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Effect of pretreatment with an organic solution on yield and quality of bio-oil obtained from fast pyrolysis of sugarcane bagasse

PUBLISHED April 25, 2023 (DOI: https://doi.org/10.54985/peeref.2304p9074854)

NOT PEER REVIEWED

Authors

Lizet Rodríguez-Machín1 , Luis Ernesto Arteaga-Pérez2 , Pérez-Bermúdez Raúl Alberto1 , Pala Mehmet3 , Feys Jeroen3 , Nemmar Aris4 , Wolter Prins3 , Ronsse Frederik3
  1. Universidad “Marta Abreu” de Las Villas, Santa Clara, Cuba
  2. Chemical Engineering School, Department of Wood Engineering, University of Bío-Bío,Concepción, Chile
  3. Dept. of Green Chemistry and Technology, Faculty of Bioscience Engineering, UGent, Belgium
  4. Department of Process and Bioprocess Engineering, University of Nantes, France

Conference / event

33° Congreso Latinoamericano de Química (33-CLAQ) y X Congreso de Ciencias Químicas, Tecnología e Innovación (QUIMICUBA'2018), October 2018 (La Habana, Cuba)

Poster summary

Sugarcane bagasse (SCB) continue receiving attention as feedstock for producing bio-oil, particularly by fast pyrolysis. However, its relatively high inorganic content affects bio-oil yield and quality. The present study reports the effect of pretreatment with aqueous solution of citric acid (CA) on pyrolytic bio-oil yield and its characteristics. The SCB samples exhibited a reduction in ash after leaching. The pyrolysis trials at 500 °C were conducted in a continuously operated fast pyrolysis mini-plant based on auger reactor technology. As a result the yield of organics obtained from CA–leached SCB was 5 wt.% higher than that from raw SCB (38.9 wt.% on pretreatment-feedstock basis). The values of water content of raw and CA–leached SCB bio-oils were close. Hence, CA can be considered as a technically viable option as an effective leaching agent to demineralize biomasses prior to thermochemical conversion processes like fast pyrolysis.

Keywords

Fast pyrolysis, Pretreatment, Sugarcane bagasse, Citric acid, Alkali, Alkaline earth metals

Research areas

Bioengineering, Chemical Engineering, Energy Engineering, Environmental Engineering, Environmental Sciences

References

  1. A.V. Bridgwater and G.V.C. Peacocke, Renew. Sust. Energ. Rev., 4, (2000) 1-73.
  2. M. Garcia-Perez, A. Chaala, H. Pakdel, D. Kretschmer and C. Roy, Biomass Bioenergy, 31, (2007) 222-242.
  3. A. Oasmaa, D.C. Elliott and J. Korhonen, Energy Fuels, 24, (2010) 6548-6554
  4. M. Carrier, T. Hugo, J. Gorgens and H. Knoetze, J. Anal. Appl. Pyrolysis, 90, (2011) 18-26.
  5. L. Rodríguez-Machín, L.E. Arteaga-Pérez, R.A. Pérez-Bermúdez, Y. Casas-Ledón, W. Prins and F. Ronsse, Biomass Bioenergy, 108, (2018) 371-380.
  6. Rodríguez-Machín, L., Arteaga-Pérez, L. E., Vercruysse, J., Pérez-Bermúdez, R. A., Prins, W. & Ronsse, F. 2018. J. Anal. Appl. Pyrolysis, 134, 465-475.
  7. Yildiz, G., Ronsse, F., Venderbosch, R., Duren, R. V., Kersten, S. R. A. & Prins, W. 2015. Applied Catalysis B: Environmental, 168–169, 203-211.

Funding

  1. Special Research Fund” (BOF) from Ghent University (No. B/13667/01 - BOF13/DOS/022)
  2. CONICYTFONDECYT (No. 11150148)

Supplemental files

No data provided

Additional information

Competing interests
No competing interests were disclosed.
Data availability statement
The datasets generated during and / or analyzed during the current study are available from the corresponding author on reasonable request.
Creative Commons license
Copyright © 2023 Rodríguez-Machín et al. This is an open access work distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Rodríguez-Machín, L., Arteaga-Pérez, L., Raúl Alberto, P., Mehmet, P., Jeroen, F., Aris, N., Prins, W., Frederik, R. Effect of pretreatment with an organic solution on yield and quality of bio-oil obtained from fast pyrolysis of sugarcane bagasse [not peer reviewed]. Peeref 2023 (poster).
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