期刊
ORGANIC LETTERS
卷 12, 期 22, 页码 5166-5169出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102177j
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资金
- Nanyang Technological University, Ministry of Education and Biomedical Research Council [M47110006]
Total synthesis of Phytophthora mating hormone alpha 1 (1) has been demonstrated. The required stereochemistries (methyl) are achieved by applying Cul-(S)-Tol-BINAP-catalyzed conjugate addition of Grignard reagents to alpha,beta-unsaturated esters.
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