期刊
ORGANIC LETTERS
卷 13, 期 21, 页码 5924-5927出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202649j
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资金
- Colorado State University
A number of diversely substituted furans are synthesized via a cycloisomerization process that goes through a unique metal carbene species. Both ligand structure and the nature of the leaving group are evaluated. The characteristics of the carbene intermediate can be modulated, resulting in highly selective hydrogen or silicon group migrations.
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