4.7 Article Proceedings Paper

Topological instability, average electronegativity difference and glass forming ability of amorphous alloys

Journal

INTERMETALLICS
Volume 17, Issue 4, Pages 183-185

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.intermet.2008.09.013

Keywords

alloy design; glasses; metallic; rapid solidification processing

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In this paper, we report the remarkable agreement of the glass forming ability of binary alloys with a new criterion that combines the topological instability parameter (lambda) and the average electronegativity difference among the elements of an alloy, assuming both exert a synergetic effect. The best glass forming compositions for Zr-Cu and Ti-Ni systems are well predicted by this new approach. Although the new criterion needs further refinement, it is concluded that the proposed approach is a promising and simple tool to guide and reduce the tedious and labour intensive work to find good glass former compositions in metallic systems. (C) 2008 Elsevier Ltd. All rights reserved.

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