4.4 Article

Surfactant-free fabrication of α-Fe2O3 structures with flower-like morphology in aqueous solution

Journal

JOURNAL OF CRYSTAL GROWTH
Volume 311, Issue 1, Pages 147-151

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2008.10.053

Keywords

Nanostructures; Crystal morphology; Growth from solutions; Semiconducting materials

Funding

  1. Chinese Academy of Sciences
  2. China Postdoctoral Science Foundation
  3. Ningbo Natural Science Foundation

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Monodisperse hematite (alpha-Fe2O3) nanostructures with flower-like morphology were obtained by a simple forced hydrolysis and thermal decomposition method without the assistance of any template or organic surfactant. The microstructure of the final flower-like particles was characterized in detail by transmission electron microscopy and selected area electron diffraction, which showed the composite structure of the particle core. Electron diffraction patterns obtained for sections located on the leaf of the particles were consistent with hematite single crystals, whereas those obtained for the middle of the particle showed additional spots, due to the presence of goethite in the particle core. Fourier transform infrared spectroscopy and X-ray diffraction also confirmed the presence of goethite phase in the particle. A mechanism based on nucleation-aggregation-recrystallization, which speculated that the goethite precipitates first and then hematite heterogeneously nucleates on goethite particles, was proposed. (C) 2008 Elsevier B.V. All rights reserved.

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