.

JOURNAL OF NUCLEAR MATERIALS (2022)

Article Materials Science, Multidisciplinary

Nanoindentation Investigation of Chloride-Induced Stress Corrosion Crack Propagation in an Austenitic Stainless Steel Weld

Haozheng J. Qu, Janelle P. Wharry

Summary: In this study, the correlation between grain orientation, grain boundaries, and hardening from TGCISCC propagation was investigated by nanoindentation mapping and scanning electron microscopy. The results showed that the hardness of individual grains does not control TGCISCC propagation, but localized strain hardening at the crack tip was observed.

METALS (2022)

Article Materials Science, Multidisciplinary

Deformation-Assisted Rejuvenation of Irradiation-Induced Phase Instabilities in Cu-Ta Heterophase Nanocomposite

Priyam Patki, Yaqiao Wu, B. Chad Hornbuckle, Kristopher A. Darling, Janelle P. Wharry

Summary: This study explored the effects of coupled deformation and irradiation extremes on Ta phase evolution in Cu-10at.%Ta nanocomposite. The findings suggest that after irradiation-induced dissolution of Ta nanoparticles, deformation-induced Ta nanoparticle nucleation and growth along grain boundaries may stabilize or rejuvenate the nanoparticles in extreme environments.
Article Physics, Applied

Elimination of remnant phases in low-temperature growth of wurtzite ScAlN by molecular-beam epitaxy

Brandon Dzuba, Trang Nguyen, Amrita Sen, Rosa E. Diaz, Megha Dubey, Mukesh Bachhav, Janelle P. Wharry, Michael J. Manfra, Oana Malis

Summary: Growth of wurtzite ScxAl1-xN (x<0.23) on c-plane GaN at high temperatures alters the lattice constants due to defects, while ScAlN grown below a certain temperature exhibits uniform alloy distribution and reduced defect density. The lattice constant of low-temperature ScAlN varies with composition and can be used to estimate alloy composition. Lattice-matched Sc0.18Al0.82N/GaN multi-quantum wells grown under these conditions show strong near-infrared absorption lines, confirming their advantageous optical and electronic properties.

JOURNAL OF APPLIED PHYSICS (2022)

Article Nanoscience & Nanotechnology

Comparing structure-property evolution for PM-HIP and forged alloy 625 irradiated with neutrons to 1 dpa

Caleb Clement, Sowmya Panuganti, Patrick H. Warren, Yangyang Zhao, Yu Lu, Katelyn Wheeler, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry

Summary: This study compares the response of PM-HIP alloys and forged alloys under neutron irradiation. The results show that PM-HIP alloys have better resistance to irradiation and less hardening. These findings provide hope for the qualification of PM-HIP alloys for nuclear applications.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Review Chemistry, Physical

Irradiation-Induced Amorphous-to-Crystalline Phase Transformations in Ceramic Materials

Cyrus Koroni, Tristan Olsen, Janelle P. Wharry, Hui Xiong

Summary: Amorphous ceramics are a class of materials with unique properties and functionalities. While irradiation is commonly associated with disorder, it has been observed that irradiation can induce crystallization in amorphous ceramics. This perspective provides a summary and review of examples from the literature on irradiation-induced amorphous-to-crystalline phase transformations in ceramics, highlighting the influential irradiation conditions, material parameters, and discussing the impact on material properties. Future research directions to harness these transformations for tailored material behavior are also presented.

MATERIALS (2022)

Article Materials Science, Multidisciplinary

Systematic study of radiation-induced segregation in neutron-irradiated FeCrAl alloys

Priyam Patki, Timothy J. Pownell, Yerik Bazarbayev, Dalong Zhang, Kevin G. Field, Janelle P. Wharry

Summary: This study systematically reports the grain boundary radiation-induced segregation (RIS) and its mechanisms in FeCrAl alloys, emphasizing the need to consider RIS implications on corrosion and oxidation susceptibility in alloy design.

