期刊
ORGANIC LETTERS
卷 14, 期 22, 页码 5644-5647出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302571t
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资金
- Fonds der Chemischen Industrie (FCI)
- Deutsche Bundesstiftung Umwelt (DBU)
A new thiophene building block, containing both a stannyl group and a boronic ester, was prepared. From this starting material, a general, nucleophile-selective one-pot reaction was developed, exploiting the different reactivities of the Stille and Suzuki-Miyaura cross-coupling reactions. A series of aromatic electrophiles were used to demonstrate the high functional group tolerance.
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