Stereoselective reaction of 2-carboxythioesters-1,3-dithiane with nitroalkenes: an organocatalytic strategy for the asymmetric addition of a glyoxylate anion equivalent

Palladium-Catalyzed Acetylation of Arenes

(2014) Stephen D. Ramgren et al.   ORGANIC LETTERS

Methylsulfinyl (Dimsyl) Anion as Umpolung Catalyst for the Chemoselective Cross-Benzoin Reaction of α-Diketones with Aldehydes

(2013) Olga Bortolini et al.   ADVANCED SYNTHESIS & CATALYSIS

Bis(amino)cyclopropenylidenes as Organocatalysts for Acyl Anion and Extended Umpolung Reactions

(2013) Myron M. D. Wilde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cinchonine and thiourea

(2013) Yumeng Xi et al.   CHEMICAL COMMUNICATIONS

Acyl anion free N-heterocyclic carbene organocatalysis

(2013) Sarah J. Ryan et al.   CHEMICAL SOCIETY REVIEWS

Dual Organocatalytic Activation of Isatins and Formaldehydetert-Butyl Hydrazone: Asymmetric Synthesis of Functionalized 3-Hydroxy-2-oxindoles

(2013) David Monge et al.   CHEMISTRY-A EUROPEAN JOURNAL

Squaramide-Catalyzed Enantioselective Michael Addition of Masked Acyl Cyanides to Substituted Enones

(2013) Kin S. Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional primary amine-thioureas in asymmetric organocatalysis

(2013) Olga V. Serdyuk et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Conjugate Addition of Acyl Anion Equivalents Promoted by Fluorodesilylation

(2013) Scott E. Denmark et al.   ORGANIC LETTERS

Exploiting Acyl and Enol Azolium Intermediates via N-Hetero- cyclic Carbene-Catalyzed Reactions of α-Reducible Aldehydes

(2012) Harit U. Vora et al.   ADVANCED SYNTHESIS & CATALYSIS

Facile Access to Chiral Ketones through Metal-Free Oxidative CC Bond Cleavage of Aldehydes by O2

(2012) Bhoopendra Tiwari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

(2012) Xavier Bugaut et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Conjugate Addition of Donor–Acceptor Hydrazones to α,β-Unsaturated Aldehydes through Formal Diaza–Ene Reaction: Access to 1,4-Dicarbonyl Compounds

(2012) Maitane Fernández et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of α-Oxy Amides via Umpolung Amide Synthesis

(2012) Matthew W. Leighty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent: Stereospecific Construction of Acyclic Quaternary Carbon Stereogenic Centers

(2012) P. Andrew Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Formal Carbonyl-Ene Reactions of Formaldehyde tert-Butyl Hydrazone with α-Keto Esters: Dual Activation by Bis-urea Catalysts

(2012) Ana Crespo-Peña et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of α-Stereogenic γ-Keto Esters via Formal Umpolung

(2012) G. K. Surya Prakash et al.   ORGANIC LETTERS

Readily available (S)-proline-derived organocatalysts for the Lewis acid-mediated Lewis base-catalyzed stereoselective aldol reactions of activated thioesters

(2012) Martina Bonsignore et al.   TETRAHEDRON

Organocatalytic Stereoselective Direct Aldol Reaction of Trifluoroethyl Thioesters

(2011) Sergio Rossi et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Enantioselective Formal Conjugate Addition of a Hydroxymoyl Anion to α,β-Unsaturated Aldehydes

(2011) Beatriz Alonso et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of α-Keto Esters via Cu(II)-Catalyzed Aerobic Deacylation of Acetoacetate Alkylation Products: An Unusually Simple Synthetic Equivalent to the Glyoxylate Anion Synthon

(2011) Kimberly M. Steward et al.   ORGANIC LETTERS

Highly stereoselective catalytic conjugate addition of acyl anion equivalent to nitroolefins

(2011) Daisuke Uraguchi et al.   Chemical Science

Photocontrollable Analyte-Responsive Fluorescent Probes: A Photocaged Copper-Responsive Fluorescence Turn-On Probe

(2010) Lin Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric organocatalytic synthesis of γ-nitrocarbonyl compounds through Michael and Domino reactions

(2010) David Roca-Lopez et al.   TETRAHEDRON-ASYMMETRY

Organocatalytic Asymmetric Aza-Michael Additions

(2009) Dieter Enders et al.   CHEMISTRY-A EUROPEAN JOURNAL

Towards Organocatalytic Polyketide Synthases with Diverse Electrophile Scope: Trifluoroethyl Thioesters as Nucleophiles in Organocatalytic Michael Reactions and Beyond

(2008) Diego A. Alonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Asymmetric Imino Aza-enamine Reaction Catalyzed by Axially Chiral Dicarboxylic Acid: Use of ArylaldehydeN,N-Dialkylhydrazones as Acyl Anion Equivalent

(2008) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY