Article
Materials Science, Multidisciplinary
Alaa M. Abd-Elnaiem, Rashed M. Hassan
Summary: The sheet resistance and electrical resistivity of As30Te60Ga10 films were measured at different thicknesses, with crystallization kinetics parameters determined for optimization of phase-change memory applications. The Sestak-Berggren equation was found to be more suitable for describing the kinetics of crystallization in As30Te60Ga10, providing an experimental basis for further studies in phase-change materials.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2021)
Article
Chemistry, Physical
Parisa Rezaei-Shahreza, Saeed Hasani, Amir Seifoddini, Marcin Nabialek, Pawel Czaja, Agata Sliwa
Summary: The non-isothermal thermal behavior of Fe74B20Nb2Hf2Si2 bulk metallic glass was investigated using various thermal analytical methods. The results revealed strong viscosity behavior in the supercooled region due to high kinetic fragility and low fragility parameter. The crystallization process was found to be controlled by the interface and resulted in the formation of Fe23B6, α-Fe, Fe2(Hf, Nb), and Fe2B phases. The growth dimensions during different crystallization stages were related to the complex structure of the main phase and the heterogeneous nucleation.
Article
Materials Science, Multidisciplinary
Evgeny Zhuravlev, Benjamin Milkereit, Bin Yang, Steffen Heiland, Pascal Vieth, Markus Voigt, Mirko Schaper, Guido Grundmeier, Christoph Schick, Olaf Kessler
Summary: This study focuses on the application of additive manufacturing, specifically Laser Powder Bed Fusion, in AlZnMgCu alloys. By analyzing the effects of powder modification methods on LPBF suitability, it is found that reducing undercooling can lead to crack-free LPBF manufacturing of alloys prone to hot cracking.
MATERIALS & DESIGN
(2021)
Article
Pharmacology & Pharmacy
Marcin Skotnicki, Agata Drogon, Janina Lulek, Marek Pyda
Summary: The process of isothermal and non-isothermal physical ageing of amorphous polylactide (PLA) with the active pharmaceutical ingredient, indapamide (IND), was investigated. The PLA-IND system exhibited two glass transitions corresponding to the Tg of PLA and IND, indicating a lack of molecular mixing between the two ingredients. Physical ageing of the PLA-IND system at different temperatures showed that the highest effect was observed at 85 degrees C. The relaxation enthalpies were fitted to the KWW equation to estimate the relaxation time and parameter describing the distribution of relaxation times. The activation energy and fragility parameters of the PLA-IND system were also determined.
Article
Polymer Science
Miroslav Huskic, Dragan Kusic, Irena Pulko, Blaz Nardin
Summary: The processing of polymers and polymeric materials leads to residual stresses in the final product, which significantly affect the mechanical properties. Experimental results show that residual stresses can be removed by heating, and they have a strong influence on the mechanical properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Chemistry, Applied
Ivano Maule, Gabriele Razzetti, Alessandro Restelli, Alessandro Palmieri, Cinzia Colombo, Roberto Ballini
Summary: The thermal stability of a set of aliphatic nitroalkanes was tested by DSC analysis, showing similar exothermic decomposition phenomenon for all compounds. Recommendations for avoiding decomposition were provided based on the estimated maximum process temperature.
ORGANIC PROCESS RESEARCH & DEVELOPMENT
(2021)
Article
Environmental Sciences
Mauricio Rodriguez Chialanza, Sofia Favre Samarra, Andres Perez Parada
Summary: The study found that the size of microplastic particles affects the DSC signal, but through appropriate sample preparation, signals corresponding to microplastics of different sizes can be identified and quantified. Additionally, the application of DSC technique in the field of microplastics may provide estimates of the number of microplastic particles within a sample.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Medicine, Research & Experimental
Yuying Pang, Asma Buanz, Simon Gaisford, Oxana Magdysyuk, Gareth R. Williams
Summary: This study investigates the crystallization and polymorphic phase transitions of FFA-polymer amorphous solid dispersions using synchrotron X-ray powder diffraction and differential scanning calorimetry. The results show that polymers can stabilize the crystalline form of FFA by inhibiting the transition process. Increasing the polymer content further inhibits polymorphic transitions.
MOLECULAR PHARMACEUTICS
(2022)
Article
Polymer Science
Yasuhito Suzuki, Takahito Kano, Tsuyoshi Tomii, Nagisa Tsuji, Akikazu Matsumoto
Summary: The physical properties of polymers are significantly affected by relaxation processes. In this study, the two relaxations of fumarate-containing polymers were investigated using DSC, solid-state NMR, and X-ray scattering. Even in copolymers, the two relaxations were observed. Tensile tests showed brittleness of PDEF at specific temperatures and structural anisotropy when extended at alpha relaxation temperature.
