4.7 Article

Investigation of structural and magnetic properties of nanocrystalline Ni0.3Zn0.7Fe2O4 prepared by high energy ball milling

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 480, Issue 2, Pages 737-740

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.02.042

Keywords

Nanostructured materials; Magnetically ordered materials; Mechanical alloying; Spin dynamics

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High energy ball milling was used to produce nanocrystalline Ni0.3Zn0.7Fe2O4 ferrite from stoichiometric mixture of ZnO, NiO, Fe2O3 powders. The structural, chemical and magnetic properties of Ni-Zn ferrite was determined by X-ray powder diffractometry, (XRD), scanning electron microscopy (SEM), Fourier transmission infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM) and ac susceptometer measurements. The mechanism of formation this ferrite was appeared to engage two steps: diffusion of ZnO in Fe2O3 and formation of Zn ferrite followed by diffusion of NiO in Zn ferrite and formation of Ni-Zn ferrite. The crystallite size of final product after 60 h ball milling was estimated to be about 18 mm which increased to 30 nm after annealing at 800 degrees C for 4 h. The VSM results indicated that the magnetization did not saturate and coercivity and remanence were zero. The dynamic properties of 60 h ball milled sample were investigated by ac susceptibility using the Neel-Brown, Vogel-Fulcher and power laws for superparamagnetism/spin glass. The frequency-dependence of blocking temperature can be well described by the Vogel-Fulcher law, and fitting the experimental data with Neel-Brown model and power law give unphysical value for relaxation time. (C) 2009 Published by Elsevier B.V.

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