Article
Chemistry, Physical
Rishabh Kumar Pandey, Korutla Srikanth, Anuj Tak, Abhishek Kumar, Tammineni Rajagopala Rao
Summary: This study focuses on the non-adiabatic effects in the photoelectron spectra of Al6N-. It performs ab initio electronic structure calculations for the first seven low-lying electronic states of Al6N- and conducts a nuclear dynamics study using time-dependent and time-independent quantum chemistry methods. A diabatic electronic representation is used to construct a model vibronic Hamiltonian and estimate the coupling parameters for the fifteen vibrational modes of Al6N-. Theoretical spectral bands are obtained using vibronic coupling theory and reduced dimensional calculations to understand the contribution of individual vibrational modes to the overall photoelectron spectra. The theoretically obtained photodetachment spectra show good agreement with the experimental spectra, indicating vibronic coupling between closely spaced spectral bands.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Xiaogu Huang, Gaoyuan Yu, Bin Quan, Jing Xu, Guomin Sun, Gaofeng Shao, Qinghua Zhang, Tengchao Guo, Jiaping Guan, Mingji Zhang, Xiaohui Zhu, Lin Gu
Summary: This study reports a design of pseudo-Jahn-Teller distortion and disordering in monoclinic birnessite-MnO2, which forms abundant self-forming interfaces and local magnetic domains. Asymmetric MnO6 octahedra are induced by the PJT distortion, resulting in increased electron spin magnetic moment in the lattice. The birnessite with PJT distortions and disordering exhibits an outstanding reflection loss value of -42.5 dB at an ultralow thickness of 1.7 mm, mainly derived from excited interfacial polarization and magnetic loss. This work demonstrates an effective approach in regulating the lattice structure of birnessite for boosting microwave absorption performance.
Article
Chemistry, Physical
Matus Mihalik, Kornel Csach, Viktor Kavecansky, Marian Mihalik
Summary: The NdMn1-xFexO2.90(5) compounds undergo first order reversible orthorhombic-orthorhombic structural phase transition from a high temperature O phase to low temperature O' phase after heat treatment in Ar. Iron shifts the transition to lower temperatures. The presence of oxygen vacancy clusters may be responsible for the stronger anomalies at the O to O' phase transition.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Review
Chemistry, Multidisciplinary
Susanta Mahapatra
Summary: Understanding the structure and dynamics of electronic excited states in molecular systems is essential for various processes, with the coupling of electronic and nuclear motion being a common feature. Pseudo-JT and pseudo-RT coupling can occur in systems with high point group symmetry and orbital degeneracy, requiring the use of quantum chemistry and quantum dynamics methods for study and analysis.
WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE
(2022)
Article
Chemistry, Physical
Swetha Erukala, Alexandra J. Feinberg, Cheol Joo Moon, Myong Yong Choi, Andrey F. Vilesov
Summary: Helium droplets are unique hosts for isolating molecular ions for spectroscopic experiments. This study shows that ion-molecule reactions in ethane are less efficient compared to ethylene, leading to the formation of weaker bound dimers and larger clusters.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Multidisciplinary Sciences
Chenyang Yu, Hai Xu, Yujiao Gong, Ruyi Chen, Zengyu Hui, Xi Zhao, Yue Sun, Qiang Chen, Jinyuan Zhou, Wenxin Ji, Gengzhi Sun, Wei Huang
Summary: This study successfully constructed fiber electrodes embedded with nanosized amorphous molybdenum trioxide featuring oxygen vacancies, demonstrating superior energy storage performance and stability.
Article
Materials Science, Multidisciplinary
Sheng Zhu, Yuechao Wang, Jinshu Zhang, Jian Sheng, Feng Yang, Meng Wang, Jiangfeng Ni, Hong Jiang, Yan Li
Summary: By studying the structure-property correlation of KxMnO2, researchers have found that the pseudocapacitive performance can be improved by tuning its structure. They have designed a K0.25MnO2 material with high capacitance and desirable rate capability. Operando Raman spectroscopy confirms that the structural evolution of [MnO6] octahedron is responsible for its superior pseudocapacitive behavior.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Multidisciplinary Sciences
Enrico Ridente, Diptarka Hait, Eric A. Haugen, Andrew D. Ross, Daniel M. Neumark, Martin Head-Gordon, Stephen R. Leone
Summary: Understanding the relaxation pathways of photoexcited molecules is crucial for gaining atomistic-level insight into photochemistry. In this study, the geometric relaxation (Jahn-Teller distortion) of the methane cation was investigated using time-resolved attosecond transient absorption spectroscopy. The results revealed that the distortion occurred within a few femtoseconds after strong-field ionization of methane. Coherent oscillations in the vibrational mode of the symmetry-broken cation were activated and detected in the x-ray signal, but damped within a few tens of femtoseconds. This study provides a comprehensive understanding of the molecular relaxation dynamics and has implications for studying complex systems.
