Metal-Catalyzed Annulations through Activation and Cleavage of C−H Bonds

Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome

(2016) Noelia Casanova et al.   ACS Catalysis

Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes

(2015) Noelia Casanova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed CH Functionalization and Spiroannulation

(2015) Suresh Reddy Chidipudi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Synthesis ofcis-β-Amino Acid Esters through Organometallic CH Activation of Ketimines

(2015) Weiping Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed CH Activation/Alkyne Annulation by Weak Coordination with O2as the Sole Oxidant

(2015) Svenja Warratz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of spiroindanes by palladium-catalyzed oxidative annulation of non- or weakly activated 1,3-dienes involving C–H functionalization

(2015) Imtiaz Khan et al.   CHEMICAL COMMUNICATIONS

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

(2015) Laetitia Souillart et al.   CHEMICAL REVIEWS

Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants

(2015) Huawen Huang et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(III)-Catalyzed [4+1] Annulation of Aromatic and Vinylic Carboxylic Acids with Allenes: An Efficient Method Towards Vinyl-Substituted Phthalides and 2-Furanones

(2015) Parthasarathy Gandeepan et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhV-Nitrenoid as a Key Intermediate in RhIII-Catalyzed Heterocyclization by CH Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo Compounds

(2015) Tao Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Dehydrogenative Coupling of Phenylheteroarenes with Alkynes or Alkenes

(2015) Tomonori Iitsuka et al.   JOURNAL OF ORGANIC CHEMISTRY

Ru(II)-Catalyzed Oxidative Spiroannulation of 2-Arylphenols with Alkynes via a C–H Activation/Dearomatization Strategy

(2015) Zhijun Zuo et al.   JOURNAL OF ORGANIC CHEMISTRY

DFT Studies on the Mechanism of the Rhodium(III)-Catalyzed C–H Activation of N-Phenoxyacetamide

(2015) Juan Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Oxidative Annulation of 2-Phenylimidazo[1,2-a]pyridines with Alkynes: Mono versus Double C–H Activation

(2015) Zisong Qi et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Understanding of the Divergent Reactivity of Cyclopropenes in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and N-Pivaloxybenzamide

(2015) Wei Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction

(2015) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer

(2015) Ramesh B. Dateer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Construction of Quinolin-2(1H)-ones via C–H Bond Activation of Simple Anilines with CO and Alkynes

(2015) Xinyao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Aerobic Carbonylation of C(sp2)–H and C(sp3)–H Bonds through Ni/Cu Synergistic Catalysis with DMF as the Carbonyl Source

(2015) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RhIII-Catalyzed [4 + 1] Annulations of 2-Hydroxy- and 2-Aminobenzaldehydes with Allenes: A Simple Method toward 3-Coumaranones and 3-Indolinones

(2015) Ramajayam Kuppusamy et al.   ORGANIC LETTERS

Cp*Co(III)-Catalyzed Annulations of 2-Alkenylphenols with CO: Mild Access to Coumarin Derivatives

(2015) Xu-Ge Liu et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Vinylic C–H Activation: A Direct Route toward Pyridinium Salts

(2015) Ching-Zong Luo et al.   ORGANIC LETTERS

Mechanistic Understanding of the Aryl-Dependent Ring Formations in Rh(III)-Catalyzed C–H Activation/Cycloaddition of Benzamides and Methylenecyclopropanes by DFT Calculations

(2015) Wei Guo et al.   ORGANOMETALLICS

Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

(2015) Shangze Wu et al.   Chemical Science

Rhodium(III)–N-Heterocyclic Carbene-Driven Cascade C–H Activation Catalysis

(2015) Debasish Ghorai et al.   ACS Catalysis

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Palladium@Cerium(IV) Oxide-Catalyzed Oxidative Synthesis ofN-(2-Pyridyl)indolesviaCH Activation Reaction

(2014) Jianbin Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Regioselective Synthesis of IndolesviaRhodium-Catalyzed CH Activation Directed by anIn-SituGenerated Redox-Neutral Group

(2014) Krishnamoorthy Muralirajan et al.   ADVANCED SYNTHESIS & CATALYSIS

The Oxidative Annulation of Tertiary Benzyl Alcohols with Internal Alkynes using an (Electron-Deficient η5-Cyclopenta- dienyl)Rhodium(III) Catalyst under Ambient Conditions

