4.7 Article

Force-dependent mobility and entropic rectification in tubes of periodically varying geometry

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 136, Issue 21, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.4726193

Keywords

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Funding

  1. National Institutes of Health (NIH), Center for Information Technology
  2. Eunice Kennedy Shriver National Institute of Child Health and Human Development
  3. Russian Foundation for Basic Research [10-03-00393]

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We investigate transport of point Brownian particles in a tube formed by identical periodic compartments of varying diameter, focusing on the effects due to the compartment asymmetry. The paper contains two parts. First, we study the force-dependent mobility of the particle. The mobility is a symmetric non-monotonic function of the driving force, F, when the compartment is symmetric. Compartment asymmetry gives rise to an asymmetric force-dependent mobility, which remains non-monotonic when the compartment asymmetry is not too high. The F-dependence of the mobility becomes monotonic in tubes formed by highly asymmetric compartments. The transition of the F-dependence of the mobility from non-monotonic to monotonic behavior results in important consequences for the particle motion under the action of a time-periodic force with zero mean, which are discussed in the second part of the paper: In a tube formed by moderately asymmetric compartments, the particle under the action of such a force moves with an effective drift velocity that vanishes at small and large values of the force amplitude having a maximum in between. In a tube formed by highly asymmetric compartments, the effective drift velocity monotonically increases with the amplitude of the driving force and becomes unboundedly large as the amplitude tends to infinity. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4726193]

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