期刊
ORGANIC LETTERS
卷 12, 期 9, 页码 1988-1991出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol100441r
关键词
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资金
- Swiss National Research Foundation [200020-126663]
- COST action D40 [C07.0097]
- University of Geneva
The first asymmetric Cu-catalyzed conjugate addition of dialkylzinc zinc reagents to a large scope of enals in presence of phosphoramidite, SimplePhos, or (R)-BINAP ligands with enantiomeric excesses up to 90% is reported. Moreover, ACA of Grignard reagents afforded moderate to good 1,4-regioselectivities with enantioselectivities up to 90%.
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