(2014) Miho Fukui et al.   ADVANCED SYNTHESIS & CATALYSIS

Diastereoselective Carbocyclization of 1,6-Heptadienes Triggered by Rhodium-Catalyzed Activation of an Olefinic CH Bond

(2014) Christophe Aïssa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversal of the Regiochemistry in the Rhodium-Catalyzed [4+3] Cycloaddition between Vinyldiazoacetates and Dienes

(2014) Pablo E. Guzmán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Dehydrogenative [4+2] Annulation of NH Imines and Alkynes by CH/NH Activation

(2014) Ruoyu He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The CH Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIIICatalysis

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Synthesis of Highly Substituted Polyheteroaromatic Compounds by Rhodium(III)-Catalyzed Multiple CH Activation and Annulation

(2014) Jayachandran Jayakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of CH Bonds

(2014) Wu Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Homologation by Non-Chelate-Assisted RhIII-Catalyzed CH Functionalization of Arenes with Alkynes

(2014) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed [3+2] Annulation of 5-Aryl-2,3-dihydro-1H-pyrroles with Internal Alkynes through C(sp2)H/Alkene Functionalization

(2014) Ming-Bo Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Transannulation of Cyclopropenes withN-Phenoxyacetamides through CH Activation

(2014) Hang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling of Styrenes with Aryl Methyl Ketones in Ionic Liquids: Direct Access to Cyclopropanes

(2014) Pietro Cotugno et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Extended π-Systems through C-H Activation

(2014) Yasutomo Segawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Isoindolones by Chiral Cyclopentadienyl-Rhodium(III)-Catalyzed CH Functionalizations

(2014) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Annulation of Diarylamines with Olefins through CH Activation: Direct Access to N-Arylindoles

(2014) Upendra Sharma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(iii)-Catalyzed synthesis of sultones through C–H activation directed by a sulfonic acid group

(2014) Zisong Qi et al.   CHEMICAL COMMUNICATIONS

Rh(iii)-catalyzed synthesis of 1-substituted isoquinolinium salts via a C–H bond activation reaction of ketimines with alkynes

(2014) Natarajan Senthilkumar et al.   CHEMICAL COMMUNICATIONS

Exploring a unique reactivity of N-heterocyclic carbenes (NHC) in rhodium(iii)-catalyzed intermolecular C–H activation/annulation

(2014) Debasish Ghorai et al.   CHEMICAL COMMUNICATIONS

Rh-Catalyzed oxidative C–H activation/annulation: converting anilines to indoles using molecular oxygen as the sole oxidant

(2014) Guoying Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles

(2014) Xun-Xiang Guo et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Carbonylative [3+2+1] Annulation ofN-Aryl-Pyridine-2-Amines with Internal Alkynes by CH Activation: Facile Synthesis of 2-Quinolinones

(2014) Jianbin Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed CH Activation and Indole Synthesis With Hydrazone as an Auto-Formed and Auto-Cleavable Directing Group

(2014) Liyao Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Spirocyclic Enones by Rhodium-Catalyzed Dearomatizing Oxidative Annulation of 2-Alkenylphenols with Alkynes and Enynes

(2014) Szymon Kujawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2014) Xiao-Feng Xia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intramolecular Redox-Neutral Annulation of Tethered Alkynes: Formal Total Synthesis of (±)-Goniomitine

(2014) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Modular Assembly of Ring-Fused and π-Extended Phenanthroimidazoles via C–H Activation and Alkyne Annulation

(2014) Liyao Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Synthesis of Isoquinolones with 8-Aminoquinoline as a Bidentate Directing Group in C–H Functionalization

(2014) Srinivasarao Allu et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Multisubstituted 2-Aminoquinolines from Annulation of 1-Aryl Tetrazoles with Internal Alkynes via Double C–H Activation and Denitrogenation

(2014) Lei Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Tunable Arylative Cyclization of 1,6-Enynes Triggered by Rhodium(III)-Catalyzed C–H Activation

