Insertion of benzyne into the Pd–C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2′-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates

Ortho Palladation of the Phenethylamines of Biological Relevance l-Tyrosine Methyl Ester and Homoveratrylamine. Reactivity of the Palladacycles toward CO and Isocyanides. Synthesis of the Natural Alkaloid Corydaldine

(2012) María-José Oliva-Madrid et al.   ORGANOMETALLICS

Recent advances in [2+2+2] cycloaddition reactions

(2011) Gema Domínguez et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed [3+2] Cycloaddition Reaction of (Diarylmethylene)cyclopropa[b]naphthalenes with Arynes: An Efficient Synthesis of 11-(Diarylmethylene)-11H-benzo[b]fluorenes

(2011) Ying Lin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Generation of benzyne from benzoic acid using C–H activation

(2010) Alastair A. Cant et al.   CHEMICAL COMMUNICATIONS

Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†

(2010) José Vicente et al.   ORGANOMETALLICS

Copper-catalysed bromoalkynylation of arynes

(2009) Takami Morishita et al.   CHEMICAL COMMUNICATIONS

Five-membered metallacycloalkynes formed from group 4 metals and [n]cumulene (n=3,5) ligands

(2009) Noriyuki Suzuki et al.   COORDINATION CHEMISTRY REVIEWS

Palladium-Catalyzed Cocyclotrimerization of Allenes with Arynes: Selective Synthesis of Phenanthrenes

(2009) Yi-Lin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Synthesis of 9-Fluorenylidenes through Aryne Annulation

(2009) Shilpa A. Worlikar et al.   ORGANIC LETTERS

Palladium-Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines

(2008) Thibaud Gerfaud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-catalyzed efficient tandem assembly of terminal alkynes and arynes: synthesis of alkynylated biphenyl derivatives

(2008) Chunsong Xie et al.   CHEMICAL COMMUNICATIONS

An Overview of Syntheses of Apogalanthamine Analogues and 7-Aza Derivatives of Steganacin and Steganone

(2008) Prasad Appukkuttan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of Fluoren-9-ones by the Palladium-Catalyzed Annulation of Arynes by 2-Haloarenecarboxaldehydes

(2008) Jesse P. Waldo et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes

(2008) Hiroto Yoshida et al.   ORGANIC LETTERS