Journal
MOLECULES
Volume 20, Issue 6, Pages 10131-10140Publisher
MDPI
DOI: 10.3390/molecules200610131
Keywords
aryne; ortho-silylaryl triflate; cesium carbonate; crown ether
Funding
- Platform for Drug Discovery, Informatics, and Structural Life Science from MEXT, Japan
- JSPS KAKENHI [15H03118, 26350971]
- Azuma Medical AMP
- Dental Research Grant
- Grants-in-Aid for Scientific Research [26350971, 15H03118] Funding Source: KAKEN
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An alternative method for generating arynes from ortho-silylaryl triflates using cesium carbonate and 18-crown-6 is reported. The method was efficiently applied to a variety of reactions between several arynes and arynophiles. We also demonstrated that the efficiency of aryne generation is significantly affected by the alkali metal countercation of the carbonate.
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