(2014) Yuki Fukui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes

(2014) Tiffany Piou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

(2014) Andrés Seoane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

(2014) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

(2014) Andrew McNally et al.   NATURE

Rh(III)-Catalyzed Intramolecular Redox-Neutral or Oxidative Cyclization of Alkynes: Short, Efficient Synthesis of 3,4-Fused Indole Skeletons

(2014) Bing Zhou et al.   ORGANIC LETTERS

Strain-Promoted Oxidative Annulation of Arynes and Cyclooctynes with Benzamides: Palladium-Catalyzed C–H/N–H Activation for the Synthesis of N-Heterocycles

(2014) Xianglong Peng et al.   ORGANIC LETTERS

Cobalt-Catalyzed Direct Carbonylation of Aminoquinoline Benzamides

(2014) Liene Grigorjeva et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Hydrazine-Directed C–H Activation for Indole Synthesis: Mechanism and Role of Internal Oxidant Probed by DFT Studies

(2014) Wen-Jie Chen et al.   ORGANOMETALLICS

Rh(iii)-catalyzed C–H functionalization/aromatization cascade with 1,3-dienes: a redox-neutral and regioselective access to isoquinolines

(2014) Dongbing Zhao et al.   Chemical Science

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Regioselective Synthesis of Functionalized PyrrolesviaGold(I)-Catalyzed [3+2] Cycloaddition of Stabilized Vinyl Diazo Derivatives and Nitriles

(2013) Giacomo Lonzi et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines

(2013) Wanrong Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving CC and CP Bond Formation

(2013) Yuto Unoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines

(2013) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Dibenzopyranones through Palladium-Catalyzed Directed C-H Activation/Carbonylation of 2-Arylphenols

(2013) Shuang Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/Copper-Catalyzed Oxidative CH Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines

(2013) Renyi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed CH Activation: Redox-Neutral and Traceless by NN Bond Cleavage

(2013) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intramolecular Hydroarylation, Amidoarylation, and Heck-type Reaction: Three Distinct Pathways Determined by an Amide Directing Group

(2013) Tyler A. Davis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Redox-Neutral Coupling ofN-Phenoxyacetamides and Alkynes with Tunable Selectivity

(2013) Guixia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework

(2013) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Access to Benzo[b]furans through Palladium-Catalyzed Oxidative Annulation of Phenols and Unactivated Internal Alkynes

(2013) Malleswara Rao Kuram et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Synthesis of Benzofurans and Coumarins from Phenols and Olefins

(2013) Upendra Sharma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages

(2013) Tomonori Iitsuka et al.   CHEMISTRY-A EUROPEAN JOURNAL

RuII-Catalyzed Vinylative Dearomatization of Naphthols via a C(sp2)–H Bond Activation Approach

(2013) Jiang Nan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed C–H Activation and Double Directing Group Strategy for the Regioselective Synthesis of Naphthyridinones

(2013) John R. Huckins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Divergent C–H Functionalization of Unsymmetrical 2-Aryl Cyclic 1,3-Dicarbonyl Compounds with Alkynes and Alkenes

(2013) Johnathon D. Dooley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Indole Synthesis Using N–N Bond as an Internal Oxidant

(2013) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Straightforward Assembly of Benzoxepines by Means of a Rhodium(III)-Catalyzed C–H Functionalization of o-Vinylphenols

(2013) Andrés Seoane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(iii)-catalyzed vinylic sp2 C–H bond functionalization: efficient synthesis of pyrido[1,2-α]benzimidazoles and imidazo[1,2-α]pyridines

(2013) Lin Dong et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by rhodium-catalyzed intramolecular double C–H bond activation

(2013) Vutukuri Prakash Reddy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed Direct Selective C(5)–H Oxidative Annulations of 2-Substituted Imidazoles and Alkynes by Double C–H Activation

(2013) Ji-Rong Huang et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Carbonylative C–H Cyclization of 2-Arylphenols: A Novel Synthetic Route to 6H-Dibenzo[b,d]pyran-6-ones

(2013) Kiyofumi Inamoto et al.   ORGANIC LETTERS

Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis

(2013) S. Duttwyler et al.   SCIENCE

Ruthenium-catalyzed cyclocarbonylation of aliphatic amides through the regioselective activation of unactivated C(sp3)–H bonds