Article
Chemistry, Multidisciplinary
Shan-Nan Du, Dan Su, Ze-Yu Ruan, Ying-Qian Zhou, Wei Deng, Wei-Xiong Zhang, Young Sun, Jun-Liang Liu, Ming-Liang Tong
Summary: Introducing magnetic switchability into artificial molecular machines allows for precise control of magnetism via external stimuli. A field-induced Co-II single-molecule magnet was found to exhibit reversible Jahn-Teller distortion and thermal conformational motion, leading to a single-crystal-to-single-crystal phase transition. Additionally, ON/OFF negative magnetodielectric effects were observed in the high-/low-temperature phase, indicating stronger spin-lattice interaction in the high-temperature phase.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Min Li, Lin Zhang, Mingyue Wang, Xiaojing Meng, Penghui Shao, Liming Yang, Chun Zhao, Nianshou Cheng, Haichao Wang
Summary: A novel amidoxime nanofiber (AO-Nanofiber) with p-t conjugated structure was fabricated and used to capture cupric tartrate (Cu-TA). The adsorption capacity of Cu-TA by AO-Nanofiber was 198.4 mg/g at an equilibrium time of 40 min, and remained stable after 10 adsorption-desorption cycles. The capture mechanism of Cu-TA by AO-Nanofiber was validated through experiments and characterization techniques.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Li Wang, Ben Ma, Yiran Teng, Wansheng Ruan, Gangya Cheng, Xinyu Zhang, Zhihui Li, Zhian Li, Chengyue Han, Alex Ibhadon, Fei Teng
Summary: Compared with traditional the Haber-Bosch process, photocatalytic ammonia production has attracted attention due to its advantages of low energy consumption and sustainability. This study focuses on the photocatalytic nitrogen reduction reaction (NRR) on MoO3.0.55H2O and α-MoO3. Structure analysis shows that MoO3.0.55H2O has distorted octahedrons, leading to the formation of Lewis acid active sites that favors N2 adsorption and activation. XPS confirms the formation of more Mo5+ as Lewis acid active sites in MoO3.0.55H2O. MoO3.0.55H2O exhibits higher charge separation and transfer efficiency, and thermodynamically favored N2 adsorption. Under visible light irradiation, MoO3.0.55H2O achieves a higher ammonia production rate compared to α-MoO3.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Yan Wan, Jinlong Jiao, Gaoting Lin, Yan Wu, Xiaoming Wang, Ranran Zhang, Qiyang Sun, Wei Tong, Guohua Wang, Qingyong Ren, Jinfeng Zhu, Binru Zhao, Meng Zhang, Minnan Chen, Jonas Weissenrieder, Xin Yao, Jie Ma
Summary: The orbital effect on the anomalous magnetism and evolution of single crystals with low La doping has been studied. It is found that substituting Y3+ by La3+ increases the degeneracy of the yz/zx orbitals and decreases the Jahn-Teller distortion, weakening the G-type orbital ordering phase. Furthermore, the substituting decreases the magnetism entropy, indicating the shrinking of the t2g and eg orbital hybridization, destabilizing the C-type antiferromagnetic ordering phase.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Jingbai Li, Steven A. Lopez
Summary: This study uses machine-learning-accelerated photodynamics simulations to investigate the structural information and reaction outcomes of a series of fluorobenzenes. The research provides insights into the effects of pseudo Jahn-Teller distortions on the excited-state lifetimes of fluorobenzenes.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Yu-Ning Wei, Xian-Gang Hu, Jian-Wei Zhang, Bo Tong, Jin-Hong Du, Chang Liu, Dong-Ming Sun, Chi Liu
Summary: Germanium (Ge)-based devices, a promising next-generation technology, face the challenge of Fermi-level pinning (FLP) at the metal/n-Ge interface, resulting in large contact resistance. In this study, carbon nanotube (CNT) insertion method is used to alleviate FLP and achieve ohmic contact and minimum contact resistance between metal and lightly doped n-Ge.