JOURNAL OF NUCLEAR MATERIALS (2023)

Article Nanoscience & Nanotechnology

Taming the Pseudoelastic Response of Nitinol Using Ion Implantation

Alejandro Hinojos, Daniel Hong, Hariharan Sriram, Longsheng Feng, Chao Yang, Janelle P. Wharry, Xuesong Gao, Khalid Hattar, Nan Li, Jeremy E. Schaffer, Yunzhi Wang, Michael J. Mills, Peter M. Anderson

Summary: Implantation of Ni50.5Ti49.5 wire with low doses of 30 MeV Ni6+ ions can systematically alter the pseudoelastic response, with extreme changes in nanoindentation load, hysteresis, and recoverable displacement occurring at a depth of 3.6 μm below the implantation surface. These changes are attributed to amorphous clusters that constrain the stress-induced B2-B19' phase transformation. Simulations support this by showing the refinement of martensite caused by nm-scale defects. These results suggest that ion implantation could expand the processing and performance capabilities of NiTi.

SCRIPTA MATERIALIA (2023)

Article Multidisciplinary Sciences

Mechanical testing data from neutron irradiations of PM-HIP and conventionally manufactured nuclear structural alloys

Janelle P. Wharry, Caleb D. Clement, Yangyang Zhao, Katelyn Baird, David Frazer, Jatuporn Burns, Yu Lu, Yaqiao Wu, Collin Knight, Donna P. Guillen, David W. Gandy

Summary: This article presents a comprehensive mechanical testing data archive of nuclear structural alloys fabricated by powder metallurgy with hot isostatic pressing (PM-HIP) after neutron irradiation. The data includes uniaxial tensile tests, fractography analysis, and nanoindentation. By openly sharing this valuable dataset, researchers can use the data to populate material performance databases, validate models, design experiments, and qualify PM HIP techniques for nuclear applications.

DATA IN BRIEF (2023)

Article Materials Science, Multidisciplinary

The role of Cr, P, and N solutes on the irradiated microstructure of bcc Fe

Patrick H. Warren, Caleb D. Clement, Chao Yang, Amrita Sen, Wei-Ying Chen, Yaqiao Wu, Ling Wang, Janelle P. Wharry

Summary: The objective of this study is to understand the evolution of irradiation-induced and assisted defects in binary body center cubic (bcc) Fe-based alloys. Three alloys (Fe9.5%Cr, Fe-4.5%P, and Fe-2.3%N) with varying solute sizes and positions were selected for investigation. The results showed that the presence of different solute species affected the development of irradiation-induced defects in the alloys, with undersized substitutional solutes (e.g., P) hindering their formation and oversized substitutional or interstitial solutes (e.g., Cr and N) potentially suppressing dislocation loop development.

JOURNAL OF NUCLEAR MATERIALS (2023)

Article Materials Science, Multidisciplinary

Role of point defects in stress-induced martensite transformations in NiTi shape memory alloys: A molecular dynamics study

Chao Yang, Janelle P. Wharry

Summary: The effect of vacancies, interstitials, and antisite defects on stress-induced phase transformation in equiatomic NiTi alloy was investigated using molecular dynamics simulation. The results show that all defects suppress the transformation, with vacancy clusters having the greatest suppressive effect and antisite defects having the least. The responsible mechanisms are grain boundary pinning and chemical disordering.

PHYSICAL REVIEW B (2022)

Article Materials Science, Multidisciplinary

Crystallographic effects on transgranular chloride-induced stress corrosion crack propagation of arc welded austenitic stainless steel

Haozheng J. Qu, Fei Tao, Nianju Gu, Timothy Montoya, Jason M. Taylor, Rebecca F. Schaller, Eric Schindelholz, Janelle P. Wharry

Summary: This study investigates the influence of crystallography on transgranular chloride-induced stress corrosion cracking (TGCISCC) in arc welded 304L austenitic stainless steel. The crack propagation can be explained by mechanical arguments, and the competition between mechanical, crystallographic, and corrosion factors is discussed in relation to crack behavior at grain boundaries.

