Total Synthesis of (+)-Asteriscanolide: Further Exploration of the Rhodium(I)-Catalyzed [(5+2)+1] Reaction of Ene-Vinylcyclopropanes and CO

Enantioselective total synthesis of (+)-asteriscanolide via Rh(i)-catalyzed [(5+2)+1] reaction

(2011) Yong Liang et al.   CHEMICAL COMMUNICATIONS

Internal Chelation-Guided Regio- and Stereoselective Pauson-Khand-Type Reaction by Chiral Rhodium(I) Catalysis

(2011) Dong Eun Kim et al.   Chemistry-An Asian Journal

Rh(I)-Catalyzed Formal [6 + 2] Cycloaddition of 4-Allenals with Alkynes or Alkenes in a Tether

(2011) Yoshihiro Oonishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes

(2011) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed Formal [5 + 1]/[2 + 2 + 1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds

(2011) Mu Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Tandem Heterocyclization and Carbonylative [(3+2)+1] Cyclization of Diyne-enones

(2011) Wanxiang Zhao et al.   ORGANIC LETTERS

Rh(i)-catalyzed formal [2+2+2] cycloadditions of 1,6-diynes with potassium (Z)-(2-bromovinyl)trifluoroborate: a new strategy and a facile entry to polysubstituented benzene derivatives

(2010) Xianjie Fang et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed domino heterocyclization and [(3+2)+2] carbocyclization: construction of fused tricycloheptadienes

(2010) Wanxiang Zhao et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Eight-Membered Carbocycles

(2010) Zhi-Xiang Yu et al.   Chemistry-An Asian Journal

RhI-Catalyzed Two-Component [(5+2)+1] Cycloaddition Approach toward [5-8-5] Ring Systems

(2010) Feng Huang et al.   Chemistry-An Asian Journal

A Metal-Catalyzed Intermolecular [5+2] Cycloaddition/Nazarov Cyclization Sequence and Cascade

(2010) Paul A. Wender et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic and Steric Control of Regioselectivities in Rh(I)-Catalyzed (5 + 2) Cycloadditions: Experiment and Theory

(2010) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of α-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?

(2010) Qian Li et al.   ORGANIC LETTERS

Rh(I)-Catalyzed [(3 + 2) + 1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson−Khand Reaction and Total Synthesis of (±)-α-Agarofuran

(2010) Lei Jiao et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Carbonylative Carbocyclization of Tethered Ene− and Yne−cyclopropenes

(2010) Changkun Li et al.   ORGANIC LETTERS

Formal total synthesis of (±)-hirsutic acid C using the tandem Rh(I)-catalyzed [(5+2)+1] cycloaddition/aldol reaction

(2010) Changxia Yuan et al.   TETRAHEDRON LETTERS

Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes

(2009) Lei Jiao et al.   CHEMICAL COMMUNICATIONS

Formal syntheses of (±)-Asterisca-3(15),6-diene and (±)-Pentalenene using Rh(I)-catalyzed [(5+2)+1] cycloaddition

(2009) Xiaohui Fan et al.   TETRAHEDRON

Substituent Effects, Reactant Preorganization, and Ligand Exchange Control the Reactivity in RhI-Catalyzed (5+2) Cycloadditions between Vinylcyclopropanes and Alkynes

(2008) Peng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (−)-Pseudolaric Acid B

(2008) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton:  Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin

(2008) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of Differences in Reactivities of Alkenes, Alkynes, and Allenes in [Rh(CO)2Cl]2-Catalyzed (5 + 2) Cycloaddition Reactions with Vinylcyclopropanes

(2008) Zhi-Xiang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An expeditious and high-yield formal synthesis of hirsutene using Rh(I)-catalyzed [(5+2)+1] cycloaddition

(2008) Xiaohui Fan et al.   TETRAHEDRON LETTERS