4.7 Article

Electric field of Ions in solution probed by hyper-Rayleigh scattering

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 130, Issue 11, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3089882

Keywords

diffusion; dissolving; electric fields; fluctuations; heavy water; liquid structure; potassium compounds; Rayleigh scattering

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The electric field of dissolved ions accounts for the narrow spike at zero frequency shift, with the polarization signature of a polar longitudinal collective mode, in the high resolution hyper-Rayleigh light scattering (HRS) spectrum for liquid water and other polar solvents. This peak in the HRS spectrum probes both the structure factor and the fluctuation time for the ion charge density in solution. The experimental results for KCl-D2O solutions are consistent with the Debye-Huckel charge structure factor and determine the diffusion coefficient and static local field factor.

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