NPJ MATERIALS DEGRADATION (2022)

Article Materials Science, Multidisciplinary

H dissolution and desorption near He-V complexes in W surfaces with different orientations

Liuming Wei, Jingwen Li, Yonggang Li, Qirong Zheng, Fan Cheng, Chuanguo Zhang, Jingyu Li, Gaofeng Zhao, Zhi Zeng

Summary: This study investigates the influence of He-V complexes on H behaviors on different W surfaces using DFT calculations. The results show that H dissolution is most difficult but H trapping is easiest on the W (110) surface, while the opposite is true on the W (111) surface. Moreover, the presence of He-V complexes increases the difficulty of H diffusion from bulk to surface and desorption.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Effect of deposition parameters on characteristics and oxidation behavior of magnetron sputtered Cr coatings

Yan Meng, Song Zeng, Chen Chen, Chaowen Zhu, Huahai Shen, Xiaosong Zhou, Xiaochun Han

Summary: The characteristics of magnetron sputtered Cr coatings vary with different temperature, bias voltage, and pressure. Coatings with random orientation, good crystallinity, and small grain size exhibit favorable oxidation behavior, while coatings with strong (200) texture, poor crystallinity, and large grains have many intrinsic defects that are detrimental to the protection property of the Cr coatings.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Automated analysis of grain morphology in TEM images using convolutional neural network with CHAC algorithm

Xinyuan Xu, Zefeng Yu, Wei-Ying Chen, Aiping Chen, Arthur Motta, Xing Wang

Summary: This study presents an automated approach for characterizing grain morphology in TEM images recorded during ion irradiation. By combining a machine learning model and a computer vision algorithm, comparable results to human analysis can be achieved with significantly reduced analysis time. Researchers can train their own models following the procedures described in this study to automate grain morphology analysis of their own TEM images.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Model development for oxidation and degradation behavior of accident tolerant Cr coating on Zr alloy cladding under high temperature steam atmosphere

Shihao Wu, Dong Wang, Yapei Zhang, Koji Okamoto, Marco Pellegrini, Wenxi Tian, Suizheng Qiu, G. H. Su

Summary: The oxidation and degradation mechanisms of Cr coating on Zr alloy cladding under high temperature steam atmosphere are summarized, and a mathematical analysis model is established to predict the changes in coating thickness. The model is applied in the analysis of structure evolution under different conditions.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Numerical and experimental development of cupronickel filler brazed joints for divertor and first wall components in DEMO fusion reactor

V. Diaz-Mena, J. de Prado, M. Roldan, I. Izaguirre, M. Sanchez, M. Rieth, A. Urena

Summary: The brazeability of a cupronickel alloy was evaluated as a filler alloy for high-temperature joining of tungsten to steel. The study investigated the brazing conditions and the impact of the selected filler on the joint quality using numerical software. The results showed different metallurgical interactions and diffusion phenomena between the filler alloy and the base materials at different temperatures. The study emphasized the importance of selecting a suitable filler to mitigate residual stresses in the joints.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Defect-specific strength factors and superposition model for predicting strengthening of ion irradiated Fe18Cr alloy

Pengcheng Zhu, Yajie Zhao, Yan-Ru Lin, Jean Henry, Steven J. Zinkle

Summary: This study investigates the effect of heavy-ion irradiation on radiation hardening in high-purity binary alloy Fe18Cr. Nanoindentation testing and high-quality TEM imaging were conducted to extract hardness and microstructure information. The strength factor was accurately calculated based on the detailed TEM characterization of irradiated microstructures, and a refined hardening superposition method was applied to quantify the mechanical properties of ion-irradiated materials.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Synthesis and characterization of sodium-aluminophosphate based glass-ceramics containing NZP phase for HLW immobilization

Bin Wu, Haixia Ning, Hanzhen Zhu, Jianjun Chen, Kang Wang, Daiyu Zhang, Fu Wang, Qilong Liao

Summary: This study discusses the effects of ZrO2 and B2O3 on the phase composition and properties of SAP-based glass-ceramics. The results show that ZrO2 addition improves the formation of NZP phase while restricting the crystallization of AlPO4 phases. The correct ratios of ZrO2 and B2O3 allow only the formation of NZP phase within the SAP glass.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

High temperature oxidation of cold spray Cr-coated accident tolerant zirconium-alloy cladding with Nb diffusion barrier layer

Hwasung Yeom, Greg Johnson, Benjamin Maier, Tyler Dabney, Kumar Sridharan

Summary: Cr-Nb bilayer coatings were developed using cold spray deposition to improve the limiting operational temperature of Cr-coated Zr-alloy system. The coatings exhibited outstanding oxidation resistance at high temperatures and formed continuous intermetallic compound layers at the interfaces.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Irradiation creep measurement and microstructural analysis of chromium nitride-coated zirconium alloy using pressurized tubes

