C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes

Carbene Transfer - A New Pathway for Propargylic Esters in Gold Catalysis

(2013) Tobias Lauterbach et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphates

(2013) Roohollah Kazem Shiroodi et al.   CHEMICAL SOCIETY REVIEWS

Vicinal Bisheterocyclizations of Alkynes via Nucleophilic Interception of a Catalytic Platinum Carbene

(2013) Paul A. Allegretti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,6-Carbene Transfer: Gold-Catalyzed Oxidative Diyne Cyclizations

(2013) Pascal Nösel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantiospecific Platinum-Catalyzed Cycloisomerizations: Synthesis of Enantioenriched Oxabicycloheptene Derivatives

(2013) Eric T. Newcomb et al.   ORGANIC LETTERS

Ligand Effect in Platinum-Catalyzed Cycloisomerization of 1,6-Enynes: Water or Carbon Monoxide, a Similar Role despite Distinct Electronic Properties?

(2013) Yves Gimbert et al.   ORGANOMETALLICS

Gold Vinylidene Complexes: Intermolecular C(sp3)H Insertions and Cyclopropanations Pathways

(2012) A. Stephen K. Hashmi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring Expansions Within the Gold-Catalyzed Cycloisomerization ofO-Tethered 1,6-Enynes. Application to the Synthesis of Natural-Product-like Macrocycles

(2012) Antoine Simonneau et al.   ChemCatChem

One-Point Binding Ligands for Asymmetric Gold Catalysis: Phosphoramidites with a TADDOL-Related but Acyclic Backbone

(2012) Henrik Teller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Role of Gold Acetylides as a Selectivity Trigger and the Importance of gem-Diaurated Species in the Gold-Catalyzed Hydroarylating-Aromatization of Arene-Diynes

(2012) A. Stephen K. Hashmi et al.   ORGANOMETALLICS

Platinum-catalyzed cyclizations viacarbene intermediates: syntheses of complementary positional isomers of isoxazoles

(2012) Paul A. Allegretti et al.   Chemical Science

Gold α-Oxo Carbenoids in Catalysis: Catalytic Oxygen-Atom Transfer to Alkynes

(2011) Jian Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic applications of gold-catalyzed ring expansions

(2011) David Garayalde et al.   Beilstein Journal of Organic Chemistry

Generation of α,β-Unsaturated Platinum Carbenes from Homopropargylic Alcohols: Rearrangements to Polysubstituted Furans

(2011) Paul A. Allegretti et al.   ORGANIC LETTERS

6-(3,4-Dichlorophenyl)-1-[(Methyloxy)methyl]-3-azabicyclo[4.1.0]heptane: A New Potent and Selective Triple Reuptake Inhibitor

(2010) Fabrizio Micheli et al.   JOURNAL OF MEDICINAL CHEMISTRY

Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans

(2010) Alexander S. Dudnik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped Propargylpyridines

(2010) Yuanzhi Xia et al.   ORGANIC LETTERS

Asymmetric Au(i)-catalyzed synthesis of bicyclo[4.1.0]heptene derivatives via a cycloisomerization process of 1,6-enynes

(2009) Chung-Meng Chao et al.   CHEMICAL COMMUNICATIONS

Rh(II)-Catalyzed Skeletal Reorganization of 1,6- and 1,7-Enynes through Electrophilic Activation of Alkynes

(2009) Kazusa Ota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Au(I)-Catalyzed Cycloisomerizations Terminated by sp3C−H Bond Insertion

(2009) Yoshikazu Horino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold η2-Coordination to Unsaturated and Aromatic Hydrocarbons: The Key Step in Gold-Catalyzed Organic Transformations

(2009) Hubert Schmidbaur et al.   ORGANOMETALLICS

PtCl2-Catalyzed [6+2] Cycloaddition of Alkynes Tethered to Cycloheptatriene

(2008) Alphonse Tenaglia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,2-Alkyl Migration as a Key Element in the Invention of Cascade Reactions Catalyzed by π-Acids

(2008) Benedikt Crone et al.   CHEMISTRY-A EUROPEAN JOURNAL

The exploration of macrocycles for drug discovery — an underexploited structural class

(2008) Edward M. Driggers et al.   NATURE REVIEWS DRUG DISCOVERY