Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphates

Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent “gold rush”

(2012) Xing-Zhong Shu et al.   CHEMICAL SOCIETY REVIEWS

Factors Controlling the Equilibrium of Pt-Catalyzed [1,2]- versus [1,3]-Acyloxy Migration

(2012) Eun Jin Cho   CHEMISTRY-A EUROPEAN JOURNAL

Gold-Catalyzed 1,2-/1,2-Bis-acetoxy Migration of 1,4-Bis-propargyl Acetates: A Mechanistic Study

(2012) Teresa de Haro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereocontrolled 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay toward Highly Functionalized 1,3-Dienes

(2012) Roohollah Kazem Shiroodi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed 1,3-Acyloxy Migration/5-exo-dig Cyclization/1,5-Acyl Migration of Diynyl Esters

(2011) David Lebœuf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters

(2011) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Reactivity Switch in the Gold-Catalysed Coupling of Allyl Sulfides with Propargylic Carboxylates

(2011) Paul Davies et al.   SYNLETT

Gold-Catalyzed Cyclopenta- and Cycloheptannulation Cascades: A Stereocontrolled Approach to the Scaffold of Frondosins A and B

(2010) David Garayalde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The use of Br/Cl to promote regioselective gold-catalyzed rearrangement of propargylic carboxylates: an efficient synthesis of (1Z, 3E)-1-bromo/chloro-2-carboxy-1,3-dienes

(2010) Yanzhao Wang et al.   CHEMICAL COMMUNICATIONS

Mechanistic Insights in Gold-Stabilized Nonclassical Carbocations: Gold-Catalyzed Rearrangement of 3-Cyclopropyl Propargylic Acetates

(2010) David Garayalde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Homogeneous Oxidative Cross-Coupling Reactions

(2009) Guozhu Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The art of total synthesis through cascade reactions

(2009) K. C. Nicolaou et al.   CHEMICAL SOCIETY REVIEWS

Gold-Catalyzed Stereocontrolled Synthesis of 2,3-Bis(acetoxy)-1,3-dienes

(2009) Xiaogen Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-Catalyzed Enantioselective Synthesis of BenzopyransviaRearrangement of Allylic Oxonium Intermediates

(2009) Minoru Uemura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on Au(I)-Catalyzed [3,3]-Sigmatropic Rearrangements using Cyclopropane Probes

(2009) Pablo Mauleón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substituent Effect on the Formation and Reactivity of Platinum Carbenoids

(2008) Eun Jin Cho et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold-Catalyzed Cycloisomerization of Cyclopropyl Alkynyl Acetates: A Versatile Approach to 5-, 6-, and 7-Membered Carbocycles

(2008) Yue Zou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Insights on the Mechanism of the Transition-Metal Stereoselective Olefin Cyclopropanation

(2008) Elena Soriano et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-catalyzed synthesis of (1E,3E)-dienes from propargylic esters

(2008) Alexander S. Dudnik et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Gold-Catalyzed 1,3-Addition of a sp3-Hybridized C−H Bond to Alkenylcarbenoid Intermediate

(2008) Sabyasachi Bhunia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed 1,2-Shift of Diverse Migrating Groups in Allenyl Systems as a New Paradigm toward Densely Functionalized Heterocycles

(2008) Alexander S. Dudnik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Au-Catalyzed Synthesis of (1Z,3E)-2-Pivaloxy-1,3-Dienes from Propargylic Pivalates

(2008) Guotao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Double Migration-Benzannulation Cascade toward Naphthalenes

(2008) Alexander S. Dudnik et al.   ORGANIC LETTERS

Gold(I)-catalyzed double migration cascades toward (1E,3E)-dienes and naphthalenes

(2008) Alexander S. Dudnik et al.   TETRAHEDRON

Gold- vs. Platinum-Catalyzed Polycyclizations byO-Acyl Migration. Solvent-Free Reactions

(2007) Xavier Moreau et al.   ADVANCED SYNTHESIS & CATALYSIS

Alkynes as masked ylides: Gold-catalysed intermolecular reactions of propargylic carboxylates with sulfides

(2007) Paul W. Davies et al.   CHEMICAL COMMUNICATIONS