An Alternative Method for Generating Arynes from ortho-Silylaryl Triflates: Activation by Cesium Carbonate in the Presence of a Crown Ether

Generation of cycloheptynes and cyclooctynes via a sulfoxide–magnesium exchange reaction of readily synthesized 2-sulfinylcycloalkenyl triflates

(2015) Suguru Yoshida et al.   CHEMICAL COMMUNICATIONS

Generation of Arynes Using Trimethylsilylmethyl Grignard Reagent for Activation of ortho-Iodoaryl or ortho-Sulfinylaryl Triflates

(2015) Suguru Yoshida et al.   CHEMISTRY LETTERS

An efficient generation method and remarkable reactivities of 3-triflyloxybenzyne

(2014) Suguru Yoshida et al.   CHEMICAL COMMUNICATIONS

Transient Protection of Strained Alkynes from Click Reaction via Complexation with Copper

(2014) Suguru Yoshida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular synthesis of bis- and tris-1,2,3-triazoles by permutable sequential azide–aryne and azide–alkyne cycloadditions

(2014) Suguru Yoshida et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tandem [4 + 2]/[2 + 2] Cycloaddition Reactions Involving Indene or Benzofurans and Arynes

(2014) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Three-Component Coupling Reaction Triggered by Insertion of Arynes into the S═O Bond of DMSO

(2014) Feng-Lei Liu et al.   ORGANIC LETTERS

Boron-Selective Biaryl Coupling Approach to Versatile Dibenzoxaborins and Application to Concise Synthesis of Defucogilvocarcin M

(2014) Yuto Sumida et al.   ORGANIC LETTERS

Transition-Metal-Free C–S Bond Formation: A Facile Access to Aryl Sulfones from Sodium Sulfinates via Arynes

(2014) Virat G. Pandya et al.   ORGANIC LETTERS

Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes

(2013) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Hot, Energized” Benzyne

(2013) Reinhard W. Hoffmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem thia-Fries rearrangement – cyclisation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate benzyne precursors

(2013) Catherine Hall et al.   CHEMICAL COMMUNICATIONS

Synthesis of Diverse Aromatic Oxophosphorus Compounds by the Michaelis–Arbuzov-type Reaction of Arynes

(2013) Suguru Yoshida et al.   CHEMISTRY LETTERS

Generation of Arynes Triggered by Sulfoxide–Metal Exchange Reaction of ortho-Sulfinylaryl Triflates

(2013) Suguru Yoshida et al.   CHEMISTRY LETTERS

Generation of Arynes via Ate Complexes of Arylboronic Esters with an ortho-Leaving Group

(2013) Yuto Sumida et al.   ORGANIC LETTERS

Addition of Cyclic Ureas and 1-Methyl-2-oxazolidone to Pyridynes: A New Approach to Pyridodiazepines, Pyridodiazocines, and Pyridooxazepines

(2013) Nozomi Saito et al.   ORGANIC LETTERS

Arynes and Cyclohexyne in Natural Product Synthesis

(2012) Christian M. Gampe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons

(2012) Hiroto Yoshida et al.   HETEROCYCLES

Regioselective reactions of 3,4-pyridynes enabled by the aryne distortion model

(2012) Adam E. Goetz et al.   Nature Chemistry

Use of benzynes for the synthesis of heterocycles

(2012) Anton V. Dubrovskiy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aryne Insertion Reactions into Carbon-Carbon σ-Bonds

(2012) Hiroto Yoshida et al.   SYNLETT

Benzannulated Bicycles by Three-Component Aryne Reactions

(2011) Kevin M. Allan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ortho-Selective Nucleophilic Addition of Primary Amines to Silylbenzynes: Synthesis of 2-Silylanilines

(2011) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Multicomponent Coupling Reaction Induced by Insertion of Arynes into the CO Bond of Formamide

(2011) Eito Yoshioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Domino Process for Benzyne Preparation: Dual Activation ofo-(Trimethylsilyl)phenols by Nonafluorobutanesulfonyl Fluoride

(2011) Takashi Ikawa et al.   ORGANIC LETTERS

Diversity-oriented synthesis leads to an effective class of bifunctional linchpins uniting anion relay chemistry (ARC) with benzyne reactivity

(2011) A. B. Smith et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Enhanced clickability of doubly sterically-hindered aryl azides

(2011) Suguru Yoshida et al.   Scientific Reports

Preparation and Regioselective Diels-Alder Reactions of Borylbenzynes: Synthesis of Functionalized Arylboronates

(2010) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Strain-promoted double-click reaction for chemical modification of azido-biomolecules

(2010) Isao Kii et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recyclable Heterogeneous Iron Catalyst for C−N Cross-Coupling under Ligand-Free Conditions

(2009) K. Swapna et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intramolecular Reactions of (E)-2,2-Disubstituted 1-Alkenyldimethylalanes with Aryl Triflates

(2009) Eric Fillion et al.   ORGANOMETALLICS