Benzyne–benzyne–RNC or CO triple sequential insertion into the Pd–C bond: synthesis of ten-membered N-heterocycles through stable ten- and eleven-membered palladacycles

Synthesis and Reactivity of Ortho-Palladated 3-Phenylpropanamides. Insertion of CO, XyNC, and Alkynes into the Pd–C Bond. Synthesis of Seven- and Nine-Membered Palladacycles and Benzazepine- and Benzazonine-Based Heterocycles

(2013) Roberto Frutos-Pedreño et al.   ORGANOMETALLICS

Insertion of benzyne into the Pd–C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2′-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates

(2012) José-Antonio García-López et al.   CHEMICAL COMMUNICATIONS

Sequential Insertion of Alkynes and CO or Isocyanides into the Pd–C Bond of Cyclopalladated Phenylacetamides. Synthesis of Eight-Membered Palladacycles, Benzo[d]azocine-2,4(1H,3H)-diones, and Highly Functionalized Acrylonitrile and Acrylamide Derivatives

(2012) Roberto Frutos-Pedreño et al.   ORGANOMETALLICS

Ortho Palladation of the Phenethylamines of Biological Relevance l-Tyrosine Methyl Ester and Homoveratrylamine. Reactivity of the Palladacycles toward CO and Isocyanides. Synthesis of the Natural Alkaloid Corydaldine

(2012) María-José Oliva-Madrid et al.   ORGANOMETALLICS

Reactivity toward CO of Eight-Membered Palladacycles Derived from the Insertion of Alkenes into the Pd–C Bond of Cyclopalladated Primary Arylalkylamines of Pharmaceutical Interest. Synthesis of Tetrahydrobenzazocinones, Ortho-Functionalized Phenethylamines, Ureas, and an Isocyanate

(2012) José-Antonio García-López et al.   ORGANOMETALLICS

Microwave-assisted synthesis of medium-sized heterocycles

(2011) Abhishek Sharma et al.   CHEMICAL COMMUNICATIONS

A Novel Non-phenolic Dibenzazecine Derivative with Nanomolar Affinities for Dopamine Receptors

(2011) Dina Robaa et al.   CHEMISTRY & BIODIVERSITY

Chiral Indolo[3,2-f][3]benzazecine-Type Dopamine Receptor Antagonists: Synthesis and Activity of Racemic and Enantiopure Derivatives

(2011) Dina Robaa et al.   JOURNAL OF MEDICINAL CHEMISTRY

Generation of benzyne from benzoic acid using C–H activation

(2010) Alastair A. Cant et al.   CHEMICAL COMMUNICATIONS

Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†

(2010) José Vicente et al.   ORGANOMETALLICS

Synthesis of novel fused azecine ring systems through application of the tert-amino effect

(2010) Petra Dunkel et al.   TETRAHEDRON

An aza-cyclophane stacked in racemic columnar assemblies: whole-molecule disorder in a two-dimensional solid solution

(2009) Matthias Zeller et al.   ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE

Dibenzazecine scaffold rebuilding—Is the flexibility always essential for high dopamine receptor affinities?

(2009) Maria Schulze et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Palladium-Catalyzed Cocyclotrimerization of Allenes with Arynes: Selective Synthesis of Phenanthrenes

(2009) Yi-Lin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Insertion of One, Two, and Three Molecules of Alkyne into the Pd−C Bond of Ortho-palladated Primary and Secondary Arylalkylamines

(2009) José Vicente et al.   ORGANOMETALLICS

Palladium-Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines

(2008) Thibaud Gerfaud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes

(2008) Hiroto Yoshida et al.   ORGANIC LETTERS

Beckmann rearrangement of cyclotriveratrylene (CTV) oxime: tandem Beckmann-electrophilic aromatic addition

(2008) Marlon R. Lutz et al.   TETRAHEDRON LETTERS