Aryne Insertion into σ Bonds

Diversity-Oriented Synthesis of Spiroannulated Benzofuran-3-one Scaffold of Leptosphaerin C and Congeners via Aryne Insertion

(2017) Ranjeet A. Dhokale et al.   JOURNAL OF ORGANIC CHEMISTRY

Emerging Developments Using Nitrogen–Heteroatom Bonds as Amination Reagents in the Synthesis of Aminoarenes

(2017) Charles E. Hendrick et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of o-Methyl Trifluoromethyl Sulfide Substituted Benzophenones via 1,2-Difunctionalization of Aryne by Insertion into the C–C Bond

(2017) Milind M. Ahire et al.   ORGANIC LETTERS

Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides

(2017) Xiaojin Li et al.   ORGANIC LETTERS

Synthesis of aryl triflones by insertion of arynes into C–SO2CF3 bonds

(2017) Xian Zhao et al.   RSC Advances

Sulfonium Ylides by (3+2) Cycloaddition of Arynes with Vinyl Sulfides: Stereoselective Synthesis of Highly Substituted Alkenes

(2016) Yuanming Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From insertion to multicomponent coupling: temperature dependent reactions of arynes with aliphatic alcohols

(2016) Manikandan Thangaraj et al.   CHEMICAL COMMUNICATIONS

Ring Expansion via Cleavage of Benzylic C−C Bonds Enabling Direct Synthesis of Medium Ring-Fused Benzocarbocycles

(2016) Bin Rao et al.   Chemistry-An Asian Journal

Synthesis of P-stereogenic diarylphosphinic amides by directed lithiation: transformation into tertiary phosphine oxides via methanolysis, aryne chemistry and complexation behaviour toward zinc(ii)

(2016) Miguel A. del Águila-Sánchez et al.   DALTON TRANSACTIONS

Insertion of N-Tosylacetimidates/Acetimidamides onto Arynes via [2 + 2] Cycloaddition

(2016) Ramagonolla Kranthikumar et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Free Synthesis of N-Aryl Hydroxamic Acids via Insertion of Arynes

(2016) Lanlan Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides

(2016) Yuanyuan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2-Benzylphenyl Ketones by Aryne Insertion into Unactivated C–C Bonds

(2016) Bin Rao et al.   ORGANIC LETTERS

Versatile Route to Benzoannulated Medium-Ring Carbocycles via Aryne Insertion into Cyclic 1,3-Diketones: Application to a Synthesis of Radermachol

(2016) Ramesh Samineni et al.   ORGANIC LETTERS

Insertion of Arynes into P–O Bonds: One-Step Simultaneous Construction of C–P and C–O Bonds

(2016) Na Qi et al.   ORGANIC LETTERS

Aryne Relay Chemistry en Route to Aminoarenes: Synthesis of 3-Aminoaryne Precursors via Regioselective Silylamination of 3-(Triflyloxy)arynes

(2016) Suguru Yoshida et al.   ORGANIC LETTERS

Synthesis of Aryl Ketoamides via Aryne Insertion into Imides

(2016) Austin C. Wright et al.   ORGANIC LETTERS

Formal Total Synthesis of (±)-Cephalotaxine and Congeners via Aryne Insertion Reaction

(2016) Pashikanti Gouthami et al.   ORGANIC LETTERS

Multiple Aryne Insertions into Oxindoles: Synthesis of Bioactive 3,3-Diarylated Oxindoles and Dibenzo[b,e]azepin-6-ones

(2016) Ramesh Samineni et al.   ORGANIC LETTERS

Preparation of organophosphorus compounds from P–H compounds using o-(trimethylsilyl)aryl triflates as aryne precursors

(2016) Guoqiang Yang et al.   TETRAHEDRON

Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through CH Activation and Orthogonal Reactivity

(2015) Emilien Demory et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion of Arynes into the π-Bond Giving [2+2] Cycloaddition-type Adducts

(2015) Hideto Miyabe   CURRENT ORGANIC CHEMISTRY

P-Arylation of Dialkyl Phosphites and Secondary Phosphine Oxides with Arynes

(2015) Qian Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Approach for the Synthesis of N-Aryl Sulfoximines via Aryne Intermediate

(2015) Sravan Kumar Aithagani et al.   ORGANIC LETTERS

Synthesis of o-Aminophenols via a Formal Insertion Reaction of Arynes into Hydroxyindolinones

(2015) Zhilong Chen et al.   ORGANIC LETTERS

Reaction of Arynes with Sulfoxides

(2015) Hong-Ying Li et al.   ORGANIC LETTERS

Activation of Aryl Thiocyanates Followed by Aryne Insertion: Access to 1,2-Thiobenzonitriles

(2015) Martin Pawliczek et al.   ORGANIC LETTERS

Facile N-arylation of amidines and N,N-disubstituted amidines

(2015) Tuanli Yao   TETRAHEDRON LETTERS

The insertion of arynes into the O–H bond of aliphatic carboxylic acids

(2015) Chunxiao Wen et al.   TETRAHEDRON LETTERS

α-Monoarylation and tandem arylation–insertion of malonates with arynes

(2015) Qian Chen et al.   TETRAHEDRON LETTERS

Regioselective Insertion ofo-Carborynes into the α-CH Bond of Tertiary Amines: Synthesis of α-Carboranylated Amines