(2013) Nao Hasegawa et al.   TETRAHEDRON

Rhodium(iii)-catalyzed intramolecular annulations involving amide-directed C–H activations: synthetic scope and mechanistic studies

(2013) Noelia Quiñones et al.   Chemical Science

Benzofuran synthesis via copper-mediated oxidative annulation of phenols and unactivated internal alkynes

(2013) Ruyi Zhu et al.   Chemical Science

Rh(iii)-catalyzed C–H activation/cycloaddition of benzamides and methylenecyclopropanes: divergence in ring formation

(2013) Sunliang Cui et al.   Chemical Science

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

(2013) Sunliang Cui et al.   Chemical Science

Chemoselective Synthesis of Naphthylamides and IsoquinolinonesviaRhodium-Catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes

(2012) Zhuangzhi Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Construction of Monocyclic Eight-Membered Rings: Intermolecular Rhodium(I)-Catalyzed [6+2] Cycloaddition of 4-Allenals with Alkynes

(2012) Yoshihiro Oonishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functionalization of C sp 3H and C sp 2H Bonds: Synthesis of Spiroindenes by Enolate-Directed Ruthenium-Catalyzed Oxidative Annulation of Alkynes with 2-Aryl-1,3-dicarbonyl Compounds

(2012) Suresh Reddy Chidipudi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diverse Reactivity in a Rhodium(III)-Catalyzed Oxidative Coupling ofN-Allyl Arenesulfonamides with Alkynes

(2012) Dongqi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intramolecular Annulation through CH Activation: Total Synthesis of (±)-Antofine, (±)-Septicine, (±)-Tylophorine, and Rosettacin

(2012) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Sultams by Rhodium(III)-Catalyzed Directed CH Activation

(2012) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Cycloaddition through CH/NH Activation: Access to Benzazepines

(2012) Lei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-catalysed synthesis of isoquinolinones and analogues via C–H and N–H bonds double activation

(2012) Hongban Zhong et al.   CHEMICAL COMMUNICATIONS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Aza-Fused Polycyclic Quinolines via Double CH Bond Activation

(2012) Ji-Rong Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Pyridines from Ketoximes and Terminal Alkynes via C–H Bond Functionalization

(2012) Rhia M. Martin et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β-Unsaturated Oxime Esters

(2012) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade

(2012) Simon Duttwyler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regioselective Carbonylation of C–H Bonds of N-Alkyl Anilines for Synthesis of Isatoic Anhydrides

(2012) Zheng-Hui Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild Rh(III)-Catalyzed C–H Activation and Annulation with Alkyne MIDA Boronates: Short, Efficient Synthesis of Heterocyclic Boronic Acid Derivatives

(2012) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Ruthenium(II) Catalysts for Oxidative C–H/N–H Bond Functionalizations of Anilines with Removable Directing Group: Synthesis of Indoles in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions

(2011) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium(I)-Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations

(2011) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Synthesis of Indenols by Rhodium-Catalyzed CH Activation and Carbocyclization of Aryl Ketones and Alkynes

(2011) Krishnamoorthy Muralirajan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

(2011) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cptprovide complementary selectivity

(2011) Todd K. Hyster et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

(2011) Ya Du et al.   CHEMICAL COMMUNICATIONS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-Catalyzed Annulation of N-Benzoylsulfonamide with Isocyanide through CH Activation

(2011) Chen Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Isoquinolone Synthesis through CH Activation Using an Oxidizing Directing Group

(2011) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Isochromene and Related Derivatives by Rhodium-Catalyzed Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes

(2011) Keisuke Morimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization

(2011) Liang Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(I)-Catalyzed Formal [6 + 2] Cycloaddition of 4-Allenals with Alkynes or Alkenes in a Tether

(2011) Yoshihiro Oonishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed (2 + 2) Intramolecular Cycloaddition of Allenenes

(2011) Moisés Gulías et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Strategies toward Indenol and Fulvene Derivatives: Rh-Catalyzed C−H Activation of Aryl Ketones Followed by Coupling with Internal Alkynes

(2011) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C–H/N–H Bond Functionalizations

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Synthesis of 1-Aminoisoquinolines via Rh(III)-Catalyzed Oxidative Coupling

(2011) Xiaohong Wei et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H/N–O Bond Functionalization: Green Isoquinolone Syntheses in Water