Article
Biochemistry & Molecular Biology
Artem L. L. Khoroshilov, Kirill M. M. Krasikov, Andrey N. N. Azarevich, Alexey V. V. Bogach, Vladimir V. V. Glushkov, Vladimir N. N. Krasnorussky, Valery V. V. Voronov, Natalya Y. Y. Shitsevalova, Volodymyr B. B. Filipov, Slavomir Gabani, Karol Flachbart, Nikolay E. E. Sluchanko
Summary: The charge transport in the paramagnetic phase of Ho0.8Lu0.2B12 was studied, revealing the existence of an anomalous Hall effect due to the instability of the fcc lattice and the electronic structure. The Hall effect was observed in four mono-domain single crystals of Ho0.8Lu0.2B12 with different crystal axis orientations. An intrinsic anisotropic positive Hall resistivity was found at low temperatures, along with a negative Hall resistivity at high magnetic fields. The anomalies in the resistivity tensor components were explained as the formation of fluctuating charge chains in the structure, with intrinsic and extrinsic mechanisms contributing to the Hall effect. Additionally, a ferromagnetic contribution from magnetic polarization of 5d states was observed in the Hall signal.
Article
Chemistry, Physical
Peter Jeszenszki, Peter R. Surjan, Agnes Szabados
JOURNAL OF CHEMICAL THEORY AND COMPUTATION
(2015)
Article
Chemistry, Physical
Peter R. Surjan, Peter Jeszenszki, Agnes Szabados
Article
Chemistry, Physical
Peter R. Nagy, Janos Koltai, Peter R. Surjan, Jeno Kurti, Agnes Szabados
JOURNAL OF PHYSICAL CHEMISTRY A
(2016)
Article
Chemistry, Physical
Zsuzsanna E. Mihalka, Agnes Szabados, Peter R. Surjan
JOURNAL OF CHEMICAL PHYSICS
(2017)
Editorial Material
Chemistry, Physical
Erkki Braendas, Agnes Szabados, Peter Surjan
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
(2014)
Article
Chemistry, Physical
Peter Jeszenszki, Vitaly Rassolov, Peter R. Surjan, Agnes Szabados
Article
Chemistry, Physical
Zsuzsanna E. Mihalka, Agnes Szabados, Peter R. Surjan
JOURNAL OF CHEMICAL PHYSICS
(2019)
Article
Chemistry, Physical
D. Foldvari Zs. Toth, P. R. Surjan, A. Szabados
JOURNAL OF CHEMICAL PHYSICS
(2019)
Article
Chemistry, Multidisciplinary
Zsuzsanna E. Mihalka, Adam Margocsy, Agnes Szabados, Peter R. Surjan
JOURNAL OF MATHEMATICAL CHEMISTRY
(2020)
Article
Chemistry, Physical
Zsuzsanna E. Mihalka, Agnes Szabados, Peter R. Surjan
Summary: This paper investigates how a half-projected spin-contaminated geminal wave function can be improved by multi-configuration perturbation theory to incorporate dynamical correlation effects.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Chemistry, Multidisciplinary
Zs E. Mihalka, M. Nooijen, A. Margocsy, A. Szabados, P. R. Surjan
Summary: The article discusses the definition of the generalized function gamma(x) for the square root of Dirac's delta and its application in quantum mechanics, noting that it is neither a traditional function nor a distribution and leads to paradoxical situations. The author seeks the help of the scientific community to resolve these paradoxes.
JOURNAL OF MATHEMATICAL CHEMISTRY
(2022)
Article
Chemistry, Physical
Peter R. Surjan, Dora Kohalmi, Agnes Szabados
Summary: This paper analyzes the partitioning introduced recently by Knowles, discussing its connections with the Adams partitioning and the Davidson-Kapuy partitioning. Davidson's partitioning is reformulated using the second quantized formalism. A relation is pointed out between the Knowles condition for the many-body perturbation theory zero order Hamiltonian and the CEPA0 equations.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Peter R. Surjan, Agnes Szabados
Summary: This paper argues that the localization diagrams, originating from off-diagonal Fockian elements, do not need to be explicitly dealt with in the Davidson-Kapuy many-body perturbation theory with localized orbitals, but can be accounted for by dressed two-electron integrals.
JOURNAL OF CHEMICAL THEORY AND COMPUTATION
(2022)
Article
Chemistry, Physical
A. Szabados, A. Margocsy, P. R. Surjan
Summary: This article introduces multiconfiguration perturbation theory (MCPT), a framework for correcting the reference function of arbitrary structures. By using an overcomplete set of projected determinants, the pivot dependence of MCPT can be eliminated. This approach allows for handling overlap without numerical procedures and constructing Moore-Penrose inverse of singular matrices.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Optics
Zsuzsanna E. Mihalka, Peter R. Surjan