Asymmetric Conjugate Addition of Grignard Reagents to 3-Silyl Unsaturated Esters for the Facile Preparation of Enantioenriched β-Silylcarbonyl Compounds and Allylic Silanes

Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

(2014) Suttipol Radomkit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation

(2013) Lukas B. Delvos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Tri- and α-Tetrasubstituted Allylsilanes by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Silylboronates

(2013) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(I)–NHC Catalyzed Asymmetric Silyl Transfer to Unsaturated Lactams and Amides

(2013) Vittorio Pace et al.   ORGANIC LETTERS

Asymmetric Conjugate Addition of Grignard Reagents to Pyranones

(2013) Bin Mao et al.   ORGANIC LETTERS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Reversible 1,3-anti/syn-Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes

(2012) Kazunori Nagao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Silyl Additions to α,β-Unsaturated Aldehydes Catalyzed by Combination of Transition Metal and Chiral Amine Catalysts

(2011) Ismail Ibrahem et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Conjugate Addition/Oxidative Dearomatization Towards Multifunctional Spirocyclic Compounds

(2011) Alena Rudolph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Enantio- and Diastereoselective Three-Component Coupling of 1,3-Dienes, Aldehydes, and a Silylborane Leading to α-Chiral Allylsilanes

(2011) Nozomi Saito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric conjugate addition of Grignard reagents to coumarins—synthesis of versatile chiral building blocks

(2011) Johannes F. Teichert et al.   CHEMICAL COMMUNICATIONS

Enantioselective Conjugate Addition Nitro-Mannich Reactions: Solvent Controlled Synthesis of Acyclicanti- andsyn-β-Nitroamines with Three Contiguous Stereocenters

(2011) James C. Anderson et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Asymmetric Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes via the Borylation of Lithiated Carbamates

(2011) Varinder K. Aggarwal et al.   ORGANIC LETTERS

Highly Diastereo- and Enantioselective Tandem Reaction toward Functionalized Pyrrolidines with Multiple Stereocenters

(2011) Shengmei Guo et al.   ORGANIC LETTERS

Reductive aldol cyclizations of unsaturated thioester derivatives of 1,3-cyclopentanedione catalyzed by chiral copper hydrides

(2011) Jun Ou et al.   TETRAHEDRON

Copper catalyzed tandem conjugated borylation–aldol reaction

(2011) Alexandre Welle et al.   TETRAHEDRON

Excess Phosphine Ligand Plays a Critical Role in the Asymmetric Copper(I) Iodide-Catalyzed Conjugate Addition of Grignard Reagents to α,β-Unsaturated Esters

(2010) Shun-Yi Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Diastereo- and Enantioselective Catalytic Tandem Michael Addition/Mannich Reaction: Access to Chiral Isoindolinones and Azetidines with Multiple Stereocenters

(2010) Shengmei Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective Cu(i)–Tol-BINAP-catalyzed asymmetric conjugate addition of Grignard reagents to α,β-unsaturated esters

(2010) Shun-Yi Wang et al.   CHEMICAL COMMUNICATIONS

Iterative strategies for the synthesis of deoxypropionates

(2010) Bjorn ter Horst et al.   CHEMICAL COMMUNICATIONS

Copper-Catalysed Domino Silylative Aldol Reaction Leading to Stereocontrolled Chiral Quaternary Carbons

(2010) Alexandre Welle et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones

(2010) Stefan Kehrli et al.   CHEMISTRY-A EUROPEAN JOURNAL

A General Strategy for the Introduction of Stereogenic Centers Bearing a Methyl Group: Total Synthesis of Sex Pheromones

(2010) Shun-Yi Wang et al.   Chemistry-An Asian Journal

Copper-Catalyzed Enantioselective Synthesis oftrans-1-Alkyl-2-substituted Cyclopropanes via Tandem Conjugate Addition−Intramolecular Enolate Trapping

(2010) Tim den Hartog et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzedanti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level

(2010) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters

(2010) Jack Chang Hung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective 1,4-Addition to α,β-Unsaturated Aldehydes

(2010) Laëtitia Palais et al.   ORGANIC LETTERS

Total Synthesis ofPhytophthoraMating Hormone α1

(2010) Shun-Yi Wang et al.   ORGANIC LETTERS

Copper-Catalyzed Asymmetric Michael Addition of Magnesium, Zinc, and Aluminum Organometallic Reagents: Efficient Synthesis of Chiral Molecules

(2009) Tobias Thaler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in enantioselective copper-catalyzed 1,4-addition

(2009) Thomas Jerphagnon et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Iriomoteolide-1a C13−C23 Fragment via Asymmetric Conjugate Addition and Julia−Kocienski Coupling Reaction

(2009) Yen-Jin Chin et al.   ORGANIC LETTERS

Efficient Construction of Polycyclic Derivatives via a Highly Selective CuI-Catalyzed Domino Reductive-Aldol Cyclization

(2009) Julia Deschamp et al.   ORGANIC LETTERS

Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon

(2009) Christian Walter et al.   TETRAHEDRON

Highly Efficient Copper(I) Iodide-Tolyl-BINAP-Catalyzed Asymmetric Conjugate Addition of Methylmagnesium Bromide to α,β-Unsaturated Esters

(2008) Shun-Yi Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Tandem Catalytic Asymmetric Friedel-Crafts/Henry Reaction: Control of Three Contiguous Acyclic Stereocenters

(2008) Takayoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Reformatsky Reaction with Aldehydes

(2008) M. Ángeles Fernández-Ibáñez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage

(2008) Christian Walter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Cu-Catalyzed 1,4-Addition of Grignard Reagents to Cyclohexenone Using Taddol-Derived Phosphine-Phosphite Ligands and 2-Methyl-THF as a Solvent

(2008) Tobias Robert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Me2Zn mediated, tert-butylhydroperoxide promoted, catalytic enantioselective Reformatsky reaction with aldehydes

(2008) Pier Giorgio Cozzi et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

C2Symmetric Chiral NHC Ligand for Asymmetric Quaternary Carbon Constructing Copper-Catalyzed Conjugate Addition of Grignard Reagents to 3-Substituted Cyclohexenones

(2008) Yasumasa Matsumoto et al.   JOURNAL OF ORGANIC CHEMISTRY

CuH-Catalyzed Enantioselective Intramolecular Reductive Aldol Reactions Generating Three New Contiguous Asymmetric Stereocenters

(2008) Bruce H. Lipshutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Reformatsky Reaction withortho-Substituted Diarylketones

(2008) M. Ángeles Fernández-Ibáñez et al.   ORGANIC LETTERS