Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through CH Activation and Orthogonal Reactivity

Double Heteroatom Functionalization of Arenes Using Benzyne Three-Component Coupling

(2015) José-Antonio García-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct introduction of a naphthalene-1,8-diamino boryl [B(dan)] group by a Pd-catalysed selective boryl transfer reaction

(2015) Liang Xu et al.   CHEMICAL COMMUNICATIONS

Multidirectional Synthesis of Substituted Indazoles via Iridium-Catalyzed C–H Borylation

(2015) Scott A. Sadler et al.   JOURNAL OF ORGANIC CHEMISTRY

Trifluoromethanesulfonyloxy-group-directed regioselective (3 + 2) cycloadditions of benzynes for the synthesis of functionalized benzo-fused heterocycles

(2015) Takashi Ikawa et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chemoselective Boronic Ester Synthesis by Controlled Speciation

(2014) James W. B. Fyfe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Perylene to a 22-Ring Aromatic Hydrocarbon in One-Pot

(2014) Bruno Schuler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Differentiated Polyboron Arenes Prepared by Direct CH Borylation and Their Highly Selective Suzuki-Miyaura Cross-Coupling Reactions

(2014) Liang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Promoted Protodeboronation of 2,6-Disubstituted Arylboronic Acids

(2014) Jerome Lozada et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Role of Aryne Distortions, Steric Effects, and Charges in Regioselectivities of Aryne Reactions

(2014) Jose M. Medina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalyzed C–H borylation of pyridines

(2014) Scott A. Sadler et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Strain-Promoted Oxidative Annulation of Arynes and Cyclooctynes with Benzamides: Palladium-Catalyzed C–H/N–H Activation for the Synthesis of N-Heterocycles

(2014) Xianglong Peng et al.   ORGANIC LETTERS

Use of 2-Bromophenylboronic Esters as Benzyne Precursors in the Pd-Catalyzed Synthesis of Triphenylenes

(2014) José-Antonio García-López et al.   ORGANIC LETTERS

Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N-Heterocycles

(2014) María-José Oliva-Madrid et al.   ORGANOMETALLICS

Benzyne–benzyne–RNC or CO triple sequential insertion into the Pd–C bond: synthesis of ten-membered N-heterocycles through stable ten- and eleven-membered palladacycles

(2013) María-José Oliva-Madrid et al.   CHEMICAL COMMUNICATIONS

Aryne Cycloaddition Reactions in the Synthesis of Large Polycyclic Aromatic Compounds

(2013) Dolores Pérez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regiocomplementary Cycloaddition Reactions of Boryl- and Silylbenzynes with 1,3-Dipoles: Selective Synthesis of Benzo-Fused Azole Derivatives

(2013) Takashi Ikawa et al.   JOURNAL OF ORGANIC CHEMISTRY

Protodeboronation of ortho- and para-Phenol Boronic Acids and Application to ortho and meta Functionalization of Phenols Using Boronic Acids as Blocking and Directing Groups

(2013) Chun-Young Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

High-Throughput Optimization of Ir-Catalyzed C–H Borylation: A Tutorial for Practical Applications

(2013) Sean M. Preshlock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ortho-Selective nucleophilic addition of amines to 3-borylbenzynes: synthesis of multisubstituted anilines by the triple role of the boryl group

(2013) Akira Takagi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Dual Selectivity: Electrophile and Nucleophile Selective Cross-Coupling Reactions on a Single Aromatic Substrate

(2013) Annika C. J. Heinrich et al.   ORGANIC LETTERS

Addition of Cyclic Ureas and 1-Methyl-2-oxazolidone to Pyridynes: A New Approach to Pyridodiazepines, Pyridodiazocines, and Pyridooxazepines

(2013) Nozomi Saito et al.   ORGANIC LETTERS

Generation of 3-borylbenzynes, their regioselective Diels–Alder reactions, and theoretical analysis

(2013) Akira Takagi et al.   TETRAHEDRON

Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation into Functionalized Aryl Boronates

