Axial-to-central chirality transfer in cyclization processes

Catalytic Asymmetric Synthesis of Cyclic Ethers Containing an α-Tetrasubstituted Stereocenter

(2013) Nick Cox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of 5,7-Bicyclic Ring Systems from Axially Chiral Allenes Using a Rh(I)-Catalyzed Cyclocarbonylation Reaction

(2013) Francois Grillet et al.   JOURNAL OF ORGANIC CHEMISTRY

Rotational Isomers of N-Methyl-N-arylacetamides and Their Derived Enolates: Implications for Asymmetric Hartwig Oxindole Cyclizations

(2013) Jérémie Mandel et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Induction via Short-Lived Chiral Enolates with a Chiral C–O Axis

(2013) Tomoyuki Yoshimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric β-Hydride Elimination en Route to Chiral Allenes

(2013) Ian T. Crouch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Studies on the Himbert Intramolecular Arene/Allene Diels–Alder Cycloaddition. Mechanistic Studies and Expansion of Scope to All-Carbon Tethers

(2013) Yvonne Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoenzymatic total synthesis of hyperiones A and B

(2013) Chicco Manzuna Sapu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper Carbenoid, Reactant and Catalyst for One-Pot Diazo Ester Coupling Cascade Rearrangement of Enediynes: Formation of Two Contiguous Tetrasubstituted Stereocenters

(2012) Shovan Mondal et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Azepine Derivatives by Rhodium-Catalyzed Tandem 2,3-Rearrangement/Heterocyclization

(2012) Itaru Nakamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Decarboxylative Amination: Synthesis of Axially Chiral Allenyl Amines

(2012) Baoqiang Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

(2012) Geoffroy Dequirez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric aldol reaction via memory of chirality

(2012) Hidetoshi Watanabe et al.   CHEMICAL COMMUNICATIONS

One-pot Crabbé homologation-radical cascade cyclisation with memory of chirality

(2012) Shovan Mondal et al.   CHEMICAL COMMUNICATIONS

Enantioselective, transition metal catalyzed cycloisomerizations

(2012) Angela Marinetti et al.   CHEMICAL SOCIETY REVIEWS

Propargyl Claisen rearrangement: allene synthesis and beyond

(2012) David Tejedor et al.   CHEMICAL SOCIETY REVIEWS

One hundred years of helicene chemistry. Part 2: stereoselective syntheses and chiral separations of carbohelicenes

(2012) Marc Gingras et al.   CHEMICAL SOCIETY REVIEWS

tert-Butyldimethylsilyl-Directed Highly Enantioselective Approach to Axially Chiral α-Allenols

(2012) Juntao Ye et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-Catalyzed Asymmetric Synthesis of N-Allenyl Amides and Their Au-Catalyzed Cycloisomerizative Hydroalkylation: A New Route Toward Enantioenriched Pyrrolidones

(2012) Audrey Boutier et al.   CHEMISTRY-A EUROPEAN JOURNAL

Protonation-Assisted Conjugate Addition of Axially Chiral Enolates: Asymmetric Synthesis of Multisubstituted β-Lactams from α-Amino Acids

(2012) Tomoyuki Yoshimura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoselective Iodolactonization of 4-Allenoic Acids with Efficient Chirality Transfer: Development of a New Electrophilic Iodination Reagent

(2012) Xiaobing Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structures and Dynamic Solution Behavior of Cationic, Two-Coordinate Gold(I)-π-Allene Complexes

(2012) Timothy J. Brown et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chirality Transfer and Memory of Chirality in Gold-Catalyzed Reactions

(2012) Nitin T. Patil   Chemistry-An Asian Journal

Efficient Synthesis of 4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides from 1,2-Allenylphosphonates and CuX2 and Subsequent Suzuki Cross-Coupling of the C-Cl Bonds

(2012) Ning Xin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

1,4-Diazaspiro[2.2]pentanes as a Flexible Platform for the Synthesis of Diamine-Bearing Stereotriads

(2012) Jared W. Rigoli et al.   JOURNAL OF ORGANIC CHEMISTRY

Modular Functionalization of Allenes to Aminated Stereotriads

(2012) Christopher S. Adams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton Grease: An Acid Accelerated Molecular Rotor

(2012) Brent E. Dial et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides with Allenes

(2012) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two-Step Asymmetric Reaction Using the Frozen Chirality Generated by Spontaneous Crystallization

(2012) Fumitoshi Yagishita et al.   ORGANIC LETTERS

Synthesis of 1,3-Diaminated Stereotriads via Rearrangement of 1,4-Diazaspiro[2.2]pentanes

(2012) Cale D. Weatherly et al.   ORGANIC LETTERS

Regioselective Prins Cyclization of Allenylsilanes. Stereoselective Formation of Multisubstituted Heterocyclic Compounds

(2012) Takuya Okada et al.   ORGANIC LETTERS

Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Aryloximes into Four-Membered Cyclic Nitrones - Chirality Transfer and Mechanistic Insight

(2012) Itaru Nakamura et al.   SYNTHESIS-STUTTGART

Novel Cyclization Reactions of Aminoallenes

(2011) Benito Alcaide et al.   ADVANCED SYNTHESIS & CATALYSIS

Complete transfer of chirality in an intramolecular, thermal [2 + 2] cycloaddition of allene-ynes to form non-racemic spirooxindoles

(2011) Kay M Brummond et al.   Beilstein Journal of Organic Chemistry

An efficient and recyclable hybrid nanocatalyst to promote enantioselective radical cascade rearrangements of enediynes

(2011) Malek Nechab et al.   CHEMICAL COMMUNICATIONS

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Gold-Catalyzed Nucleophilic Cyclization of Functionalized Allenes: A Powerful Access to Carbo- and Heterocycles

(2011) Norbert Krause et al.   CHEMICAL REVIEWS

On the Memory of Chirality in Gold(I)-Catalyzed Intramolecular Carboalkoxylation of Alkynes

(2011) Olalla Nieto Faza et al.   JOURNAL OF ORGANIC CHEMISTRY

Light-Induced Enantiospecific 4π Ring Closure of Axially Chiral 2-Pyridones: Enthalpic and Entropic Effects Promoted by H-Bonding

(2011) Elango Kumarasamy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Axially Chiral o-Iodoanilides by Phase-Transfer Catalyzed Alkylations

(2011) Seiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Intramolecular Cyclobutane Formation via Photochemical Reaction ofN,N-Diallyl-2-quinolone-3-carboxamide Using a Chiral Crystalline Environment

(2011) Fumitoshi Yagishita et al.   ORGANIC LETTERS

Regioselective Transformation ofO-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by Copper-Catalyzed Skeletal Rearrangement

(2011) Itaru Nakamura et al.   ORGANIC LETTERS

Asymmetric photocycloaddition of naphthamide with a diene using the provisional molecular chirality in a chiral crystal

(2011) Masami Sakamoto et al.   PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES

Brønsted Base-Catalyzed Tandem Isomerization-Michael Reactions of Alkynes: Synthesis of Oxacycles and Azacycles

(2010) Hongjun Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

The intramolecular amination of allenes

(2010) George C. Feast et al.   CHEMICAL COMMUNICATIONS

Reactive spin state dependent enantiospecific photocyclization of axially chiral α-substituted acrylanilides

(2010) Anoklase Jean-Luc Ayitou et al.   CHEMICAL COMMUNICATIONS

Chemoenzymatic Dynamic Kinetic Resolution of Axially Chiral Allenes

(2010) Jan Deska et al.   CHEMISTRY-A EUROPEAN JOURNAL

Memory of Chirality in Cascade Rearrangements of Enediynes

(2010) Malek Nechab et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Memory of Axial Chirality in Aryl Radical Phosphanylations

(2010) Achim Bruch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical and Heck Cyclizations of Diastereomerico-Haloanilide Atropisomers

(2010) David B. Guthrie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Rhazinilam: Axial to Point Chirality Transfer in an Enantiospecific Pd-Catalyzed Transannular Cyclization

(2010) Zhenhua Gu et al.   ORGANIC LETTERS

Nickel-Catalyzed Asymmetric Ullmann Coupling for the Synthesis of Axially Chiral Tetra-ortho-Substituted Biaryl Dials

(2010) Wen-Wen Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to SE2′ Chirality Transfer Reactions

(2010) Masamichi Ogasawara et al.   ORGANIC LETTERS

Pinacol Coupling of 2,2′-Biaryldiketone: An Application for the Synthesis of Enantiopure 3,4-Dihydrodibenzo[c,g]phenanthrene-3,4-diol Derivatives

(2010) Mitsuru Kitamura et al.   SYNLETT

Electrophilic Addition and Cyclization Reactions of Allenes

(2009) Shengming Ma   ACCOUNTS OF CHEMICAL RESEARCH

First Stereoselective Total Synthesis of FD-594 Aglycon

(2009) Ritsuki Masuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Samarium Diiodide Mediated Reactions in Total Synthesis

(2009) K. C. Nicolaou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereochemical Relay via Axially Chiral Styrenes: Asymmetric Synthesis of the Antibiotic TAN-1085

(2009) Keiji Mori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective catalysis and complexity generation from allenoates

(2009) Bryan J. Cowen et al.   CHEMICAL SOCIETY REVIEWS

Gold and platinum catalysis—a convenient tool for generating molecular complexity