Padhraic L. Mulligan, Andrew T. Nelson, Chad M. Parish, Patrick A. Champlin, Xiang Chen, Daniel Morrall, Jason M. Harp

Summary: Environmental barrier coatings are being developed to reduce oxidation and embrittlement in Zr-based materials. Chromium nitride is a candidate for this application, but understanding its impact on irradiation-induced creep and microstructure is critical.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Determination of impurity distribution in IG-11/110 nuclear graphite using TOF-SIMS

Dexuan Yan, Xinlei Cao, Ke Shen

Summary: This study investigated the purification mechanism of polycrystalline graphite by comparing IG-11 graphite with IG-110 nuclear grade graphite. The analysis revealed that metallic impurities in IG-11 were primarily segregated within graphite porosities, while IG-110 demonstrated a significant reduction in impurities. This research contributes to the development of innovative graphite purification techniques for greater purity and stronger oxidation resistance.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Study of multi-pebble oxidation process in high-temperature gas-cooled reactor

Wei Xu, Wei Peng, Lei Shi, Qi Sun

Summary: This paper investigates the oxidation and shape evolution of matrix graphite in high temperature gas-cooled reactors during air-ingress accidents. A reaction kinetics model is established and computational fluid dynamics with a dynamic mesh method is used to simulate the oxidation process. The results show that the geometric shape of graphite changes significantly with increasing flow rate, and the graphite pebbles tend to form a structure with a narrow front and wide tail.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Synthesis and characterization of super occluded LiCl-KCl in zeolite-4A as a chloride salt waste form intermediate

Allison Harward, Casey Elliott, Michael Shaltry, Krista Carlson, Tae-Sic Yoo, Guy Fredrickson, Michael Patterson, Michael F. Simpson

Summary: This paper investigates the hygroscopic properties of eutectic LiCl-KCl absorbed into zeolite-4A. The study finds that water absorption and corrosion worsen with increasing salt loading. It also suggests that the salt can be stored in a non-inert atmosphere for a certain period of time.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Hermeticity of SiC/SiC composite and monolithic SiC tubes irradiated under radial high-heat flux

Takaaki Koyanagi, Xunxiang Hu, Christian M. Petrie, Gyanender Singh, Caen Ang, Christian P. Deck, Weon-Ju Kim, Daejong Kim, James Braun, Yutai Katoh

Summary: This study provides critical experimental data on the effects of irradiation on the hermeticity of SiC composite cladding, finding that irradiation can cause a decrease in hermeticity and cracking, and coating the outer surface can mitigate the cracking issue.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Theoretical estimation of multiple hydrogen isotope content in metal layers slowly co-deposited from plasmas

S. Krat, A. Prishvitsyn, Yu. Gasparyan

Summary: This study proposes a probabilistic and diffusion-based model to describe the co-deposition of multiple hydrogen isotopes with slowly grown metal layers. The model calculates the relative concentrations of different hydrogen isotopes in the co-deposited metal layers. It is found that if hydrogen isotopes have different detrapping energies, only the isotope with the highest detrapping energy shows a monotonic decrease in concentration with deposition temperature. Furthermore, the study evaluates the uncertainty of tritium concentration in the co-deposited layer based on the uncertainty in detrapping energy of tritium and deuterium, predicting a >10% tritium concentration uncertainty for a 0.01 eV difference.

JOURNAL OF NUCLEAR MATERIALS (2024)

Article Materials Science, Multidisciplinary

Computational study of thermophysical properties of cerium doped UO2: Effect of oxidation states

Tijo Vazhappilly, Arup Kumar Pathak

Summary: This study investigates the effect of Ce atom substitution in UO2 on its thermophysical properties using density functional theory. The results show that the Ce substitution levels and the oxidation state of Ce/U atoms strongly influence the band structure and specific heat capacity of the UO2 lattice. These findings provide important insights into the fuel properties of UO2 under reactor conditions.

JOURNAL OF NUCLEAR MATERIALS (2024)