(2012) Motoki Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Organotrifluoroborate Salts: Precipitation-Driven Equilibrium under Non-Etching Conditions

(2012) Alastair J. J. Lennox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arynes and Cyclohexyne in Natural Product Synthesis

(2012) Christian M. Gampe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

Steric Effects Compete with Aryne Distortion To Control Regioselectivities of Nucleophilic Additions to 3-Silylarynes

(2012) Sarah M. Bronner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Cross-Coupling Reactions with Differentiation between Two Nucleophilic Sites on a Single Aromatic Substrate

(2012) Julian Linshoeft et al.   ORGANIC LETTERS

Iridium-catalyzed C–H borylation of quinolines and unsymmetrical 1,2-disubstituted benzenes: insights into steric and electronic effects on selectivity

(2012) Hazmi Tajuddin et al.   Chemical Science

ortho-Selective Nucleophilic Addition of Primary Amines to Silylbenzynes: Synthesis of 2-Silylanilines

(2011) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[16]Cloverphene: a Clover-Shaped cata-Condensed Nanographene with Sixteen Fused Benzene Rings

(2011) José M. Alonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Synthesis of Organoboronic Acids

(2011) Lukasz T. Pilarski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

A Method for the Deprotection of Alkylpinacolyl Boronate Esters

(2011) Jing Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Anthranilamide: A Simple, Removableortho-Directing Modifier for Arylboronic Acids Serving also as a Protecting Group in Cross-Coupling Reactions

(2011) Hideki Ihara et al.   ORGANIC LETTERS

Preparation and Regioselective Diels-Alder Reactions of Borylbenzynes: Synthesis of Functionalized Arylboronates

(2010) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

(2010) Britt A. Vanchura et al.   CHEMICAL COMMUNICATIONS

Synthetic applications of rhodium catalysed conjugate addition

(2010) Hannah J. Edwards et al.   CHEMICAL SOCIETY REVIEWS

Iridium-Catalyzed CH Activation versus DirectedorthoMetalation: Complementary Borylation of Aromatics and Heteroaromatics

(2010) Timothy E. Hurst et al.   CHEMISTRY-A EUROPEAN JOURNAL

Indolyne and Aryne Distortions and Nucleophilic Regioselectivites

(2010) Paul H.-Y. Cheong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

(2010) G-Yoon J. Im et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Reactions of Highly Substituted Arynes

(2010) Pamela M. Tadross et al.   ORGANIC LETTERS

Gold(III)-Catalyzed Halogenation of Aromatic Boronates withN-Halosuccinimides

(2010) Di Qiu et al.   ORGANIC LETTERS

Mild Silver(I)-Mediated Regioselective Iodination and Bromination of Arylboronic Acids

(2010) Raed M. Al-Zoubi et al.   ORGANIC LETTERS

“One-Pot” Tandem C−H Borylation/1,4-Conjugate Addition/Reduction Sequence

(2010) Hazmi Tajuddin et al.   ORGANIC LETTERS

Boronic acids in medicinal chemistry: anticancer, antibacterial and antiviral applications

(2010) Paul C. Trippier et al.   MedChemComm

Synthesis of Aminoboronic Acids and Their Applications in Bifunctional Catalysis

(2009) Irene Georgiou et al.   ACCOUNTS OF CHEMICAL RESEARCH

Controlled Iterative Cross-Coupling: On the Way to the Automation of Organic Synthesis

(2009) Congyang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Boronic acids as building blocks for molecular nanostructures and polymeric materials

(2009) Kay Severin   DALTON TRANSACTIONS

Easily Attachable and Detachableortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

(2009) Hideki Ihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indolynes as Electrophilic Indole Surrogates: Fundamental Reactivity and Synthetic Applications

(2009) Sarah M. Bronner et al.   ORGANIC LETTERS

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS

Benzyne Click Chemistry: Synthesis of Benzotriazoles from Benzynes and Azides

(2008) Feng Shi et al.   ORGANIC LETTERS

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS