Article
Materials Science, Paper & Wood
Qianqian Wang, Simeng Liu, Honglei Chen, Jun Liu, Huan Liu, Qianqian Zhu
Summary: In this study, highly efficient and environmentally friendly carboxylated cellulose silica hybrid adsorbents were developed by combining the advantages of cellulose and silica. The surface property and chemical composition of the hybrid adsorbents were extensively characterized, and the results showed that silica particles were densely deposited on their surface. These hybrid adsorbents demonstrated a high adsorption capacity that was more than 45% higher than that of carboxylated cellulose adsorbent, thanks to their porous structure and large specific surface area. They also maintained a high MB adsorption efficiency of up to 70% even after undergoing five cycles. This research has important implications for wastewater treatments as the cellulose silica hybrid adsorbents offer sustainable and cost-effective alternatives to traditional adsorbents.
Article
Environmental Sciences
Prarabdh Jain, Kedar Sahoo, Lenin Mahiya, Harsh Ojha, Harshita Trivedi, Avanish Singh, Manoj Kumar
Summary: A low cost polyvinyl alcohol-glutaraldehyde cross-linked hydrogel beads were successfully used for color removal from model industrial effluent containing Congo Red dye, achieving a high adsorption capacity and showing good reusability. Adsorption analysis revealed a multi-layer adsorption and pseudo second order kinetics, with fixed bed experiments best explained by the Thomas mathematical model. The studies demonstrated that external and internal mass diffusion were no longer rate limiting factors in the experiments.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Chemistry, Multidisciplinary
P. Golvari, E. Nouri, N. Mohsenzadegan, M. R. Mohammadi, S. O. Martinez-Chapa
Summary: This study introduces a new strategy to improve the efficiency and reduce the fabrication cost of dye-sensitized solar cells by eliminating the multi-layer deposition of TiO2. By replacing it with mesoporous TiO2 beads with specific characteristics and doping them with lithium, the electronic properties are enhanced. The spherical beads with tailored morphology and crystal structures show outstanding light scattering and harvesting characteristics, resulting in a 40% increase in solar to electric power conversion efficiency.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Polymer Science
Hani Hussain Sait, Ahmed Hussain, Mohamed Bassyouni, Imtiaz Ali, Ramesh Kanthasamy, Bamidele Victor Ayodele, Yasser Elhenawy
Summary: The discharge of textile wastewater is a major challenge for water ecosystems. This study developed a novel activated carbon/chitosan microbead (ACMB) for dye removal from textile wastewater. The ACMB demonstrated a remarkable improvement in adsorption capacity and proved to be an effective adsorbent for the removal of direct blue 78 dye.
Article
Engineering, Chemical
Jia Xin Yap, C. P. Leo, Derek Juinn Chieh Chan, Nazlina Haiza Mohd Yasin, Mohd Shaiful Sajab
Summary: Water pollution requires sustainable materials for green treatment solutions. This study successfully extracted nanocellulose from microalgae through alkaline treatment, bleaching, and hydrolysis without TEMPO-mediated oxidation. The effects of acid concentration on nanocellulose properties were studied and the maximum yield was achieved using sulphuric acid with a concentration of 60%(v/v). The extracted microalgae nanocellulose was incorporated into carboxymethyl cellulose/sodium alginate beads, significantly increasing methylene blue adsorption capacity and achieving a high dye removal percentage.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Applied
Jong-Chan Kim, Jungkyu Kim, Jinseok Park, Jung-Kwon Oh, In-Gyu Choi, Hyo Won Kwak
Summary: The study involved the preparation of chemically modified lignin and alginate hybrid adsorbents for efficient removal of cationic dyes. The encapsulation of carboxylated lignin into alginate beads resulted in higher methylene blue removal capacity due to the introduction of carboxylated anions. The Alg/C-Lig beads exhibited a high monolayer maximum adsorption capacity and stable adsorption efficiency even after multiple adsorption/desorption cycles, making them a promising candidate for dye wastewater purification.
REACTIVE & FUNCTIONAL POLYMERS
(2021)
Article
Materials Science, Multidisciplinary
Zhen Zhang, Noureddine Abidi, Lucian Lucia
Summary: The presence of toxic dyes in water threatens environmental safety, making efficient removal of dyes from wastewater highly desired. This study successfully fabricated efficient biosorbents through a simple gelation process of sodium alginate and carboxymethyl chitosan in an acidic aqueous solution. The resulting hydrogel beads showed excellent water absorption properties, pH-responsive swelling characteristics, and high methylene blue (MB) adsorption capacity, comparable to existing lignocellulosic and alginate-based hydrogels. The adsorption mechanism was explained by strong electrostatic forces. This research provides a promising and sustainable approach to dye decontamination.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Environmental Sciences
Caroline Maria Bezerra de Araujo, Albertina Goncalves Rios, Alexandre Filipe Porfirio Ferreira, Mauricio Alves da Motta Sobrinho, Alirio Egidio Rodrigues, Marcos Gomes Ghislandi
Summary: Nano-biocomposite hydrogel samples prepared with graphene oxide and agar have demonstrated effective removal of organic components in water, particularly for cationic dyes Nile Blue A and methylene blue. The hydrogel samples showed satisfactory adsorption capacities and regenerative potential for the cationic dyes, while exhibiting limited removal for the anionic dye Acid Orange 7.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Wei Wang, Mengbo Fan, Jiaming Ni, Weijun Peng, Yijun Cao, Huiyong Li, Yukun Huang, Guixia Fan, Yunliang Zhao, Shaoxain Song
Summary: This study investigates the use of Montmorillonite nanosheet/poly(acrylamide-co-acrylic acid)/sodium alginate hydrogel beads as an adsorbent for dye effluent. The hydrogel beads demonstrate multilayer and heterogeneous adsorption of methylene blue and exhibit excellent dynamic adsorption performance compared to traditional adsorbents. These findings suggest that the hydrogel beads have great potential for practical applications in the treatment of dye effluent.