Article
Materials Science, Multidisciplinary
Rosa Maria Sales da Silveira, Alessandra Vieira Guimaraes, Clarissa Hadad de Melo, Rafaella Martins Ribeiro, Alexandre Bellegard Farina, Loic Malet, Luiz Henrique de Almeida, Leonardo Sales Araujo
Summary: The nickel-base alloy 718 is widely used due to its superior performance at high temperatures, and its properties can be further improved by controlled additions of alloying elements such as yttrium.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Construction & Building Technology
Panos Apostolidis, Michael Elwardany, Adrian Andriescu, David J. Mensching, Jack Youtcheff
Summary: The contribution of thermodynamics of mixing to glass transition in polymer-modified asphalt binders was studied quantitatively using a differential scanning calorimeter with an epoxy system. The miscibility of the binders was determined by measuring the heat capacity (Cp) and glass transition temperature (Tg) based on entropic changes. The enthalpy of mixing was also examined to ensure complete crosslinking of the binders. The results showed that the positive deviations of Tg from the ideal mixing rule indicated the presence of repulsive forces between the asphalt and epoxy components.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Polymer Science
Yoshitomo Furushima, Akihiko Toda, Masaru Nakada, Nobuhiro Hirota, Hideaki Takahashi, Toshiumi Tatsuki, Satoshi Fujiwara, Kazuma Okada, Masatoshi Ohkura
Summary: The study used fast scanning calorimetry and temperature modulated FSC to analyze the enthalpy relaxation behavior of low isotacticity polypropylene amorphous phase, revealing the influence of crystallization. It was found that above the crystallization temperature, the consecutive glass transition of the rigid amorphous phase and the gradual increase in heat capacity of the mobile amorphous phase were experimentally indistinguishable.
Article
Polymer Science
Mohamed H. Darweesh, Safaa H. El-Taweel, Bernhard Stoll
Summary: The thermal and mechanical properties of binary blends of polypropylene (PP) with a statistical copolymer (VM) were investigated. The two components were found to be miscible in the melt. DSC testing showed that the crystallization temperature of PP decreased with increasing VM content. The measurement of viscoelastic properties revealed a three-phase model, with VM mainly located in the mobile amorphous phase and PP in the rigid amorphous phase.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Materials Science, Paper & Wood
Hefang Liu, Qiyuan Tu, Luyao Huang, Wenhua Gao, Jinsong Zeng, Bin Wang, Jinpeng Li, Jun Xu
Summary: In this study, a concentrated cellulose nanofibril (CNF) suspension was prepared from bleached hardwood kraft pulp without pretreatment. The concentration process promoted the formation of pores in the CNFs, but these pores partially collapsed and shrunk during the re-dispersion and re-concentration process.
Article
Food Science & Technology
Judith Hege, Marta Ghebremedhin, Bhagyashri L. Joshi, Christine Schreiber, Thomas A. Vilgis
Summary: Colostrum puddings are popular in India and some European countries, made by heating fresh colostrum from the first or second day of lactation and adding spices and sugar for flavor. The gel formation of colostrum is primarily caused by significantly higher concentration of various proteins, especially 13-lactoglobulin.
INTERNATIONAL JOURNAL OF GASTRONOMY AND FOOD SCIENCE
(2021)
Article
Chemistry, Physical
Erfan Rezvani Ghomi, Saied Nouri Khorasani, Mohsen Karimi Kichi, Mohammad Dinari, Shahla Ataei, Mohammad Hossein Enayati, Mohammad Sadegh Koochaki, Rasoul Esmaeely Neisiany
COLLOID AND POLYMER SCIENCE
(2020)
Article
Materials Science, Multidisciplinary
M. Imani, E. Dastanpoor, M. H. Enayati, A. K. Basak
Summary: In this study, mechanical alloying of Ni and P powders was conducted, revealing that different intermetallic compounds were formed in Ni80P20 and Ni88P12 alloys. Thermodynamic analysis showed that the intermetallic phases were the most stable phases during mechanical alloying in these alloys.
METALS AND MATERIALS INTERNATIONAL
(2021)
Article
Physics, Applied
Shuo Huang, Zhihua Dong, Wangzhong Mu, Valter Strom, Guocai Chai, Levente Vitos
APPLIED PHYSICS LETTERS
(2020)
Article
Chemistry, Physical
E. Dastanpour, M. H. Enayati, A. Masood, V Strom
Summary: This study successfully investigates the substitution of Ni for Fe in the amorphous precursor of high flux density alloys, achieving improved amorphization capability, homogenous nanocrystalline structure with excellent soft magnetic properties, and altered mechanical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
E. Dastanpour, A. Masood, M. H. Enayati, V Strom
Summary: This study demonstrates how multi-alloying Nanomet can avoid strict annealing requirements and achieve homogeneous nanocrystallization. By introducing CoCNi and CoCMo, the amorphization capability is improved, leading to a broader temperature range for a homogeneous nanocrystallization, thus relaxing the annealing requirements.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Engineering, Mechanical
Masoud Hosseini Ballam, Fathallah Karimzadeh, Mohammad Hossein Enayati, Alireza Sanati
Summary: The research used ultrasonic surface nanocrystallization treatment (USNT) to improve the surface characteristics and tribological properties of AISI 316 stainless steel, resulting in a significant reduction in friction coefficient and decreased wear.
