Article
Chemistry, Physical
Hyong June Kim, Min Jong Kil, Jemin Lee, Byung Chan Yang, Dohyun Go, Yonghyun Lim, Young-Beom Kim, Jihwan An
Summary: The study introduces a gradient cermet anode for DM-SOFCs operated at 450 degrees C using co-sputtering method, which shows higher voltage and power density, better thermal stability, and improved coking resistance compared to homogeneous anode. The combination of high triple phase boundary density and percolating ceria network in the gradient cermet anode contributes to these enhancements in cell performance.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
A. A. A. da Silva, M. C. Steil, F. N. Tabuti, R. C. Rabelo-Neto, F. B. Noronha, L. Mattos, F. C. Fonseca
Summary: Research showed that ceria dopant has a significant impact on the stability and catalytic activity of direct ethanol solid oxide fuel cells, demonstrating stability in ethanol steam reforming. The Ni/doped-ceria anodic catalytic layer can provide the steam needed for internal reforming, resulting in stable fuel cell operation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Applied
Enrico Sartoretti, Chiara Novara, Maria Cristina Paganini, Mario Chiesa, Micaela Castellino, Fabrizio Giorgis, Marco Piumetti, Samir Bensaid, Debora Fino, Nunzio Russo
Summary: Copper-ceria mixed oxides are considered promising catalysts for oxidation reactions, but their mechanistic understanding is still incomplete. In this study, pure and Cu-doped ceria samples were investigated through spectroscopic techniques, revealing the role of different copper sites and lattice defects. Cu+ species and Cu0 clusters promote CO adsorption at low temperature, while isolated Cu2+ monomers and dimers enhance lattice oxygen mobility. Changes in the structure of Cu-doped ceria occur during CO oxidation, but can be reversed and reorganized in the presence of O2. The excellent performance of Cu-doped ceria originates from the cooperation among different catalytic sites in the mixed oxide.
Article
Chemistry, Multidisciplinary
Zhaoming Xia, Yue Yin, Jun Li, Hai Xiao
Summary: Due to limited degrees of freedom, stable single-atom catalysts (SACs) often have one energetically lower structure that dominates over other high-energy metastable structures. However, our experiments with SACs anchored on CeO2 reveal that the high-energy metastable structures, although in much lower proportion than the dominant lowest-energy structure, can greatly influence catalysis due to their unique coordination environment and oxidation state. This discovery challenges the common assumption in SAC studies and calls for new developments to explore and exploit catalysis via high-energy metastable structures.
Article
Chemistry, Physical
Matthew J. Wolf, Ernst D. Larsson, Kersti Hermansson
Summary: The study shows that substitutional halogen impurities in CeO2(111) result in a halide ion and a Ce3+ ion, with the effects on oxygen chemistry depending on the identity of the halogen. Additionally, electron transfer from the Ce3+ ion leads to the adsorption of a superoxide molecule, impacting oxygen molecule adsorption.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Materials Science, Ceramics
Igor V. Zagaynov, Ivan V. Shelepin, Sergey V. Fedorov, Alexander V. Naumkin, Alexey V. Bykov, Anatoly A. Konovalov
Summary: Ceria based solid solution doped with copper, manganese, and rare earth elements were synthesized and shown to have enhanced surface area and oxygen mobility. The catalytic activity in CO oxidation was higher in samples containing neodymium compared to samarium. These materials also showed potential as solid electrolytes for intermediate temperature solid oxide fuel cells.
CERAMICS INTERNATIONAL
(2021)
Review
Chemistry, Physical
Paul Kavanagh
Summary: Fuel cells have the potential to provide sustainable clean energy, but the reliance on Pt as an electrocatalyst for half-cell reactions poses challenges. Bio-inspired molecular catalysts, made of Earth-abundant elements, are being explored as alternative electrocatalysts. Progress in this area focuses on electrodes modified with molecular catalysts and fuel cells incorporating surface-confined molecular catalysts for both anodic and cathodic reactions. Prospect and challenges of using molecular catalysts in fuel cell assemblies are discussed.
CURRENT OPINION IN ELECTROCHEMISTRY
(2021)
Article
Chemistry, Physical
Yige Wang, Chuan Jia, Zewei Lyu, Minfang Han, Junwei Wu, Zaihong Sun, Fumitada Iguchi, Keiji Yashiro, Tatsuya Kawada
Summary: The study demonstrates that dense GDC interlayers with a thickness of 1 mm can be successfully manufactured using the physical vapor deposition method. The GDC interlayer sintered at 1100 degrees C exhibits the lowest degradation rate during cell operation, attributed to its most effective inhibition of Sr diffusion.
JOURNAL OF MATERIOMICS
(2022)
Article
Chemistry, Physical
Yue Wang, Qing Shen, Yongcheng Tong, Zhongliang Zhan
Summary: Tailoring the surface chemistry of oxides is effective in adjusting their catalytic behavior. In this study, nickel-doped cerium oxide nanorods were synthesized and evaluated as anode catalysts for solid oxide fuel cells. The results show that the incorporation of nickel significantly enhances the catalytic activity, which is attributed to the presence of nanoparticles and increased surface active oxygen.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Yue Wang, Changsong Cui, Yongcheng Tong, Shiwei Wang, Ranran Peng, Chusheng Chen, Zhongliang Zhan
Summary: Ceria is an excellent oxide catalyst for breaking down H2 without noble metals, and doping with lanthanide ions can effectively regulate the catalytic activities of ceria nanorods. Among the tested compositions, Ce0.8Sm0.2O2-$ exhibits the highest catalytic activity. Surface reducibility, availability of oxygen vacancies, and bonded hydroxyls are key factors determining the catalytic performance of lanthanide-doped ceria nanorods in low-temperature solid oxide fuel cells.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Qingsong Zhang, Fanyu Zhang, Jichen Dong, Mingchao Shao, Mingliang Zhu, Dong Wang, Yunlong Guo, Jianling Zhang, Yunqi Liu
Summary: Covalent organic frameworks (COFs) are porous materials with crystallinity and topological diversity. A novel synthetic method to lock the imine bond using amino groups was developed for COFs. The nucleation process of COFs was controlled by precursor hydrolysis, and a family of two-dimensional COFs with high chemical stability and excellent performance was successfully synthesized. One of the materials (BI-COF-1) showed high photocatalytic activity.