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Development of transition-metal-catalyzed cycloaddition reactions leading to polycarbocyclic systems

(2011) Moisés Gulías et al.   PURE AND APPLIED CHEMISTRY

Synthesis of indoles via palladium-catalyzed C–H activation of N-aryl amides followed by coupling with alkynes

(2011) Feng Zhou et al.   TETRAHEDRON LETTERS

An improved catalyst architecture for rhodium(iii) catalyzed C–H activation and its application to pyridone synthesis

(2011) Todd K. Hyster et al.   Chemical Science

syn-Selective Rhodium(I)-Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence

(2010) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3-Aliphatic-Substituted Indoles and Pyrroles

(2010) Malcolm P. Huestis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium catalyzed synthesis of highly substituted naphthalenes via direct ring construction from amides with alkynes

(2010) Junliang Wu et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Oxidative Coupling/Cyclization of Benzamides with Alkynes via C–H Bond Cleavage

(2010) Satoshi Mochida et al.   CHEMISTRY LETTERS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Naphtho[1,8-bc]pyran Derivatives and Related Compounds through Hydroxy Group Directed CH Bond Cleavage under Rhodium Catalysis

(2010) Satoshi Mochida et al.   Chemistry-An Asian Journal

Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C−H Bonds

(2010) Nobuyoshi Umeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

(2010) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic and Steric Control of Regioselectivities in Rh(I)-Catalyzed (5 + 2) Cycloadditions: Experiment and Theory

(2010) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Carbonylation of C(sp3)−H Bonds: A New Entry to 1,4-Dicarbonyl Compounds

(2010) Eun Jeong Yoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Synthesis of Isoquinolines from Aryl KetoneO-Acyloxime Derivatives and Internal Alkynes

(2010) Pei Chui Too et al.   ORGANIC LETTERS

Amine directed Pd(ii)-catalyzed C–H bond functionalization under ambient conditions

(2010) Benjamin Haffemayer et al.   Chemical Science

A Palladium-Catalyzed Oxidative Cycloaromatization of Biaryls with Alkynes Using Molecular Oxygen as the Oxidant

(2009) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Indoles from Simple Anilines and Alkynes: Palladium-Catalyzed CH Activation Using Dioxygen as the Oxidant

(2009) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

(2009) Tatsuya Fukutani et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed [3C + 2C + 2C] cycloaddition of enynylidenecyclopropanes: efficient construction of fused 5-7-5 tricyclic systems

(2009) Gaurav Bhargava et al.   CHEMICAL COMMUNICATIONS

Catalysis and Sustainable Development: The Marriage for Innovation

(2009) Matthias Beller et al.   ChemSusChem

Synthesis of Functionalized α-Pyrone and Butenolide Derivatives by Rhodium-Catalyzed Oxidative Coupling of Substituted Acrylic Acids with Alkynes and Alkenes

(2009) Satoshi Mochida et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Carbonylation at Ortho C−H Bonds in Aromatic Amides Leading to Phthalimides: C−H Bond Activation Utilizing a Bidentate System

(2009) Satoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes

(2009) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of Both C(sp3)−C(sp2) Bonds of Alkylidenecyclopropanes: Formation of Ethylene−Osmium−Vinylidene Complexes

(2009) Ruth Castro-Rodrigo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis at the molecular frontier

(2009) Paul A. Wender et al.   NATURE

Synthesis of substituted 6-imino-2-piperidinones by Rh-catalyzed [4+2] annulation of 4-alkynals with carbodiimides

(2009) Ken Tanaka et al.   TETRAHEDRON

Enantioselective Synthesis of Spirocyclic Benzopyranones by Rhodium‐Catalyzed Intermolecular [4+2] Annulation

(2008) Daiki Hojo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorescent Naphthyl- and Anthrylazoles from the Catalytic Coupling of Phenylazoles with Internal Alkynes through the Cleavage of Multiple CH Bonds

(2008) Nobuyoshi Umeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Dihydropyridines and Pyridines from Imines and Alkynes via C−H Activation

(2008) Denise A. Colby et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Function-Oriented Synthesis, Step Economy, and Drug Design

(2007) Paul A. Wender et al.   ACCOUNTS OF CHEMICAL RESEARCH