Journal
LANGMUIR
Volume 31, Issue 21, Pages 5962-5969Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.5b00516
Keywords
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Funding
- National Natural Science Foundation of China [51272070, 21031001, 20971040, 21001042, 21101060]
- Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China [708029]
- Natural Science Foundation of Heilongjiang Province of China [E201455]
- Research Fund for the Doctoral Program of Higher Education of China [20112301110002]
- Postdoctoral Science-Research Developmental Foundation of Heilongjiang Province [LBH-Q13136]
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Bi2Ti2O7-TiO2 composite nano:wire arrays were prepared via a two-step sequential solvothermal and subsequent calcination process. The, morphology and structure of the Bi2Ti2O7-TiO2 composite nanowire array composite were Characterized by X-ray diffraction, field emission scanning election microscopy, and transmission electron microscopy. The UV-visible diffuse reflectance spectroscopy analysis indicated that the absorption spectrum of the Bi2Ti2O7-TiO2 composite nanowire array composite was extended to the visible light region due to the existence of Bi2Ti2O7. The Bi2Ti2O7-TiO2 composite nanowire arrays exhibit superhydrophilicity with water,contact angles of 0 degrees after irradiation With visible, light, and the superhydrophilic nature is retained for at least 15 days. This effect enables us to consider self-cleaning applications that do not require permanent UV exposure: Compared to pure Bi2Ti2O7 and TiO2, the vertically aligned Bi2Ti2O7-TiO2 composite nanowire arrays Showed; more significant visible light self-cleaning performance due to the synergistic effect of superhydrophilicity and significant photocatalytic activity caused by effective electron hole separation at the interfaces of the two semiconductors; which was confirmed by the electrochemical analysis and surface photovoltage technique.
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