APPLIED CLAY SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Neset Erek Sen, Zeynep Mine Senol
Summary: Chitosan-diatomite composite beads (Ch-D) were synthesized and exhibited improved adsorption capacity for Allura red AC (AR) food dye through hydrogen bonding and electrostatic interactions. The Ch-D composite showed a removal rate of 98% at 25 degrees Celsius, natural pH value, and an initial AR dye concentration of 200 mg L-1. The maximum adsorption capacity was found to be 34.7 mg g-1. The interactions between functional groups on the Ch-D composite and AR dye involved pi-pi interactions, hydrogen bonds, and electrostatic interactions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Materials Science, Multidisciplinary
Sabahattin Deniz
Summary: Recently, non-toxic and cost-effective MgO particles were prepared by sol-gel technique for the removal of Reactive Red 21 dye. The Langmuir model accurately characterized the adsorption behavior, which was found to be thermodynamically spontaneous. The prepared MgO particles exhibited a high adsorption capacity for Reactive Red 21 in a wide pH range, with excellent regeneration capability.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Engineering, Environmental
Arpan Herbert, Upendra Kumar, Prashanth Janardhan
Summary: This study investigated the removal of Auramine dye using peanut shells as adsorbents, with DPS and NPS showing excellent performance. Langmuir isotherm fit better at optimum conditions with q(m) values of 96.15 mg/g for DPS and 294.12 mg/g for NPS. The preparation cost of DPS was 6873 INR per 1 kg, while for NPS it was 106.19 INR per 1 kg.
WATER ENVIRONMENT RESEARCH
(2021)
Article
Environmental Sciences
Krzysztof Kusmierek, Joanna Fronczyk, Andrzej Swiatkowski
Summary: In this study, the adsorption abilities of mineral materials, including zeolite, halloysite, chalcedonite, and Devonian sand, for the removal of Rhodamine B from water were investigated. Adsorption kinetics and equilibrium, as well as the effect of pH, were studied. The results showed that the pseudo-second-order model best fit the adsorption kinetics and the Freundlich isotherm represented the equilibrium data well. The maximum adsorption capacities of RhB were determined for each material, and pH was found to strongly influence the adsorption process.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Environmental Sciences
Shweta Rawat, Abhijit Maiti
Summary: Adsorption is the most effective method for arsenic removal, but it cannot be applied in large-scale treatment in centralized water supply systems. In this study, a low-cost laterite-derived adsorbent (LDA) was combined with cross-flow ultrafiltration (Ads-UF) to develop a strategy for remediation of arsenic-contaminated water. The effect of adsorbent particles on permeate flux was assessed, and two different hybrid configurations were considered. The results showed that flux decline was higher with Ads-UF compared to Ads-SF-UF, and the spent LDA was found to be safe for disposal.
Article
Chemistry, Multidisciplinary
Mai El-Kammah, Elsayed Elkhatib, Susana Gouveia, Claudio Cameselle, Emad Aboukila
Summary: This study proposed the development of a nanoscale adsorbent material using waste from Moringa oleifera seeds for the removal of Indigo Carmine from textile effluents. The adsorption process was found to fit the Langmuir isotherm in the equilibrium of adsorption and the power function in the kinetic behavior. The maximum adsorption capacity of the absorbent nanoparticles was significantly higher than that of the bulk Moringa oleifera seeds. The dominant mechanisms of Indigo Carmine adsorption on the nanoparticles were identified as hydrogen bonding, electrostatic interlinkage, and pi-pi interactions. The Moringa oleifera seed nanoparticles showed promise as a green and low-cost adsorbent for textile wastewaters.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2022)
Article
Biotechnology & Applied Microbiology
Aysegul Ulku Metin, Erol Alver
BIOPROCESS AND BIOSYSTEMS ENGINEERING
(2016)
Article
Chemistry, Analytical
Hakan Ciftci, Erol Alver, Filiz Celik, Aysegul U. Metin, Ugur Tamer
Article
Biotechnology & Applied Microbiology
Erol Alver, Aysegul Ulku Metin
INTERNATIONAL BIODETERIORATION & BIODEGRADATION
(2017)
Article
Spectroscopy
Erol Alver, Mehmet Bulut, Aysegul Ulku Metin, Hakan Ciftci
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2017)
Article
Engineering, Environmental
Erol Alver, Aysegul U. Metin
CHEMICAL ENGINEERING JOURNAL
(2012)
Article
Electrochemistry
Hakan Ciftci, Ugur Tamer, Aysegul U. Metin, Erol Alver, Nevin Kizir
JOURNAL OF APPLIED ELECTROCHEMISTRY
(2014)
Article
Polymer Science
Erol Alver, Aysegul U. Metin, Hakan Ciftci
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2014)
Article
Biochemical Research Methods
Ayla Demirci, Erol Alver
JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES
(2013)
Article
Biotechnology & Applied Microbiology
Mustafa Turk, Ugur Tamer, Erol Alver, Hakan Ciftci, Aysegul U. Metin, Siyami Karahan
ARTIFICIAL CELLS NANOMEDICINE AND BIOTECHNOLOGY
(2013)
Article
Biochemistry & Molecular Biology
Erol Alver, Aysegul Ulku Metin, Francois Brouers
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2020)
Article
Engineering, Multidisciplinary
Erol Alver, Aysegul Ulku Metin, Hakan Ciftci
SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI
(2015)
Review
Engineering, Multidisciplinary
Erol Alver, Ayla Demirci, Mustafa Ozcimder
SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI
(2012)