期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 15, 页码 5760-5763出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja201126h
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资金
- Research Grants Council of the Hong Kong Special Administration Region [404610]
- Direct Grant [2060407]
- The Chinese University of Hong Kong
Carborynes can exist in two resonance forms, bonding form vs biradical form. The biradical form can be readily generated via the elimination of LiI from 1-iodo-n-lithio-1,n-C2B10H10 (n = 2, 7) under UV irradiation. They can undergo alpha-C H bond insertion with aliphatic ethers, affording alpha-carboranylated ethers in excellent regioselectivity at room temperature. This serves as a new methodology for the generation of a series of functionalized carboranes bearing alkoxy units.
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