4.7 Article

Optimization of petroleum refinery effluent treatment in a UASB reactor using response surface methodology

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 197, Issue -, Pages 26-32

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2011.09.052

Keywords

Optimization; Petroleum refinery effluent; UASB; Biogas production; Response surface methodology

Funding

  1. National Iranian Oil Refining and Distribution Company

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An upflow anaerobic sludge blanket (UASB) bioreactor was successfully used for the treatment of petroleum refinery effluent. Before optimization, chemical oxygen demand (COD) removal was 81% at a constant organic loading rate (OLR) of 0.4 kg/m(3) d and a hydraulic retention time (HRT) of 48 h. The rate of biogas production was 559 mL/h at an HRT of 40 h and an influent COD of 1000 mg/L Response surface methodology (RSM) was applied to predict the behaviors of influent COD, upflow velocity (V-up) and HRT in the bioreactor. RSM showed that the best models for COD removal and biogas production rate were the reduced quadratic and cubic models. respectively. The optimum region, identified based on two critical responses, was an influent COD of 630 mg/L, a V-up of 0.27 m/h, and an HRT of 21.4 h. This resulted in a 76.3% COD removal efficiency and a 0.25 L biogas/L feed d biogas production rate. (C) 2011 Elsevier B.V. All rights reserved.

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