期刊
ORGANIC LETTERS
卷 15, 期 7, 页码 1772-1775出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400625f
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资金
- Colorado State University
Enantiospecific cycloisomerizations of 1,6-enynes to form oxabicyclo[4.1.0]heptene derivatives are described. Enantiospecificity is consistently high regardless of alkene or alkyne substitution, providing a general approach to greatly enantioenriched cyclopropanes. Additionally, a model for stereochemical transfer is proposed.
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