(2014) Da Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds

(2014) Yuwen Zeng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of ortho-Haloaminoarenes by Aryne Insertion of Nitrogen–Halide Bonds

(2014) Charles E. Hendrick et al.   JOURNAL OF ORGANIC CHEMISTRY

Three-Component Coupling Reaction Triggered by Insertion of Arynes into the S═O Bond of DMSO

(2014) Feng-Lei Liu et al.   ORGANIC LETTERS

Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N-Heterocycles

(2014) María-José Oliva-Madrid et al.   ORGANOMETALLICS

Facile synthetic protocols for perfluoroalkyl-substituted diazapentaphenes

(2014) Shigeyuki Yamada et al.   TETRAHEDRON

Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes

(2013) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-pot Synthesis of 2,3-Benzodiazepines from Arynes and β-Diketones

(2013) Kentaro Okuma et al.   CHEMISTRY LETTERS

Insertion of Arynes into N-Halo Bonds: A Direct Approach to o-Haloaminoarenes

(2013) Charles E. Hendrick et al.   ORGANIC LETTERS

Insertion of Arynes into Arylphosphoryl Amide Bonds: One-Step Simultaneous Construction of C–N and C–P Bonds

(2013) Chaoren Shen et al.   ORGANIC LETTERS

Addition of Cyclic Ureas and 1-Methyl-2-oxazolidone to Pyridynes: A New Approach to Pyridodiazepines, Pyridodiazocines, and Pyridooxazepines

(2013) Nozomi Saito et al.   ORGANIC LETTERS

Aminocyanation by the Addition of N–CN Bonds to Arynes: Chemoselective Synthesis of 1,2-Bifunctional Aminobenzonitriles

(2013) Bin Rao et al.   ORGANIC LETTERS

Intermolecular C–O addition of carboxylic acids to arynes: synthesis of o-hydroxyaryl ketones, xanthones, 4-chromanones, and flavones

(2013) Anton V. Dubrovskiy et al.   TETRAHEDRON

A novel and convenient strategy for the synthesis of phthalazines from an aryne precursor

(2013) Hassen Bel Abed et al.   TETRAHEDRON LETTERS

Insertion of benzyne into the Pd–C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2′-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates

(2012) José-Antonio García-López et al.   CHEMICAL COMMUNICATIONS

Aryne Insertion into I–I σ-Bonds

(2012) Diego Rodríguez-Lojo et al.   ORGANIC LETTERS

Formal Insertion of o-Carborynes into Ferrocenyl C–H Bonds: A Simple Access to o-Carboranylferrocenes

(2012) Sunewang Rixin Wang et al.   ORGANOMETALLICS

Aryne Insertion Reactions into Carbon-Carbon σ-Bonds

(2012) Hiroto Yoshida et al.   SYNLETT

A C–N insertion of β-lactam to benzyne: unusual formation of acridone

(2012) Jimin Kim et al.   TETRAHEDRON LETTERS

Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation

(2011) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Regioselective Insertion of Carborynes into Ethereal C−H Bond: Facile Synthesis of α-Carboranylated Ethers

(2011) Sunewang R. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Insertion of Arynes into a C(sp)−O(sp3) σ Bond

(2011) Krzysztof Z. Ła̧czkowski et al.   ORGANIC LETTERS

Insertion of Benzyne into a Bi–S Bond: A New Synthetic Route toortho-Functionalized Bismuthanes and Its Application to the Synthesis of Dibenzothiophene

(2011) Jing Chen et al.   ORGANOMETALLICS

Intermolecular N-Heterocyclic Carbene Catalyzed Hydroacylation of Arynes

(2010) Akkattu T. Biju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryne,ortho-Quinone Methide, andortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates

(2010) Hiroto Yoshida et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

(2010) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Regioselective Reactions of Highly Substituted Arynes

(2010) Pamela M. Tadross et al.   ORGANIC LETTERS

Aryne Acyl-Alkylation in the General and Convergent Synthesis of Benzannulated Macrolactone Natural Products: An Enantioselective Synthesis of (−)-Curvularin

(2010) Pamela M. Tadross et al.   ORGANIC LETTERS

O ressurgimento da química de benzino com sililaril triflatos no contexto das reações de inserção em ligações sigma

(2010) Rafael D. C. Gallo et al.   QUIMICA NOVA

The Benzyne Aza-Claisen Reaction

(2009) Alastair A. Cant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion of Arynes into Carbon–Chlorine Bonds of Chlorotriazines

(2009) Hiroto Yoshida et al.   CHEMISTRY LETTERS

Selective Synthesis ofo-Acylbenzylphosphonates by Insertion Reactions of Arynes into β-Ketophosphonates

(2009) Yi-Lin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Insertion of Benzene Rings into the Amide Bond: One-Step Synthesis of Acridines and Acridones from Aryl Amides

(2009) Didier G. Pintori et al.   ORGANIC LETTERS

Ring expansion reaction of α-sulfonyl cyclic ketones via insertion of arynes into C–C: a facile and mild access to medium- and large-sized benzannulated carbocycles

(2009) Tiexin Zhang et al.   TETRAHEDRON LETTERS

Fluorenes as new molecular scaffolds for carbon–carbon σ-bond cleavage reaction: acylfluorenylation of arynes

(2008) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS