Mechanism and origins of selectivity in rhodium-catalyzed intermolecular [3 + 2] cycloadditions of vinylaziridines with allenes

Metal-Catalyzed Annulations through Activation and Cleavage of C−H Bonds

(2016) Moisés Gulías et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent Intermolecular [3+2] Cycloadditions of Vinyl Aziridines and Allenes: Stereospecific Synthesis of Chiral Pyrrolidines

(2016) Tao-Yan Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism and Selectivity of RuII- and RhIII-Catalyzed Oxidative Spiroannulation of Naphthols and Phenols with Alkynes through a C−H Activation/Dearomatization Strategy

(2016) Mei Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of iridium-catalysed branched-selective hydroarylation of vinyl ethers: a computational study

(2016) Mei Zhang et al.   DALTON TRANSACTIONS

The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes

(2016) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Hetero-(5 + 2) Cycloaddition of Vinylaziridines and Alkynes: A Theoretical View of the Mechanism and Chirality Transfer

(2016) Lei Zhu et al.   ORGANOMETALLICS

Synthesis of Unsaturated N-Heterocycles by Cycloadditions of Aziridines and Alkynes

(2016) Jian-Jun Feng et al.   ACS Catalysis

Mechanism and Origins of Ligand-Controlled Linear Versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes

(2016) Genping Huang et al.   ACS Catalysis

Rhodium-Catalyzed [5 + 2 + 1] Cycloaddition of Ene–Vinylcyclopropanes and CO: Reaction Design, Development, Application in Natural Product Synthesis, and Inspiration for Developing New Reactions for Synthesis of Eight-Membered Carbocycles

(2015) Yi Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Modular Access to the Stereoisomers of Fused Bicyclic Azepines: Rhodium-Catalyzed Intramolecular Stereospecific Hetero-[5+2] Cycloaddition of Vinyl Aziridines and Alkenes

(2015) Jian-Jun Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism and Selectivity in Rhodium-Catalyzed [7 + 2] Cycloaddition and Cyclopropanation/Cyclization of Allenylcyclopentane-alkynes: Metallacycle-Directed C(sp3)-C(sp3) vs C(sp3)-H Activation

(2015) Genping Huang   JOURNAL OF ORGANIC CHEMISTRY

Origins of Stereoselectivity in Intramolecular Aldol Reactions Catalyzed by Cinchona Amines

(2015) Yu-hong Lam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transfer of Chirality in the Rhodium-Catalyzed Intramolecular Formal Hetero-[5 + 2] Cycloaddition of Vinyl Aziridines and Alkynes: Stereoselective Synthesis of Fused Azepine Derivatives

(2015) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Rhodium-Catalyzed Cyclopropanation/Cyclization of Allenynes

(2015) Genping Huang   ORGANIC LETTERS

Controlling the Selectivity of C–H Activation in Pyridinium Triazolylidene Iridium Complexes: Mechanistic Details and Influence of Remote Substituents

(2015) Kate F. Donnelly et al.   ORGANOMETALLICS

Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)–H borylation of chlorosilanes

(2015) Genping Huang et al.   Chemical Science

Catalyst-Controlled C–C σ Bond Cleavages in Metal Halide-Catalyzed Cycloisomerization of 3-Acylcyclopropenes via a Formal 1,1-Halometalation Mechanism: Insights from Quantum Chemical Calculations

(2015) Genping Huang et al.   ACS Catalysis

Catalytic Efficiency Is a Function of How Rhodium(I) (5 + 2) Catalysts Accommodate a Conserved Substrate Transition State Geometry: Induced Fit Model for Explaining Transition Metal Catalysis

(2015) Thomas J. L. Mustard et al.   ACS Catalysis

Mechanistic Insight into the Gold-Catalyzed Carboxylative Cyclization of Propargylamines

(2015) Ruming Yuan et al.   ACS Catalysis

Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and α,β-Unsaturated Ketones

(2014) Chao-Fan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Chemistry of Transition Metals with Three-Membered Ring Heterocycles

(2014) Chung-Yang (Dennis) Huang et al.   CHEMICAL REVIEWS

Enantioselective Cobalt-Catalyzed Transformations

(2014) Hélène Pellissier et al.   CHEMICAL REVIEWS

Recent Advances in Stereoselective [2+2+2] Cycloadditions

(2014) Muriel Amatore et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Reactivity for the Diels–Alder Reaction of Cumulenes: A Distortion-Interaction Analysis along the Reaction Pathway

(2014) Song Liu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Mechanistic Insights into the Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Multisubstituted Pyrroles: Understanding the Remarkable Regio- and Enantioselectivity

(2014) Chao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity and Chemoselectivity of Allenes in Rh(I)-Catalyzed Intermolecular (5 + 2) Cycloadditions with Vinylcyclopropanes: Allene-Mediated Rhodacycle Formation Can Poison Rh(I)-Catalyzed Cycloadditions

(2014) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands

(2014) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How Tethers Control the Chemo- and Regioselectivities of Intramolecular Cycloadditions between Aryl-1-aza-2-azoniaallenes and Alkenes

(2014) Xin Hong et al.   ORGANIC LETTERS

Mechanism of Palladium/Amine Cocatalyzed Carbocyclization of Aldehydes with Alkynes and Its Merging with “Pd Oxidase Catalysis”

(2014) Stefano Santoro et al.   ACS Catalysis

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Axial-to-central chirality transfer in cyclization processes

(2013) Damien Campolo et al.   CHEMICAL SOCIETY REVIEWS

Theoretical Studies on the Mechanism of the C–H Amination of Silyl Cyclopropenes by Azodicarboxylates

(2013) Genping Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Vinylcyclopropane Derivatives in Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Carbocyclic Compounds

(2013) Lei Jiao et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism and Selectivity of Rhodium-Catalyzed 1:2 Coupling of Aldehydes and Allenes

(2013) Genping Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dichotomous Hydrogen Atom Transfer vs Proton-Coupled Electron Transfer During Activation of X–H Bonds (X = C, N, O) by Nonheme Iron–Oxo Complexes of Variable Basicity

(2013) Dandamudi Usharani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Synthesis of (+)-allo-Kainic Acid via MgI2-Mediated Tandem Aziridine Ring Opening–Formal [3 + 2] Cycloaddition

(2013) Giada Arena et al.   ORGANIC LETTERS

Recent advances in the synthesis of naturally occurring pyrrolidines, pyrrolizidines and indolizidine alkaloids using proline as a unique chiral synthon

(2013) Chinmay Bhat et al.   RSC Advances

Transition-Metal-Catalyzed Cycloisomerizations of α,ω-Dienes

(2012) Yoshihiko Yamamoto   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Transition-Metal-Catalyzed Cyclization of Alkynals via Oxametallacycle Intermediates

(2012) Ken Tanaka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ligand Effects on Rates and Regioselectivities of Rh(I)-Catalyzed (5 + 2) Cycloadditions: A Computational Study of Cyclooctadiene and Dinaphthocyclooctatetraene as Ligands

(2012) Xiufang Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control and Design of Mutual Orthogonality in Bioorthogonal Cycloadditions

(2012) Yong Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl Aziridines

(2012) Joshua J. Hirner et al.   ORGANOMETALLICS

Recent Developments in the [5+2] Cycloaddition

(2011) Hélène Pellissier   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Mediated Annulation of Vinyl Aziridines with Michael Acceptors: Stereocontrolled Synthesis of Substituted Pyrrolidines and Its Application in a Formal Synthesis of (−)-α-Kainic Acid

(2011) Martin A. Lowe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in gold-catalyzed cycloaddition reactions

(2011) Fernando López et al.   Beilstein Journal of Organic Chemistry

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Preparation and synthetic applications of alkene complexes of group 9 transition metals in [2+2+2] cycloaddition reactions

(2011) Nico Weding et al.   CHEMICAL SOCIETY REVIEWS

Total Synthesis of (+)-Asteriscanolide: Further Exploration of the Rhodium(I)-Catalyzed [(5+2)+1] Reaction of Ene-Vinylcyclopropanes and CO

(2011) Yong Liang et al.   Chemistry-An Asian Journal

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Asymmetric Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of 1-Yne-vinylcyclopropanes for Bicyclo[3.3.0] Compounds with a Chiral Quaternary Carbon Stereocenter and Density Functional Theory Study of the Origins of Enantioselectivity

(2011) Mu Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes

(2010) Fuyuhiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective transition metal-catalysed higher-order carbocyclisation reactions

(2010) Phillip A. Inglesby et al.   CHEMICAL SOCIETY REVIEWS

Recent Strategies for the Synthesis of Pyridine Derivatives

(2010) Matthew D. Hill   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Electronic and Steric Control of Regioselectivities in Rh(I)-Catalyzed (5 + 2) Cycloadditions: Experiment and Theory

(2010) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Density Functional Theory Study of the Mechanisms and Stereochemistry of the Rh(I)-Catalyzed Intramolecular [3+2] Cycloadditions of 1-Ene- and 1-Yne-Vinylcyclopropanes

(2010) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[2+2+2] Cycloaddition Reactions of Macrocyclic Systems Catalyzed by Transition Metals. A Review

(2010) Anna Pla-Quintana et al.   MOLECULES

Reaction of α-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?

(2010) Qian Li et al.   ORGANIC LETTERS

Synthesis of Cyclopentitols by Ring-Closing Approaches

(2009) Vanya B. Kurteva et al.   CHEMICAL REVIEWS

The Diene Effect: The Design, Development, and Mechanistic Investigation of Metal-Catalyzed Diene-yne, Diene-ene, and Diene-allene [2+2+1] Cycloaddition Reactions

(2009) Mitchell P. Croatt et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Transition State Distortion Energies Correlate with Activation Energies of 1,4-Dihydrogenations and Diels−Alder Cycloadditions of Aromatic Molecules

(2009) Amy E. Hayden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substituent Effects, Reactant Preorganization, and Ligand Exchange Control the Reactivity in RhI-Catalyzed (5+2) Cycloadditions between Vinylcyclopropanes and Alkynes

(2008) Peng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition oftrans-Vinylcyclopropane-enes

(2008) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of Differences in Reactivities of Alkenes, Alkynes, and Allenes in [Rh(CO)2Cl]2-Catalyzed (5 + 2) Cycloaddition Reactions with Vinylcyclopropanes

(2008) Zhi-Xiang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cheap Metal for a “Noble” Task:  Preparative and Mechanistic Aspects of Cycloisomerization and Cycloaddition Reactions Catalyzed by Low-Valent Iron Complexes

(2008) Alois Fürstner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in syntheses of carbocycles and heterocycles via homogeneous gold catalysis. Part 2: Cyclizations and cycloadditions

(2008) Hong C. Shen   TETRAHEDRON