CHEMISTRY OF MATERIALS
(2022)
Article
Energy & Fuels
Bangxin Li, John T. S. Irvine, Jiupai Ni, Chengsheng Ni
Summary: The study demonstrates that adding Ce and Ni elements in solid oxide fuel cells can improve performance under ethanol fuel, reduce coke deposition issues, making the fuel cell more stable and efficient.
Article
Chemistry, Physical
Xingyue Qi, Jiaxin Fu, Kunhong Jiang, Tao Chen, Yalin He, Jiefei Li, Jing Cao, Hang Wei, Long Huang, Haibin Chu
Summary: The use of oxygen-vacancy-riched ceria supported Pd catalyst effectively alleviates the catalyst deactivation caused by the poisoning of Pd surface. It achieves high catalytic activity and stability with 100% selectivity for glucose oxidation at room temperature.
JOURNAL OF CATALYSIS
(2022)
Article
Materials Science, Ceramics
Alexander Schwiers, Christian Lenser, Olivier Guillon, Norbert H. Menzler
Summary: The integration of doped ceria into fuel electrode-supported solid oxide cells is a difficult task due to high sintering temperatures. The interdiffusion between the layers is undesirable. In this study, we investigated the influence of different dopants (X = Y, Gd or Sm) on the interdiffusion behavior between ceria (10XDC) and yttria-stabilized zirconia (8YSZ). Despite small differences in interdiffusion behavior, the different dopants did not lead to significant changes in the cell impedance. However, the presence of NiO in the fuel electrode resulted in enhanced interdiffusion kinetics and the formation of porosity at the electrolyte interface, which negatively affected the electrode performance.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Ivan Surin, Zhenchen Tang, Julian Geiger, Suyash Damir, Henrik Eliasson, Mikhail Agrachev, Frank Krumeich, Sharon Mitchell, Vita A. Kondratenko, Evgenii V. Kondratenko, Gunnar Jeschke, Rolf Erni, Nuria Lopez, Javier Perez-Ramirez
Summary: The discovery of low-valent manganese stabilized on ceria as a stable catalyst for ammonia oxidation to nitrous oxide offers a promising solution to the high manufacturing costs and suboptimal selectivity and stability of nitrous oxide synthesis. The catalyst exhibits higher productivity than state-of-the-art alternatives and establishes a structure-performance relationship.
ADVANCED MATERIALS
(2023)
Review
Energy & Fuels
S. P. S. Badwal, S. Giddey, A. Kulkarni, J. Goel, S. Basu
Article
Electrochemistry
Adam C. Rady, Sarbjit Giddey, Aniruddha Kulkarni, Sukhvinder P. S. Badwal, Sankar Bhattacharya
ELECTROCHIMICA ACTA
(2015)
Article
Chemistry, Physical
Michael D. Dolan, Mark A. Kochanek, Christopher N. Munnings, Keith G. McLennan, David M. Viano
JOURNAL OF ALLOYS AND COMPOUNDS
(2015)
Article
Chemistry, Physical
S. Giddey, A. Kulkarni, C. Munnings, S. P. S. Badwal
JOURNAL OF POWER SOURCES
(2015)
Article
Electrochemistry
HyungKuk Ju, Sarbjit Giddey, Sukhvinder P. S. Badwal, Roger J. Mulder
ELECTROCHIMICA ACTA
(2016)
Article
Energy & Fuels
Adam C. Rady, Sarbjit Giddey, Aniruddha Kulkarni, Sukhvinder P. S. Badwal, Sankar Bhattacharya
Article
Materials Science, Multidisciplinary
Adam C. Rady, C. Munnings, Sarbjit Giddey, Sukhvinder P. S. Badwal, Sankar Bhattacharya, Aniruddha Kulkarni
JOURNAL OF MATERIALS SCIENCE
(2016)
Article
Chemistry, Physical
A. P. Kulkarni, S. Giddey, S. P. S. Badwal
JOURNAL OF PHYSICAL CHEMISTRY C
(2016)
Article
Chemistry, Multidisciplinary
S. Giddey, S. P. S. Badwal, C. Munnings, M. Dolan
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2017)
Article
Chemistry, Multidisciplinary
A. P. Kulkarni, S. Giddey, S. P. S. Badwal
JOURNAL OF CO2 UTILIZATION
(2017)
Article
Electrochemistry
Daniel Fini, Sukhvinder P. S. Badwal, Sarbjit Giddey, Aniruddha P. Kulkarni, Sankar Bhattacharya
ELECTROCHIMICA ACTA
(2018)
Article
Electrochemistry
A. Kulkarni, S. Giddey, S. P. S. Badwal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2015)
Article
Electrochemistry
HyungKuk Ju, Sarbjit Giddey, Sukhvinder P. S. Badwal
ELECTROCHIMICA ACTA
(2017)