(2009) Alois Fürstner   CHEMICAL SOCIETY REVIEWS

Exploiting [2+2] cycloaddition chemistry: achievements with allenes

(2009) Benito Alcaide et al.   CHEMICAL SOCIETY REVIEWS

Gold-Catalyzed [4C+3C] Intramolecular Cycloaddition of Allenedienes: Synthetic Potential and Mechanistic Implications

(2009) Beatriz Trillo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Light-Induced Transfer of Molecular Chirality in Solution: Enantiospecific Photocyclization of Molecularly Chiral Acrylanilides

(2009) Anoklase Jean-Luc Ayitou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific Photochemical Norrish/Yang Type II Reaction of Nonbiaryl Atropchiral α-Oxoamides in Solution—Axial to Point Chirality Transfer

(2009) Anoklase Jean-Luc Ayitou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Highly Enantioenriched 3,4-Dihydroquinolin-2-ones by 6-Exo-trigRadical Cyclizations of Axially Chiral α-Halo-ortho-alkenyl Anilides

(2009) David B. Guthrie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Chiral Allenoates by Guanidine-Catalyzed Isomerization of 3-Alkynoates

(2009) Hongjun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation and Trapping of Cyclopentenylidene Gold Species: Four Pathways to Polycyclic Compounds

(2009) Gilles Lemière et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium Catalyzed Allene Amination: Diastereoselective Synthesis of Aminocyclopropanes via a 2-Amidoallylcation Intermediate

(2009) Armin H. Stoll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkylidenesilacyclopropanes Derived from Allenes: Applications to the Selective Synthesis of Triols and Homoallylic Alcohols

(2009) Kay M. Buchner et al.   ORGANIC LETTERS

6π-Photocyclization of O-tert-butylacrylanilides. N-substitution dictates the regiochemistry of cyclization

(2009) Anoklase Jean-Luc Ayitou et al.   PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES

Catalytic enantioselective synthesis of axially chiral allenes

(2009) Masamichi Ogasawara   TETRAHEDRON-ASYMMETRY

Highly Regio- and Stereoselective Double Michael Addition-Cyclization of 2,3-Allenoates with Organozinc Compounds: Efficient Synthesis of 5-Benzylidenecyclohex-2-enones

(2008) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Fluorine as a Versatile Control Element for the Construction of Molecules with Helical Chirality

(2008) Tim Rasmusson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Role of Bent Acyclic Allene Gold Complexes in Axis-to-Center Chirality Transfers

(2008) Vincent Gandon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights

(2008) Véronique Michelet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric synthesis of β-lactams using chiral-memory effect on photochemical γ-hydrogen abstraction by thiocarbonyl group

(2008) Masami Sakamoto et al.   CHEMICAL COMMUNICATIONS

Alternative Synthetic Methods through New Developments in Catalysis by Gold

(2008) Antonio Arcadi   CHEMICAL REVIEWS

Gold-Catalyzed Hydrative Carbocyclization of 1,5- and 1,7-Allenynes Mediated by π-Allene Complex: Mechanistic Evidence Supported by the Chirality Transfer of Allenyne Substrates

(2008) Chun-Yao Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Photosensitized 2 + 2 Cycloaddition Reaction Using Homochirality Generated by Spontaneous Crystallization

(2008) Masami Sakamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Powdered KOH in DMSO:  An Efficient Base for Asymmetric Cyclization via Memory of Chirality at Ambient Temperature

(2008) Takeo Kawabata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Synthesis of Endocyclic Allenes and Their Application in Stereoselective [2 + 2]Cycloaddition with Ketenes

(2008) Masamichi Ogasawara et al.   ORGANIC LETTERS

Annulations of Enantioenriched Allenylsilanes with in Situ Generated Iminium Ions: Stereoselective Synthesis of Diverse Heterocycles

(2008) Ryan A. Brawn et al.   ORGANIC LETTERS

Asymmetric Radical and Anionic Cyclizations of Axially Chiral Carbamates†

(2008) David B. Guthrie et al.   ORGANIC LETTERS

Recent advances in syntheses of carbocycles and heterocycles via homogeneous gold catalysis. Part 2: Cyclizations and cycloadditions

(2008) Hong C. Shen   TETRAHEDRON

Multiple chirality transfers in the enantioselective synthesis of 11-O-debenzoyltashironin. Chiroptical analysis of the key cascade

(2008) Alessandra Polara et al.   TETRAHEDRON LETTERS

Atropisomerism in the 2-Arylimino-N-(2-hydroxyphenyl)thiazoline Series:  Influence of Hydrogen Bonding on the Racemization Process

(2007) Christian Roussel et al.   JOURNAL OF ORGANIC CHEMISTRY