SURFACE TOPOGRAPHY-METROLOGY AND PROPERTIES
(2021)
Article
Physics, Applied
Shuo Huang, Zhihua Dong, Esmat Dastanpour, Valter Strom, Guocai Chai, Lajos Karoly Varga, Olle Eriksson, Levente Vitos
Summary: In the investigation of the AlxCr0.2MnFe0.5Co0.3Ni0.5 high-entropy alloys, it was found that the entropy change is primarily caused by the magnetic and vibrational degrees of freedom, leading to a substantial magnetocaloric effect.
APPLIED PHYSICS LETTERS
(2021)
Article
Physics, Applied
Shuo Huang, Zhihua Dong, Wangzhong Mu, Valter Stroem, Guocai Chai, Lajos Karoly Varga, Olle Eriksson, Levente Vitos
Summary: The study focused on the ab initio-assisted design and synthesis of high-entropy alloys, with Al0.44Cr0.25MnFeCo0.05Ni0.2 alloy showing promising magnetocaloric properties near room temperature. This suggests potential applications in magnetic refrigeration systems.
APPLIED PHYSICS LETTERS
(2021)
Article
Physics, Applied
Esmat Dastanpour, Shuo Huang, Stephan Schonecker, Huahai Mao, Valter Strom, Olle Eriksson, Lajos Karoly Varga, Levente Vitos
Summary: This study investigates the effect of vanadium (V) content on the local magnetic moment and magnetic transition temperature in Al50V(x)(Cr0.33Mn0.33Co0.33)((50-x)) (x = 12.5, 6.5, 3.5, and 0.5 at.%) high-entropy alloys. Experimental investigations, as well as ab initio and thermodynamic calculations, were carried out. The results show that lower V content increases the B2 phase fraction, saturation magnetization, and Curie point. Tuning the composition and phase fractions could lead to promising high-entropy magnetic materials.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2023)
Article
Chemistry, Physical
Esmat Dastanpour, Shuo Huang, Zhihua Dong, Stephan Schonecker, Valter Strom, Olle Eriksson, Lajos Karoly Varga, Levente Vitos
Summary: We have conducted an in-depth study on the magnetic phase resulting from spinodal decomposition in the BCC phase of a CrFe-rich composition. This magnetic phase is present after casting or water quenching following annealing at 1250 degrees C for 24 h, but absent after annealing in the range of 900-1100 degrees C for 24 h. It is formed in the temperature range of approximately 450-550 degrees C and loses magnetization above 640 degrees C, due to a structural transformation into paramagnetic sigma and FCC phases.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Physics, Applied
Shuo Huang, Esmat Dastanpour, Stephan Schonecker, Valter Strom, Guocai Chai, Laszlo Ferenc Kiss, Lajos Karoly Varga, Hongyun Jin, Olle Eriksson, Levente Vitos
Summary: In this study, the magnetocaloric response of Al-Cr-Mn-Co medium-entropy alloys is explored through theoretical and experimental methods. A dual-phase system with large magnetic moment, Al50Cr19Mn19Co12, is synthesized and its structural and magnetocaloric properties are confirmed. The results show that the selected alloy exhibits a co-continuous mixture of a disordered body-centered cubic and an ordered B2 phase, with the ordered B2 phase responsible for the substantial magnetocaloric effect. The study contributes to the understanding of potential multi-component alloys in magnetocaloric applications.
APPLIED PHYSICS LETTERS
(2023)
Article
Chemistry, Multidisciplinary
B. W. Hoogendoorn, O. Karlsson, X. Xiao, A. Pandey, S. E. Mattsson, V. Strom, R. L. Andersson, Y. Li, R. T. Olsson
Summary: Cellulose nanofibers (CNFs) were used in the aqueous electrodeposition of nickel and cadmium for battery metal recycling. It was found that cadmium could be selectively extracted with a purity of over 99%, while leaving the nickel in the solution. The inclusion of CNFs in the electrolytes induced growth of dendrites, leading to increased deposition yields and enhanced recovery of cadmium.
NANOSCALE ADVANCES
(2023)